CuO/MIL(Cr,Cu)复合材料的制备及其类芬顿催化降解苯酚性能研究

采用水热煅烧法合成CuO/MIL(Cr, Cu)非均相类芬顿催化剂,对CuO/MIL(Cr, Cu)复合材料进行了XRD、FT-IR、SEM、XPS、BET等表征,结果表明CuO均匀分散在金属有机框架MIL(Cr, Cu)的表面。对不同催化剂催化降解苯酚的性能进行比较。结果表明,当催化剂用量为0.3 g/L,H₂O₂浓度为50 mmol/L,pH=6,初始底物浓度为30 mg/L时,CuO/MIL(Cr, Cu)复合材料对苯酚的降解效果可达100%,降解效果优于CuO、MIL-101(Cr)。通过自由基猝灭实验和EPR测试等证明·OH是催化体系主要的活性自由基,并给出其可能的催化降解机理。CuO/MIL(Cr, Cu)复合材料可在近中性条件下降解酚类污染物,具有良好的应用前景。     

涂装车间漆雾过滤设备内流场数值模拟与设计优化

涂装车间在喷涂过程中会产生大量含有漆雾的喷涂废气,在处理喷涂废气之前需对其中的漆雾进行预过滤,在干式喷房中纸盒式漆雾过滤器由于更经济环保,越来越多地被投入使用。针对运行参数对过滤器过滤效率的影响,利用计算流体力学对折流板式纸盒过滤器的过滤效果进行了数值模拟研究,对过滤器的设计参数提出了优化建议。结果表明:设计参数对过滤器过滤效率的影响较大,过滤器对10 μm以下的漆雾颗粒过滤效率在10%~20%,过滤效率较低,对于10 μm以上的漆雾颗粒,过滤效率随粒径的增大而升高,对60 μm及以上的漆雾颗粒过滤效率达99%以上,部分大颗粒漆雾掉落至过滤器内,可实现漆雾储存;过滤器过滤效率随进口流速的增大而降低,随漆雾浓度的增大而升高,设备进出口压差随进口流速的增大而增大,但远低于喷房压阻限制。     

中厚板平面形状控制中的GM-AGC系统

阐述了对中厚板平面形状控制系统的基本要求和提高中厚板成材率的关键技术内容,研究了中厚板平面形状控制ＧＭ－ＡＧＣ系统的基本结构,着重分析和研究了成形轧制阶段变截面轧制的控制特点,以及提高平面形状控制精度必须考虑的几个问题,对ＧＭ－ＡＧＣ系统应采用的改进措施。     

K 16Mn连铸坯热装炉轧制对轧材组织性能影舷

采用高温固溶加热法,在φ300轧机上模拟现场连铸坯热装炉轧制工艺,分别考察了K16Mn钢不同热装温度和开轧温度对轧材组织性能的影响.结果表明,热装轧制和常规冷装轧制屈服、抗拉强度相当,热装轧制成品塑性、韧性均较好.热装轧制工艺对K16Mn钢组织的影响,随着热装温度的提高,轧前奥氏体晶粒变得粗大,并且轧后组织混晶程度提高.这可通过提高开轧温度,首道次采用大压下量促使铸坯发生完全再结晶来消除.从而细化晶粒.改善成品组织性能.     

新型钢管砼框架节点试验研究及其应用

给出了钢管混凝土框架节点的试验结果,并采用有限元法对新型节点模式进行了应力场分析。介绍了该新型节点的设计方案及在实际工程中的应用。     

Electrophysiological research of synapse formation from beginning to maturity

The development of synapses is an important question in neurobiology. We employ patchclamp technique to record MEPCs and EPCs of myoballs inXenopus cell culture. The rate of EPC/MEPC is related with synapses maturation. Accordingly, we define the mature synapses as those whose rate of presynaptic membrane ’ s EPC to MEPC is more than 8. The process of maturation needs about 2–5 h after neuntes contact with myoballs. We divide the development of synapses into three stages: young, developing and mature. The neurotransmitters stack gradually and increase by hundreds of times along with young synapses growing into maturity. So the process of synapses maturation should include presynaptic membrane specialization, postsynaptic membrane specialization and neurotransmitters stack.     

Two tyrosines in CD3ε-ITAM are required to induce T lymphocyte apoptosis

CD3ε of T cell antigen receptor complex (TCR/CD3) plays an important role in the resembling of the complex and activation signaling through its conservative immunoreceptor tyrosine-based activation motif (ITAM) in the cytoplasmic tail. Previous study showed that a chimera molecule, consisting of the extracellular-transmembrane domain of human CD8α fused to the cytoplasmic domain of CD3ε, induced apoptosis of T lymphocytes, indicating that apoptotic signals were transduced through the CD3ε- ITAM. To elineate involvement of the two tyrosines in apoptotic signaling pathway, cDNAs with mutations at Y170F, Y181F and Y170F/Y181F in CD8-ε-ITAM were made by point mutation and PCR, and then cloned into pcDNA3 eukaryotic expression vectors. Stable expression cell lines were established after transfection of the expression vectors into CD8+- Jurkat T lymphocytes. Stimulation of these cell lines with anti-CD8 monoclonal antibody showed that only the cells with expression of wild type chimera CD8-ε died by apoptosis, but not those cells with expressions of mutated CD8-ε chimera, indicating that the two tyrosines in CD3ε-ITAM were required for the apoptotic signal transduction in T lymphocytes.     

Effect of calcium ions on the secondary structures of photosystemⅡ and its relations with photoinhibition

Calcium ions play an important role in the oxygen_evolving process of photosystem Ⅱ as demonstrated in many experiments. The changes of the secondary structures of PS Ⅱ induced by the depletion of Ca 2+ were reported. The results indicated that the removal of Ca 2+ led to the transition of α helix to turns and sheet structures. While Ca 2+ was re_added to the media, only the structures changed to turns could be recovered. The protein conformational changes of PS Ⅱ during the donor side photoinhibition induced by the depletion of Ca 2+ were also studied. This showed that the protein conformational changes differed between the control and Ca 2+ _depleted samples in a short period of illumination (within 10 min). However, the changes became similar when the illumination time was increased.     

Third-order optical nonlinearities for lanthanum (Ⅲ) complexes with 1,10-phenanthroline components

The nonlinear refractive indexes n 2 for the ethanol solutions of 1,10-phenanthroline (2.0×10 -3 mol·L -1), [bis(1,10-phenanthroline) lanthanum (Ⅲ)] nitrate (1.0×10 -3 mol·L -1), and [nitrato-fluoracil-bis (1,10-phenanthroline) lanthanum (Ⅲ)] nitrate (1.0×10 -3 mol·L -1) are first measured, the third-order nonlinear optical susceptibilities χ (3) and <γ> are calculated, and the mechanisms of the third-order optical nonlinearities enhanced by lanthanum (Ⅲ) are discussed preliminarily.