The strong cooperativity of dioxygen binding by dicobalt (II) diporphyrin compounds in nonaqueous solution at room temperature

Thermodynamic data were determined for the reversible binding of O₂ to two compounds of dicobalt(II) di(meso-tetra-phenyl)porphyrin derivatives with different lengths of diamidoaliphatic bridge (abbreviated to Co₂PP₈ and Co₂PP₄) in N,N-dimethylformamide at room temperature. The partial pressure of dioxygen necessary for half-oxygenation (P _1/2) and hill coefficient (n) at 298 K were determined as follows:P _1/2=54.2 kPa,n=2.0 for Co₂PP₈ andP _1/2=6.8 kPa,n=1.8 for Co₂PP₄, respectively. The rate equations of reversible oxygen binding by Co₂PP₈ were determined and the reaction path was proposed. The results of ther-modynamic and kinetic studies indicate that there exists strong cooperative effect during oxygenation of the compounds. The ESR observation reveals that the dioxygen complexes formed in the solutions are of superoxo (Co-O ₂ ⁻ ) type. Supported by the Research Foundation of the State Education Commission of China Zhou Xiaohai: born in 1962, Ph.D. Associate professor     

Studies on the reaction between Laccase ando-methoxyphenol by microcalorimetry

The reaction between Laccase ando-methoxyphenol have been studied by LKB-2107 batch microcalorimetry system. Thermodynamic parameters Δ _r H _m , ΔG _o , ΔG _T ^≠ and kinetic parameters (K _m ,k ₂) have been determined. The process of the reaction has been analyzed from changes in energy by using the transition state theory. Two methods for enhancing catalytic power of Laccase are proposed. The results shown that formation of an enzyme-substrate complex is “anticatalytic”. The enter and sole source of catalytic power is the stabilization of transition state; reactant-state interactions are by nature inhibitory and only waste catalytic power. Supported by the National Natural Science Foundation of China Wang Tianzhi: born in 1968. Ph D     

全层片组织 TiAl 基合金室温断裂机理的研究

在ＳＥＭ和ＴＥＭ下对Ｔｉ３３Ａｌ３Ｃｒ０．５Ｍｏ合金全层片组织薄板状和薄膜状试样分别进行了动态拉伸，并原位观察了试样中裂纹的形核及扩展过程．发现裂纹遇到内相界面时会发生偏转或裂尖发生钝化；主裂纹主要以使剪切带断裂而与微裂纹相连接的方式扩展并沿曲折路径进行．     

一种ARROW型弯曲波导研究

分别用射线分析法和电磁场分析法，通过保角变换在直角坐标系下研究ＡＲＲＯＷ型弯曲波导特性，导出了其模色散方程（本征模方程）。经优化设计的ＡＲＲＯＷ型弯曲波导结构，使ＴＥ０模的损耗降至为０．０３２９ｃｍ＾－１。     

RESEARCH ON THE STRUCTURE AND THE PROPERTY OF THE HYGROSCOPIC AND PERMEABLE FABRIC FOR SPORTSWEAR

Two structure models for knitting fabric are set up according to the wet-heat transmission principle of the fabric. Four kinds of knitted fabrics for sportswear are designed and produced. The wet-heat property of these fabrics is researched.     

一致凸线性距离空间的最佳联合逼近性

本文证明了一致凸线性距离空间存在唯一的最佳联合逼近元。     

用高阶曲线有限条法分析混凝土曲线梁桥

针对工程中提出的曲线梁桥的新课题，为了有效地进行全桥分析，获取设计所需的纵向、横向内力，文章采用高阶有限条法（ＨｉｇｈｏｒｄｅｒＦｉｎｉｔｅＳｔｒｉｐＭｅｔｈｏｄ）分析等截面曲线梁桥。其形函数用Ｈｅｒｍｉｔ函数法构造，形式简洁、运用能量原理从基于薄板的几何矩阵和基于线弹性的内力矩阵导出了单元刚度矩阵，采用ＦＯＲＴＲＡＮ－７７语言完成了编程工作．经过算例比较．说明了高阶曲线有限条法的简洁性和高精度性。     

一种大容量IGBT的驱动和快速保护方法

提出的大容量绝缘栅双极型晶体管（ＩＧＢＴ）器件的驱动和快速保护方法能满足各种容量的ＩＧＢＴ器件和功率场效应晶体管（ＭＯＳＦＥＴ）器件对驱动和短路保护的要求。介绍了驱动电路和快速保护电路的原理，及保护电路响应时间的测量方法。给出了在不同基准电压下，模拟不同退饱和的集射电压下的保护响应时间。短路试验证明了保护电路的快速性。此驱动保护电路已用于由５０Ａ／６００Ｖ ＩＧＢＴ模块构成的逆变器和由４００Ａ／６００Ｖ ＩＧＢＴ模块构成的直流斩波器。工业运行结果表明保护方法响应时间快，抗干扰能力强。     

A study of bacterial linear growth using a microcalorimetric method

By using an LKB-2277 bioactivity monitor, we have determined the thermogenesis curves of four kinds of anaerobes linear growth. From the thermogenesis curves, we established the growth thermokinetic equation: dP/dt=k _m·P ⁿ , the order of growth metabolismn=0, and calculated the mean specific rate constant of multiplication {ie95-1}. It is a new kind of bacterial growth, it was compared with exponential growth. Liu Yi: born Nov. 1970. Ph. D. Curent research interest is in biothermochemistry research Supported by the National Natural Science Foundation of China     

Microcalorimetric study of the effect of porphyrin-cholesterol esters on cancer cells HL-60

By using an LKB-2277 Bioactivity Monitor, the effect of porphyrin-cholesterol esters on cancer cells HL-60 were examined at 25°C. There is a difference in the shape of the thermogenesis curve samong different kinds of porphyrin-cholesterol esters, and the death rate of HL-60 cells is also different. The results show that porphyrin-chsterol esters can powerfully inhibit their metabolism, the inhibitory sequence is II>I>III, but the inhibitory way of each ester is different. Supported by the National Natural Science Foundation of China Liu Yi: born in Nov. 1970, Ph. D. graduate student