Preparation of MCM-41-supported chiral Salen Mn （Ⅲ） catalysts and their catalytic properties in the asymmetric epoxidation of olefins

A secondary amino-modified mesoporous molecular sieve MCM-41 was obtained by reaction of bis(3-(triethoxysilyl)propyl)amine with MCM-41. The chiral Salen-Mn (III) complex was anchored onto the modified MCM-41 by a multi-step grafting method and two heterogenized catalysts with different Mn contents were obtained. The catalysts were characterized by XRD, N2 adsorption, ICP, FT-IR and DR UV-Vis. Their catalysis on asymmetric epoxidation of several olefins was studied with NaClO and m-CPBA as oxidants respectively. It was found that both the activity and enantioselectivity of the cata- lysts decreased after the homogeneous catalyst was heterogenized. The reasons resulting in the de- crease of catalytic performance were discussed.     

Mechanism of the interaction between Au nanoparticles and polymerase in nanoparticle PCR

Nanoparticle PCR is a novel method to optimize DNA amplification. It performs well in improving specificity, enhancing sensitivity and speed. Several mechanisms were proposed in previous studies: one was based on the interaction between gold nanoparticles (AuNPs) and DNA while the other was attributed to the heat transfer property of AuNPs. In this paper, we propose that the interaction between AuNPs and DNA polymerase can significantly influence PCR. First, the addition of DNA polymerase can eliminate the inhibitory effects of excess AuNPs. Second, the addition of AuNPs will increase yield of the desired PCR product and make the optimum concentration of DNA polymerase move to higher value. Third, while excess polymerase might inhibit amplification efficiency, AuNPs can reverse this process and the yield of PCR amplification. Based on these results we propose a possible mechanism that AuNPs might modulate the activity of polymerase and improve PCR amplification.     

利用神经网络外推中垂面上低仰角HRTF的方法

为了构建关于仰角方向连续的头相关传输函数(HRTF),提出采用径向基函数神经网络外推中垂面上低仰角方向HRTF的方法.基于KEMAR人工头和真人的数据,对3种不同网络输入方式下外推方法的有效性进行了研究.结果表明:外推值和测量值的相关系数可达0.93;增大网络输入的数据量、减小外推方向和已知方向的空间距离可提高外推的准确性;外推的误差随频率的升高而增大.     

离子强度对牛磺酸离子交换平衡的影响

采用静态吸附法研究离子强度对牛磺酸/OH-体系在阴离子树脂D290上离子交换平衡的影响,测定了不同离子强度下牛磺酸在碱式阴离子交换树脂上的交换平衡等温线.研究结果表明:(1)随着溶液离子强度的升高,阴离子树脂对牛磺酸的平衡交换吸附容量逐渐降低,牛磺酸在树脂上的分配系数λTau逐渐下降;(2)随着溶液离子强度增大,达到平衡时液相的pH值升高,溶液中牛磺酸阴离子Tau±含量迅速增加,而牛磺酸两性离子Tau±含量迅速降低;(3)在一定的牛磺酸浓度范围内,溶液离子强度增大,有利于提高离子交换树脂对牛磺酸的选择性.     

氯丁橡胶/丁基橡胶的成形工艺研究

选用CR1211和IIR1751为生胶原料,以氧化锌/氧化镁和硫磺为硫化体系,二氧化硅和白炭黑为补强剂,经混炼、硫化等加工过程,研究了CR1211和IIR1715并用橡胶的成形工艺。结果表明,当IIR投料顺序在先时,混炼较容易,硫化胶的力学性能优异,稳定性好,当CR1211和IIR1715投料比为1∶1时,硫化橡胶强度和热性能都较好。同时还发现,硫化橡胶强度随硫化温度升高而下降,合适的硫化条件为160℃,10.5 min。     

浅论安源路矿工人运动对井冈山革命斗争的贡献

中国共产党在上世纪二十年代发动和领导的安源路矿工人运动,极大地提高了安源工人的思想觉悟,为此后的井冈山革命斗争打下了坚实的思想政治基础和革命骨干力量储备。经过安源路矿工人运动洗礼的工人及农民,成为井冈山革命斗争源源不竭的力量源泉。     

A new estimator of covariance matrix via partial Iwasawa coordinates

This paper is concerned with the problem of improving the estimator of covariance matrix under Stein’s loss. By the partial Iwasawa coordinates of covariance matrix, the corresponding risk can be split into three parts. One can use the information in the weighted matrix of weighted quadratic loss to improve one part of risk. However, this paper indirectly takes advantage of the information in the sample mean and reuses Iwasawa coordinates to improve the rest of risk. It is worth mentioning that the process above can be repeated. Finally, a Monte Carlo simulation study is carried out to verify the theoretical results.     

Ruin probabilities with pairwise quasi-asymptotically independent and dominatedly-varying tailed claims

This paper considers the nonstandard renewal risk model in which a part of surplus is invested into a Black-Scholes market whose price process is modelled by a geometric Brownian motion, claim sizes form a sequence of not necessarily identically distributed and pairwise quasi-asymptotically independent random variables with dominatedly-varying tails.The authors obtain a weakly asymptotic formula for the finite-time and infinite-time ruin probabilities.In particular,if the claims are identically distributed and consistently-varying tailed,then an asymptotic formula is presented.     

Modeling the congestion cost and vehicle emission within multimodal traffic network under the condition of equilibrium

Traditional system optimization models for traffic network focus on the treatment of congestion, which usually have an objective of minimizing the total travel time.However,the negative externality of congestion,such as environment pollution,is neglected in most cases.Such models fall short in taking Greenhouse Gas(GHG) emissions and its impact on climate change into consideration.In this paper,a social-cost based system optimization(SO) model is proposed for the multimodal traffic network considering both traffic congestion and corresponding vehicle emission.Firstly,a variation inequality model is developed to formulate the equilibrium problem for such network based on the analysis of travelers’ combined choices.Secondly,the computational models of traffic congestion and vehicle emission of whole multimodal network are proposed based on the equilibrium link-flows and the corresponding travel times.A bi-level programming model,in which the social-cost based SO model is treated as the upper-level problem and the combined equilibrium model is processed as the lower-level problem,is then presented with its solution algorithm.Finally,the proposed models are illustrated through a simple numerical example.The study results confirm and support the idea of giving the priority to the development of urban public transport,which is an effective way to achieve a sustainable urban transportation.     

论过渡时期我国的制度建设

过渡时期,我国进行了政治、经济、文化教育等方面的制度建设,建立了人民民主专政制度、人民代表大会制度、中国共产党领导的多党合作和政治协商制度,以及生产资料公有制、按劳分配制度和政治教育制度.这些制度的形成,为社会主义制度在中国的确立和完善打下了基础.