（R）－2－硫代四氢噻唑－4－羧酸甲酯的合成及消旋化

Ｌ－半胱氨酸甲酯盐酸盐和二硫化碳在三乙胺存在下反应，当摩尔比为１：１．５：２时，得到的（Ｒ）－２－硫代四氢噻唑－４－羧酸甲酯，产率８０％；摩尔比为１：１．５１３．５时，得到Ｒ，Ｓ－２－硫代四氢噻唑－４－羧酸甲酯。另外，由（Ｒ）－２－硫代四氢噻唑－４－羧酸与甲醇及二氯亚硫酰反应，也得到（Ｒ）－２－硫代四氢噻唑－４－羧酸甲酯，产率为９８％，     

高排架渡槽风振的计算方法

考虑渡槽的流－固耦合效应,导出了结构风振方程,导得了流－固耦合系统的传递函数矩阵的模态展开式,给出了结构风振响应的时域（时程分析）和频域（随机振动）计算公式。通过时程分析与随机风振的数值算例表明,结构风振响应分析一般应同时考虑结构振荡模态与流体振荡模态的贡献,提出的计算方法是可行的,可用于工程设计参考。     

Carbon isotopic record of foraminifers in surface sediments from the South China Sea and its significance

Since the 1990s, the papers and data involved withthe South China Sea (SCS) have been emerging in largenumbers in the world as people pay more attention to thepaleoceanography of the SCS. There have been more than100 cores mentioned in papers containing p…     

The terrestrial NPP simulations in China since Last Glacial Maximum

Based on Atmosphere-Vegetation Interaction Model （AVIM）, the magnitude and spatial distribution of terrestrial net primary productivity （NPP） in China is simulated during three different geological eras, Last Glacial Maximum （LGM）, Mid-Holocene （MH） and the present. The simulation shows that the glacial-interglacial variation of East Asian summer monsoon in China is the key factor affectfng the NPP change. During the three eras, mean NPPs are 208 g/m^2·a, 409 g/m^2·a, and 355 g/m^2·a. The total NPPs are 2.05 Pg/a, 3.89 Pg/a and 3.33 Pg/a, respectively. The terrestrial NPP in China during warm-humid climate is larger than that during cold-arid eras, and the correlation analysis between NPP and climate factors suggests that temperature is the primary factor affecting the terrestrial NPP during 21 kaBP （LGM）, and for 6 kaBP （MH） and the present the primary factor is precipitation.     

Pollen records and time scale for the RM core of the Zoige Basin, northeastern QinghaiTibetan Plateau

A continuous pollen record from the Zoige Basin in the northeastern Qinghai-Tibetan Plateau not only provides information on the vegetation and climate changes during the last two glacial/interglacial cycles, hut also gives proof to establish the time scale of the upper 60 m of the RM core. Subalpine spruce-fir forests colonized the Zoige Basin during the interglacials and interstadials, implying warm and wet climate conditions. Alpine periglacial desert or dry desert may have existed during the penultimate glacial and the last glacial maxima, respectively. Alpine sedge meadow dominated the landscape during MIS 4. The MIS 3 is punctuated by a number of stadials similar to those documented in the Guliya and GISP2 ice cores, as indicated by repeated rise and fall of subalpine spruce-fir forests. Our pollen record reveals a regional climate history similar to those from the neighboring sites, including the Arabian Sea and the Guliya ice core, and thus supports the notion that the Qinghai-Tibetan Plateau acts as an important link between climatic events in the North Atlantic realm and the Asian monsoon domain.     

基于风压线形叠加法张拉膜结构风荷载与风振响应分析

综合分析了几种现有的张拉膜结构风荷载分析的方法,在此基础上提出了用风压线形叠加法进行风荷载计算的新方法,并給出一个工程算例进行了风振响应分析。该方法采用平均风压与脉动风压线性组合叠加的办法,生成风压时程函数,既保证了作用于结构上的风荷载随时间变化,而且还能保证结构所受的力是围绕着静力风压上下波动。这种算法可为膜结构的抗风设计提供参考。     

南半球对流层上层纬向风与东亚夏季风环流

研究了南半球对流层上层纬向风和东亚夏季风在年际变化尺度上的关系, 用150百帕60°S和30°S之间的纬向平均的纬向风差值(ISH)可以很好地代表南半球纬向风的年际变化. 结果发现: ISH和东亚夏季风环流在年际变化尺度上有非常显著的负相关关系. 研究揭示: 从南半球到热带区域的纬向风的径向遥相关型(主体在东半球)可能是这种关系的主要内在原因. 通过这种遥相关型使得风场和气压场发生改变从而影响东亚夏季风环流; 另外, 与ISH相关连的欧亚大陆区的异常遥相关波列也是一个重要的机制. 而且ISH和东亚夏季风环流的关系有同时性, 也有非同时性. 因此这种关系的存在一定意义上也具有预测价值.     

基于小波变换的高空风估计

随着雷达技术的快速发展及对探测要求的逐步提高，用常规方法计算层风将造成信息的浪费，且结果也不能真正代表所测层的风速，在分析了高空探测常规计算层风不足之处的基础上，提出了采用小波变换计算层风的新方法，通过计算机仿真及实际数据的对比分析。证实了所提方法的有效性和可靠性。     

Salen-Co(Ⅲ)手性催化剂的合成与外消旋环氧化合物的水解动力学拆分

将（S，S）－1，2－二苯基乙二胺（DPEDA）与2－羟基－5－甲基－3－叔丁基苯甲醛缩合，得到手性Salen，再与Co络合，氧化后得到Salen-Co（Ⅲ）手性催化剂，用于催化外消旋环氧化合物的水解动力学拆分，得到了光学活性的环氧化合物和二醇，产率较高，对映体过量20.6%-61.6％。     

高层建筑风荷载计算中的基本振型表达式分析

通过对大量实测和计算数据的分析和拟合，得出了合理的高层建筑平动和扭转基本振型解析函数曲线，可为补充和修改我国高层建筑设计规范风荷载条文中的 振型表达式提供参考。同时，实例分析表明，在高层建筑的初步设计阶段，上述振型曲线在风荷载计算中的应用，可以提高计算精度。