共振散射光谱分析方法测定痕量庆大霉素

在pH值为3.2-6.2 NaOAc-HOAc缓冲介质中,十二烷基苯磺酸钠分别与硫酸庆大霉素(GEN)、硫酸妥布霉素(TOB)、硫酸卡那霉素(KANA)、硫酸新霉素(NEO)等氨基糖苷类抗生素相互作用形成缔合物,在320,340,420 和470 nm有4个散射峰.GEN,TOB,KANA和NEO的浓度分别在0.072 0-5.04,0.128-7.04,0.240-4.80,0.076 0-6.84 mg/L与共振散射强度成正比,检出限分别为0.010,0.031,0.090,0.070 mg/L.该法有好的选择性和灵敏度,用于市售庆大霉素注射液、片剂和胶囊的测定,结果比较满意.     

初始条件及喷雾对柴油机缸内流动影响研究

将柴油机缸内气体与整个燃烧室部件(气缸盖-气缸套-活塞组)作为一个耦合体,在对耦合体进行传热数值模拟的基础上得到缸内流动计算的壁面边界条件.利用大型通用CFD软件STAR-CD及ES-ICE对6110柴油机缸内三维非稳态流动进行数值模拟研究,着重分析不同初始条件及燃油喷射对缸内流动的影响.研究结果表明初始条件在柴油机进气过程缸内流场多维计算中主要影响流场的流动状态,特别是涡团形状和中心位置;喷雾过程中燃油的喷射流动直接影响到缸内的流场分布.     

Investigating different bio-responses of the upper ocean to Typhoon Haitang using Argo and satellite data

The responses of the upper ocean to Typhoon Haitang in July 2005 are investigated using Argo float and multiplatform satellite data. The results show decreasing sea surface temperature （SST）, a deepening of the mixed layer depth （MLD）, and enhanced Chloro- phyll-a （Chl-a） concentration. Two extreme cool regions are identified. While the magnitude of SST cooling in the two regions is similar, the biological response （Chl- a enhancement） differs. To facilitate comparisons, the region to the northeast of Taiwan is defined as region A and the region east of Taiwan as region B. Ekman pumping and the intrusion of the Kuroshio play an important role in the enhancement of Chl-a in region A. Cold eddies provide the material source for the forma- tion of the cold center in region B, where mixing is dominant. Because of the relatively high translation speed （5 m/s） in region B, Ekman pumping has little influence on the cooling and Chl-a enhancement pro- cesses. Moreover, the MLD is shallower than the nutri- cline, which means that mixing does not result in a marked increase in nutrients in the euphotic layer （where the nutrient concentration is uniformly depleted）. Sea temperatures, in contrast, gradually decrease with depth below the bottom of the mixed layer. In contrast toregion A, region B showed no significant enhancement of Chl-a but strong SST cooling.     

声光效应的实验研究

利用LD泵浦全固态固体激光器产生的532nm绿光在SO2000型声光效应实验仪上进行了声光衍射角、声光调制的实验研究,并与650nm红光作了比较.实验得出:532nm绿光的拉曼-奈斯衍射实验效果较好,在实验中很容易将±1级衍射光的光强调制的较强且强度一致,而高级衍射光几乎不会出现,全部能量都分布在0级衍射光和±1级衍射光上,可用来制作双通道声光调制器和声光偏转器.     

光子晶体光纤中反斯托克斯效应的实验研究

在对自行设计的光纤进行实验研究的过程中,通过逐渐增加泵浦脉冲的中心波长λD发现随着λD逐渐接近零色散波长λD,在一系列非线性效应的作用下泵谱脉冲的频谱逐渐展宽,同时其转化效率也逐渐增加,在短波段的反斯托克斯波的强度也逐渐增加.尤其当λD等于λD时,反斯托克斯波达到最强,说明此时相位匹配的很好,致使四波混频效应最为显著.而当λD逐渐远离λD时,在频谱宽度逐渐减小的同时,泵谱转化效率也逐渐降低.当λD为860 nm时,反斯托克斯波几乎消失,这允分说明泵谱中心波长λD在频率转换过程中的显著影响.     

一种计算对称反对称及周期性问题的改进无网格法

分析对称反对称或周期性问题时,通常只需要取一半或一个周期的局部模型进行离散求解．由于无网格法存在较为显著的边界截断效应,与整体模型相比局部模型的无网格解答精度会有所下降,在边界附近更为显著．为消除这种边界效应,提出了一种改进的无网格近似方法．该方法考虑了局部模型外的节点（虚拟节点）对于模型内各节点（真实节点）的近似影响,并利用对称反对称或周期性关系压缩虚拟节点的自由度,在不增加额外自由度的条件下能够使局部模型和整体模型得到完全相同的结果．通过求解对称反对称和周期性问题算例验证了该方法的有效性．最后对一般性问题的无网格边界效应也进行了简要的讨论．     

Cooling process of iron ore pellets in an annular cooler

A 3-D mathematical model was presented for the cooling process of iron ore pellets based on the laws of mass, momentum, and heat transfer. The flow, pressure, and temperature fields were obtained by numerical simulation with the commercial software FLUENT. In order to verify the model, a mass and energy balance field test was systematically carried out on an annular cooler in Shougang Mining Company. The maximum relative errors of temperature, pressure, and velocity between computational and testing results are 2.87%, -8.11%, and 7.14%, respectively, indicating the validity of the model. Further, the effects of process parameters, such as pellet diameter, bed thickness, air velocity, and temperature, on the pellet bed temperature profiles were studied.     

Martensitic transformation and magnetic properties of aged Ni-Fe-Ga-Ti shape memory alloy

This article reports the effect of ageing on the microstructure, martensitic transformation, magnetic properties, and mechanical properties of Ni₅₁Fe₁₈Ga₂₇Ti₄ shape memory alloy. There are five specimens of this alloy aged at 573 up to 973 K for 3 h per each. This range of ageing temperature greatly affects the microstructure of the alloy. As the ageing temperature increased from 573 up to 973 K, the microstructure of Ni₅₁Fe₁₈Ga₂₇Ti₄ alloy gradually changed from the entirely martensitic matrix at 573 K to the fully austenitic microstructure at 973 K. The volume fraction of precipitated Ni₃Ti particles increased with the ageing temperature increasing from 573 to 773 K. Further increasing the ageing temperature to 973 K decreased the content of Ni₃Ti in the microstructure. The martensitic transformation temperature was decreased steadily by increasing the ageing temperature. The magnetization saturation, remnant magnetization, and coercivity increased with the ageing temperature increasing up to 773 K. A further increase in ageing temperature decreased these magnetic properties. Moreover, the hardness values were gradually increased at first by increasing the ageing temperature to 773 K, and then dramatically decreased to the lowest value at 973 K.     

Reinforcing effect of laminate structure on the fracture toughness of Al3Ti intermetallic

Metal/intermetallic laminate composites can improve the mechanical properties of intermetallic materials using metal layers. In recent years, titanium aluminide intermetallics have received increasing attention due to their excellent performance properties, such as high melting point, high specific strength and stiffness, and good corrosion resistance. However, the low fracture toughness of Al3Ti alloys at room temperature has greatly limited their application, and fiber or particle reinforcement has not shown a significant toughening effect. Research into the reinforcing effects of the interface and near-interface zone on the fracture behavior of Al3Ti is lacking. Ti/Al3Ti metal/intermetallic laminate composite was synthesized from titanium and aluminum foils using vacuum hot-pressed sintering technology. The microstructure of the prepared material was analyzed by scanning electron microscope and electron backscattered diffraction. Results illustrate that both Ti and Al3Ti were single-phase and there was a noticeable stress concentration on the interface. To obtain indentation and cracks, loads were applied to different locations of the composite by a microhardness tester. The growth path of the cracks was then observed under microscope, showing that crack propagation was prevented by the interface between the Ti and Al3Ti layers, and the cracks that propagated parallel to the laminate shifted to the interface. Fracture toughness of the different areas, including Al3Ti layers, interface, and near-interface zone, were measured by the indentation fracture method. The fracture toughness at and near the interface was 1.7 and 2 times that of the Al3Ti layers, respectively. Results indicate that crack blunting and crack front convolution by the laminate structure was primarily responsible for increased toughness.     

Electromigration in eutectic SnAg solder reaction couples with various ambient temperatures and current densities

The electromigration behavior of eutectic SnAg solder reaction couples was studied at various temperature (25 and 120℃ when the current density was held constant at 104 A/cm2 or 5×103 A/cm2. Under the current density of 104 A/cm2, scallop type Cu₆Sn₅ spalls and migrates towards the direction of electron flow at room ambient temperature (25℃), but transforms to layer type Cu₃Sn and leaves Kirkendall voids in it at high ambient temperature (120℃). Under the current density of 5×103 A/cm2 plus room ambient temperature, no obvious directional migration of metal atoms/ions is found. Instead, the thermal stress induced by mismatch of dissimilar materials causes the formation of superficial valley at both interfaces. However, when the ambient temperature increases to 120℃, the mobility of metal atoms/ions is enhanced, and then the grains rotate due to the anisotropic property of β-Sn.