微波ECR等离子体溅射沉积T_t薄膜的结构研究

用电子回旋共振(ECR)等离子体溅射方法在室温基片上沉积出的T_i薄膜的结构是用X RD和TEM进行分析的。结果表明所沉积的T_i薄膜是平均粒径,晶粒尺寸分布很窄的稳定fcc结构。在实验过程中发现可以通过对工作参数的调整控制薄膜的晶粒尺寸。我们还讨论了ECR等离子体对薄膜结构和晶粒尺寸的影响。     

次近邻电子跳跃对聚苯胺基态电子结构的影响

在聚苯胺的Baranowski-Büttner-Voit模型基础上,引入了含有次近邻电子跳跃的哈密顿修正项,并推导出相关理论公式.数值计算了完全氧化态的Pernigraniline-base(PNB)和半氧化态的Emeraldine-base(EB)的基态电子能谱结构,结果表明(1)次近邻电子跳跃对能隙和总带宽的影响较小;(2)随着次近邻跳跃强度的增加,PNB聚合物价带宽度将增加,导带被压缩;而EB聚合物的导带与价带均被压缩.     

SO_2预放电参数的研究

本文采用脉冲漂移管-质谱仪方法研究了SF_6混合气体放电生成的SO_2气体的预放电参数,包括吸附系数、吸附速率、负离子迁移率、负离子种类和质量,并且测量了SO_2-O_2中不同负离子电流的变化关系.     

原子光谱和能级的符号表示

近代物理的两大支柱是量子力学与相对论,在现代科学技术中以量子力学的运用最为广泛,原子物理学就属于量子力学知识体系当中的一个范畴。文章运用玻尔理论及受力分析的方法,针对不同的情况,考虑不同的相互作用,将定态能量和光谱用符号表示,为分析问题、解决问题提供便利。     

Growth mechanisms of Ag and Cu nanodendrites via Galvanic replacement reactions

Dendritic silver and copper crystals were produced via Galvanic replacement reactions on zinc and aluminum plates, respectively. The growth orientations of these metals were determined using electron microscopy. The results showed that a fast crystal growth associated with a high concentration of metal cations led to kinetically controlled growth along the <112> axes of the cubic close-packed structures. However, a slow growth rate resulted in thermodynamically controlled growth along the [111] axis. The crystal growth was not found to rely upon the direct deposition of metal cations at crystallographic sites on crystal facets, but instead, hydrated metal cations deposited on the crystal surface to form an amorphous coating layer, followed by the reduction of metal cations and crystallization at the crystal/coating interface. Twin defects and stacking faults were often observed across the whole particle and commonly observed ?{422} diffraction spots were explained by stacking faults rather than by the possible presence of any superstructures. The present work offers evidences to claim that both the crystal growth rate and Coulomb interaction between negatively charged crystal surface and metal cations play an important role in the formation of metal dendrites in replacement reactions.     

低碳马氏体回火组织形貌与机械性能的关系

本文用复型和透射电镜等方法对15MnB、18CrNiW两种钢的低碳马氏体组织形貌与机械性能之间的相应关系,进行了较为详细的论述.     

电子交换作用对BCS理论的影响(1)

本文利用Kim的Hamiltonian具体讨论了V,Al金属中交换作用对BCS理论的影响.计算结果表明,其影响相当可观.     

用正电子素探测镀镍添加剂的亲电子能力

本实验分别测定五种镀镍添加剂与正电子素在水溶液中络合反应的表观生成速度常数Kobs,并以此作为衡量它们的亲电子能力的标准.本文描述正电子素与有机分子络合反应机理,并指明所探测的是吸引单个电子的能力.