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91.
Zhou Xiaohai Deng Lizhi Wu Xuye Zhang Shaohui Liu Shengquan Huang Suqiu Qu Songsheng 《武汉大学学报:自然科学英文版》1997,2(4):484-488
Thermodynamic data were determined for the reversible binding of O2 to two compounds of dicobalt(II) di(meso-tetra-phenyl)porphyrin derivatives with different lengths of diamidoaliphatic bridge
(abbreviated to Co2PP8 and Co2PP4) in N,N-dimethylformamide at room temperature. The partial pressure of dioxygen necessary for half-oxygenation (P
1/2) and hill coefficient (n) at 298 K were determined as follows:P
1/2=54.2 kPa,n=2.0 for Co2PP8 andP
1/2=6.8 kPa,n=1.8 for Co2PP4, respectively. The rate equations of reversible oxygen binding by Co2PP8 were determined and the reaction path was proposed. The results of ther-modynamic and kinetic studies indicate that there
exists strong cooperative effect during oxygenation of the compounds. The ESR observation reveals that the dioxygen complexes
formed in the solutions are of superoxo (Co-O
2
−
) type.
Supported by the Research Foundation of the State Education Commission of China
Zhou Xiaohai: born in 1962, Ph.D. Associate professor 相似文献
92.
Wang Tianzhi Li Weiping Wu Dingquan Wan Hongwen Yang Feng Qu Songsheng 《武汉大学学报:自然科学英文版》1997,2(4):511-513
The reaction between Laccase ando-methoxyphenol have been studied by LKB-2107 batch microcalorimetry system. Thermodynamic parameters Δ
r
H
m
, ΔG
o
, ΔG
T
≠
and kinetic parameters (K
m
,k
2) have been determined. The process of the reaction has been analyzed from changes in energy by using the transition state
theory. Two methods for enhancing catalytic power of Laccase are proposed. The results shown that formation of an enzyme-substrate
complex is “anticatalytic”. The enter and sole source of catalytic power is the stabilization of transition state; reactant-state
interactions are by nature inhibitory and only waste catalytic power.
Supported by the National Natural Science Foundation of China
Wang Tianzhi: born in 1968. Ph D 相似文献
93.
在SEM和TEM下对Ti33Al3Cr0.5Mo合金全层片组织薄板状和薄膜状试样分别进行了动态拉伸,并原位观察了试样中裂纹的形核及扩展过程.发现裂纹遇到内相界面时会发生偏转或裂尖发生钝化;主裂纹主要以使剪切带断裂而与微裂纹相连接的方式扩展并沿曲折路径进行. 相似文献
94.
分别用射线分析法和电磁场分析法,通过保角变换在直角坐标系下研究ARROW型弯曲波导特性,导出了其模色散方程(本征模方程)。经优化设计的ARROW型弯曲波导结构,使TE0模的损耗降至为0.0329cm^-1。 相似文献
95.
Two structure models for knitting fabric are set up according to the wet-heat transmission principle of the fabric. Four kinds of knitted fabrics for sportswear are designed and produced. The wet-heat property of these fabrics is researched. 相似文献
96.
97.
用高阶曲线有限条法分析混凝土曲线梁桥 总被引:1,自引:1,他引:1
针对工程中提出的曲线梁桥的新课题,为了有效地进行全桥分析,获取设计所需的纵向、横向内力,文章采用高阶有限条法(HighorderFiniteStripMethod)分析等截面曲线梁桥。其形函数用Hermit函数法构造,形式简洁、运用能量原理从基于薄板的几何矩阵和基于线弹性的内力矩阵导出了单元刚度矩阵,采用FORTRAN-77语言完成了编程工作.经过算例比较.说明了高阶曲线有限条法的简洁性和高精度性。 相似文献
98.
一种大容量IGBT的驱动和快速保护方法 总被引:2,自引:0,他引:2
提出的大容量绝缘栅双极型晶体管(IGBT)器件的驱动和快速保护方法能满足各种容量的IGBT器件和功率场效应晶体管(MOSFET)器件对驱动和短路保护的要求。介绍了驱动电路和快速保护电路的原理,及保护电路响应时间的测量方法。给出了在不同基准电压下,模拟不同退饱和的集射电压下的保护响应时间。短路试验证明了保护电路的快速性。此驱动保护电路已用于由50A/600V IGBT模块构成的逆变器和由400A/600V IGBT模块构成的直流斩波器。工业运行结果表明保护方法响应时间快,抗干扰能力强。 相似文献
99.
By using an LKB-2277 bioactivity monitor, we have determined the thermogenesis curves of four kinds of anaerobes linear growth.
From the thermogenesis curves, we established the growth thermokinetic equation: dP/dt=k
m·P
n
, the order of growth metabolismn=0, and calculated the mean specific rate constant of multiplication {ie95-1}. It is a new kind of bacterial growth, it was
compared with exponential growth.
Liu Yi: born Nov. 1970. Ph. D. Curent research interest is in biothermochemistry research
Supported by the National Natural Science Foundation of China 相似文献
100.
By using an LKB-2277 Bioactivity Monitor, the effect of porphyrin-cholesterol esters on cancer cells HL-60 were examined at
25°C. There is a difference in the shape of the thermogenesis curve samong different kinds of porphyrin-cholesterol esters,
and the death rate of HL-60 cells is also different. The results show that porphyrin-chsterol esters can powerfully inhibit
their metabolism, the inhibitory sequence is II>I>III, but the inhibitory way of each ester is different.
Supported by the National Natural Science Foundation of China
Liu Yi: born in Nov. 1970, Ph. D. graduate student 相似文献