Transitional phenomenon of particle dispersion in gas-solid two-phase flows

Without using any turbulent model, direct numerical simulation of a three-dimensional gas-solid two-phase turbulent jet was performed by finite volume method. The effects on dispersion of particles with different Stokes numbers by the transitional behavior of turbulent structures were investigated. To produce high-resolution results and reduce the computation and storage, the fractional-step projection algorithm was used to solve the governing equations of gas phase fluid. The low-storage, three-order Runge-Kutta scheme was used for time integration. The governing equations of particles were solved in the Lagrangian framework. These numerical schemes were validated by the good agreement be-tween the statistical results of flow field and the related experimental data. In the study of particle dis-persion, it was found that the effects on particle dispersion by the spanwise vortex structures were prominent. The new behaviors of particle dispersion were also observed during the evolution of the flow field, i.e. the transitional phenomenon of particle dispersion occurs for the particles with small and intermediate Stokes numbers.     

二元向量输出的Partially Bent函数

把关于布尔函数的Carlet不等式推广到向量输出的布尔函数并且引入了向量输出的Partially Bent函数的概念,即广义Carlet不等式中等式成立的向量输出布尔函数.给出了一些广义Carlet不等式中等式成立的充分必要条件.进一步讨论了二元向量输出的partially bent函数的密码学性质.     

大涡结构在有压梯度边界层流中的演化机理

采用直接数值模拟方法,研究大涡结构在不同压力梯度作用下的非线性演化特征.计算结果表明:在逆压梯度条件下,大涡结构幅值快速增长,形成很强的流向涡结构,雷诺应力迅速增加,这可能导致猝发现象的产生;与此相反,在顺压梯度边界层流中,大涡结构很难被激发起来,易于流体流动趋于稳定状态.这些结论与某些理论和试验结果一致.     

湍流多尺度相干结构间歇性的PIV实验研究

利用粒子成像测速(PIV)系统测量了湍流边界层中流向速度平面,并对湍流多尺度相干结构统计特性进行了实验研究.利用连续子波变换,计算了不同尺度、不同法向位置的子波系数概率密度函数.结果发现缓冲区有着更强的间歇性.利用子波系数量化湍流间歇性的方法,应用推广的自相似律(ESS),计算了子波系数结构函数的标度指数.研究表明:当多尺度相干结构被提取出后,利用子波系数计算的ESS标度律就符合科尔莫戈罗夫提出的线性标度律,验证了多尺度相干结构是湍流边界层产生奇异标度律的原因.此外,利用PIV系统测量的数据,给出了流向平面内的以子波系数表达的能量分布.这种方法有利于进一步对多尺度相干结构在空间平面内的辨识与特性进行研究.     

Electronic properties and stabilities of methoxy-substituted Lindqvist polyoxometalates [Nb2W4019CH3]3- by DFT

The electronic properties and stabilities of five [Nb2W4O18OCH3]3-isomers have been investigated using a density functional theory method.The results show that the isomer with the methoxy group occupying a bridging position between two tungsten atoms(two tungsten atoms in the plane that contains two niobium atoms) in the [Nb2W4O18OCH3]3-framework is the most stable isomer in acetonitrile.The stability of the one-electron-reduced isomers changes little.The most stable one-electron-reduced isomer has the methoxy group occupying a bridging position between niobium atoms in the [Nb2W4O18OCH3]4-framework.The M-Ob(M = Nb,W;b denotes bridging) bond lengths in anions in which the metal atoms are connected by a methoxy group are longer than those in [Nb2W4O19]4-.The highest occupied molecular orbitals(HOMO) in [Nb2W4O19]4-mainly delocalize over the bridging oxygen atoms of two niobium atoms and two tungsten atoms located in the equatorial plane,and the bridging oxygen atoms on the axial surface.The lowest unoccupied molecular orbitals(LUMO) of [Nb2W4O19]4-are mainly concentrated on the tungsten atoms and antibonding oxygen atoms.Methoxy substitution modifies the electronic properties of the [Nb2W4O18OCH3]3-isomers.The HOMOs in the five isomers formally delocalize over the bridging oxygen atoms,which are distant from the surface containing the methoxy group and four metal atoms.The LUMOs delocalize over the d-shells of the four metal atoms that are close to the methoxy group,and the p-orbitals of oxygen.One-electron reduction occurred at the tungsten atoms,not the niobium atoms.     

Structures and Properties of Composite Yarns of Filaments and Wool Staple Fibers

More and more composite yarns of filament and wool staple fiber have been applied to develop the new type of fabrics. However, the great difference in yarn structures between the composite yarns and conventional staple yarns does affect the properties of yarns and fabrics. In this paper, it has been studied that the differences of the composite yarn properties of tensile, bending rigidity, torsional rigidity, the hairiness and irregularity etc.     

喹诺酮药物及其金属配合物研究进展

本文综述了喹诺酮类抗菌药物的发展历程和喹诺酮金属化合物的配位结构和活性等方面的研究现状,展望了此类研究的发展趋势。     

南方菟丝子水溶性成分的研究

采用Sephadex LH-20、RP-18反相柱、MCI和硅胶层析方法对南方菟丝子全草的化学成分进行分离纯化，运用现代波谱技术鉴定TZ个化合物：表儿茶素、刺五加-O-β—D-葡萄糖甙和Roseoside I。     

混合结构建筑温度收缩应力的近似计算

目前国内的混合结构建筑，由于温度变化以及材料伸缩等原因引起的墙体裂缝现象较为普遍。根据混合结构房屋构件之间的相互约束以及协同工作的关系，文章提出了温度收缩应力和变形的近似计算方法。计算结果表明，与现场实测的结果吻合较好，计算公式可供工程实践参考。     

沉降观测中被测建构筑物可视为基本稳定的判定

详细介绍了沉降观测中被测建构筑物可视为基本稳定的判定方法,提出了在沉降观测中应注意的事项。