苯酚的直接催化羟基化及其产物的气相色谱分析

具有ＭＥＬ拓扑结构的新型钛硅沸石ＴＳ－２，对用Ｈ２Ｏ２直接将苯酚选择性氧化为邻、对苯二酚的反应，表现出优良的催化活性，Ｈ２Ｏ２的选择率和产物所上率都很高。产品混合物的定量分析采用气相色谱法，以ＯＶ－２５为固定液、联苯为内标，得到了令人满意的结果。     

B值随机变量序列部分和的矩的收敛速度

本文讨论2阶一致光滑空间及2型空间中随机变量序列部分和的矩的收敛速度问题,所得定理推广了Chow的结果。     

Monte Carlo散射标记方法在辐射防护设计中的应用

在X射线检查系统中,辐射防护中除了需要重点考虑透射和漏射外,散射的成分也必须考虑,而且散射的影响变得越来越重要,这一点在同方威视的固定式、组合式和车载式系统中都已经得到了体现。针对散射的问题,该文进行了系统的研究,提出了在Monte Carlo计算中采用散射标记方法分析各散射体对于散射的贡献,克服了传统方法无法准确计算某一点的散射剂量率以及各散射体对散射的贡献的局限,并利用实验进行了验证。该文采用的计算工具是Geant4软件包。结果表明,该文提出的方法是可行的,尤其在复杂系统的辐射防护优化设计中具有较好的指导作用。     

Resource Search in Unstructured Peer-to-Peer System Based on Multiple-Tree Overlay Structure

We propose a multiple-tree overlay structure for resource discovery in unstructured P2P systems. Peers that have similar interests or hold similar type of resources will be grouped into a tree-like cluster. We exploit the heterogeneity of peers in each cluster by connecting peers with more capacities closer to the root of the tree. The capacity of a peer can be defined in different ways （e.g. higher network bandwidth, larger disk space, more data items of a certain type etc.） according to different needs of users or applications.     

How do Shp2 mutations that oppositely influence its biochemical activity result in syndromes with overlapping symptoms?

Activating and inactivating mutations of SHP-2 are responsible, respectively, for the Noonan (NS) and the LEOPARD (LS) syndromes. Clinically, these developmental disorders overlap greatly, resulting in the apparent paradox of similar diseases caused by mutations that oppositely influence SHP-2 phosphatase activity. While the mechanisms remain unclear, recent functional analysis of SHP-2, along with the identification of other genes involved in NS and in other related syndromes (neurofibromatosis-1, Costello and cardio-facio-cutaneous syndromes), strongly suggest that Ras/MAPK represents the major signaling pathway deregulated by SHP-2 mutants. We discuss the idea that, with the exception of LS mutations that have been shown to exert a dominant negative effect, all disease-causing mutations involved in Ras/MAPK-mediated signaling, including SHP-2, might lead to enhanced MAPK activation. This suggests that a narrow range of MAPK signaling is required for appropriate development. We also discuss the possibility that LS mutations may not simply exhibit dominant negative activity. Received 30 November 2006; received after revision 8 February 2007; accepted 13 March 2007     

纳米固体超强酸SO42-/ZnO催化合成乙酸异戊酯的研究

本文利用纳米固体超强酸SO4^2-/ZnO催化合成乙酸异戊酯的最佳反应条件,既反应时间2.0h,催化剂用量为酸质量的1.0%,酸醇比为1∶2,验证实验产率为96.7%,且该实验反应时间短,无腐蚀无污染,催化剂可回收可重复利用.     

The Development of Materials for the Production of Hydrogen from Bio-ethanol

1 Results There is an increased interest in the hydrogen production from renewable sources. In this context, recently, numerous studies which use ethanol for hydrogen production have appeared. Ethanol is easily handled, non-toxic, and it can be obtained from biomass. The steam-reforming of bioethanol has been shown to beeffective for hydrogen production:C2H5OH 3 H2O  6 H2 2 CO2. Six moles of hydrogen can be yielded for each mole of ethanol reacted. However, depending on the catalyst used, other und...     

关于2-群的注记

通过对2-群的研究，得到了一类2-群的结构，进而给出了一类无限2-群有无限的阿贝尔子群的例子．     

DEA-based anti-HIV immunotherapy model

Acquiredimmunitydeficiencysyndrome(AIDS)isoneofthemostfataldiseasesthathasspreadacrossthewholeworldsinceitfirstoccurred.Itiscausedbythehumanimmunodeficiencyvirus(HIV)[1].Mostofthechemotherapiesareaimedatkillingorhaltingthepathogen,butanewtreatmentistoreduceviralpopulationandimprovetheimmuneresponse.Thistreatmentcanboosttheimmunesystemandservetohelpthebodyfightinfectiononitsown,soitiscalledantiHIVimmunotherapy[2,3].TheaimofthisworkistofindefficientstrategiesforsuchtreatmentsusingtheDataEnv…     

2,3-二溴甲基-5,6-二氰基吡嗪的合成新方法

以2,3-二甲基-5,6-二氰基吡嗪为原料,在AIBN的引发下,用NBS进行自由基溴化反应,合成了标题产物,其结构经熔点,MS,1HNMR,UV等予以确证,从而为该物质的合成探索了一条新途径.