A wide tuning range electro-optic filter based on long-period waveguide grating

We present the design of an electro-optic filter with polarization insensitivity based on a long period waveguide grating. The filter exhibits an ultra-large wavelength tuning range of exceeding 35 nm and covering the whole C band (1530 to 1565 nm) in a bias voltage range from −84 to 84 V. In the whole tuning range, the transmission coefficients for quasi TE modes are over 97% and the 3 dB bandwidths are below 0.8 nm. The wavelength sensitivity to the tunable voltage is about 0.208 nm/V. This electro-optic filter can be used in dynamic WDM networks for fast wavelength scanning/selection, communication channel reconfiguration, and optical switching.     

Advances in the synthesis and reactivity of 2-pyranylidene carbene complexes

Pyranylidene carbene complexes bearing a pyran ring carbene ligand represent a unique kind of organometallic species due to their special structures and reactivity. In this review, we present a comprehensive summary on the synthesis and reactivity of pyranylidene carbene complexes during the past four decades.     

Near-field coupling and SERS effects of palladium nanoparticle dimers

The linear optical properties and the surface-enhanced Raman scattering (SERS) effect of spherical palladium nanoparticle dimers are analyzed theoretically using generalized Mie theory. The calculation results demonstrate that the near-field coupling effect greatly influences the absorption, scattering and extinction spectra of nanoparticle dimers. The surface plasmon resonance wavelength red-shifts dramatically as the separation between nanoparticles decreases. Because of the near-field coupling between nanoparticles and the size effect, the maximum SERS enhancement factor at the ‘hot spot’ between palladium nanoparticle dimers is as high as 10⁷–10⁸, while the averaged SERS enhancement factor over the entire nanoparticle surface is in the range of 10⁵–10⁶. The deviation between the position of the peak in the extinction spectrum and the wavelength for maximum surface-averaged enhancement for the Pd nanoparticle dimers indicates that localized surface plasmon resonance has different influences on the far and near fields. These theoretical results may help to reveal the relationship between the far and near fields, as well as understand the mechanism of electromagnetic enhancement in the surface-enhanced scattering of transition metals.     

Topological analysis of methane lean premixed flame in turbulent jet flow by direct numerical simulation

Direct numerical simulation is employed to investigate the premixed jet flame of methane in lean, combined with a detailed chemical kinetics including 17 species and 58 elemental steps and distinct Lewis numbers. Cold methane-air mixture at 0.55 equivalence ratio is injected into the coflow area with 9500 Reynolds number. The coflow ambient gas is set to be the burnt gas of the methane-air mixture in main jet and temperature is assigned to be the corresponding adiabatic flame temperature 1515 K. The whole s...     

Temperature variability since A.D. 1837 inferred from tree-ring maximum density of <Emphasis Type="Italic">Abies fabri</Emphasis> on Gongga Mountain,China

Two tree-ring MXD (maximum latewood density) chronologies of Abies fabri were developed from the eastern slopes of Gongga Mountain, and a regional chronology (RC) was established based on the two MXD chronologies. There were significant positive correlations between the three MXD chronologies and August–September temperature, and the RC had the highest correlation (r=0.733, n=48, P<0.001) with mean August–September temperature. Based on growth-climate analyses, we reconstructed mean August–September temperature during the past 171 years for the study area. The reconstruction explained 53.5% of the instrumental temperature variance during the period 1960–2007 (F=52.8, R²_adj =52.4%). In the past 171 years, there were 22 very warm years and 23 very cold years, four cold periods (1837–1842, 1884–1891, 1899–1905 and 1984–1989) and three warm periods (1966–1973, 1916–1924 and 1876–1881). Our reconstruction was validated by other tree ring-based temperature reconstructions from the surrounding area and documented climate disaster events.     

Determination of the controlled landing trajectory of Chang’E-1 satellite and the coordinate analysis of the landing point on the Moon

Based on the tracking observations of radio ranges and VLBI delays of Chang’E-1 (CE-1) satellite during the controlled landing on the Moon on March 1, 2009, the landing trajectory and the coordinates of the landing point are determined by positioning analysis. It is shown that the landing epoch (the emission epoch of the last signal) of CE-1 satellite on the Moon was at UTC8h13m6.51s. The lunar longitude, latitude and surface height of the landing point in the lunar primary axes frame are respectively 52.27...     

Indoor SVOC pollution in China: A review

Epidemiological and toxicological studies have proved that semi-volatile organic compounds (SVOCs) may have significant adverse effects on human health.For example,phthalic acid esters (PAEs),polybrominated diphenyl ethers (PBDEs) and polycyclic aromatic hydrocarbons (PAHs) may harm the endocrine,reproductive and respiratory systems of humans.Moreover,some SVOCs are carcinogenic.This paper summarizes the source emission characteristics for typical SVOCs observed indoors,evaluates the gas-phase and particle-...     

Locomotion behavior and dynamics of geckos freely moving on the ceiling

To understand the mechanical interactions when geckos move on ceiling and to obtain an inspiration on the controlling strategy of gecko-like robot, we measured the ceiling reaction force (CRF) of freely moving geckos on ceiling substrate by a 3-dimensional force measuring array and simultaneously recorded the locomotion behaviors by a high speed camera. CRF and the preload force (F_P) generated by the geckos were obtained and the functions and the differences between forces generated by fore- and hind- feet were discussed. The results showed that the speed of gecko moving on the ceiling was 0.17–0.48 m/s, all of the fore- and hind-legs pulled toward the body center. When geckos attached on the ceiling incipiently, the feet generated a very small incipient F_P and this fine F_P could bring about enough adhesive normal force and tangential force to make the gecko moving on ceiling safely .The F_P of the fore-feet is larger than that of the hind-feet. The lateral CRF of the fore-feet is almost the same as that of the hind-feet’s. The fore-aft CRF generated by the fore-feet directed to the motion direction and drove their locomotion, but the force generated by the hind-feet directed against the motion direction. The normal CRF of fore- and hind-feet accounted for 73.4% and 60.6% of the body weight respectively. Measurements show that the fore-aft CRF is obviously lager than the lateral and normal CRF and plays a major role in promoting the fore-feet, while the hind-feet of the main role are to provide a smooth movement. The results indicate that due to the differences of the locomotion function of each foot between different surfaces, the gecko can freely move on ceiling surfaces, which inspires the structure designing, gait planning and control developing for gecko-like robot.     

Investigation on the mechanism of convective heat and mass transfer with double diffusive effect inside a complex porous medium using lattice Boltzmann method

A new lattice Boltzmann model is proposed for the coupling of multi-physics in natural convection by introducing another distri-bution function to represent the scalar transport of mass and an additional source term on the right hand side of the lattice Boltzmann equation (LBE) based on the TD2G9 model. According to the Boussinesq assumption and considering the coupled diffusive effect, the governing equations for the coupling of multi-physics in natural convection is proposed based on the non-equilibrium thermodynamic theory. Combined with the algorithm for the reconstruction of a porous medium, this model is used to investigate the coupled heat and mass transfer under multi-physics of natural convection inside a porous medium at the pore scale. The characteristic of profiles of dimensionless velocity, temperature and concentration are shown graphically for different values of Rayleigh number (Ra) and porosity. Furthermore, the influence of the temperature gradient on the mass transfer inside a porous medium has been examined numerically. Thus, the mechanism of the coupled heat and mass transfer inside a porous medium is investigated numerically at the pore scale innovatively.     

Qualitative and quantitative relationships between affinity constants from model study and real adsorption data

Linear polymers bearing the same functional groups as their corresponding adsorbents could be used as models to study the ad-sorption behaviors. However, the relationships between the data from model study and real adsorption have not been fully interpreted. In this work, three adsorbent (CP1-Zn²⁺, CP2-Zn²⁺ and CP3-Zn²⁺) and their corresponding linear models (P1-Zn²⁺, P2-Zn²⁺ and P3-Zn²⁺) were synthesized. The affinity constants (Ka) between these models and target peptide DFLAE (DE5) were obtained by isothermal titration calorimetry (ITC). Adsorption capacities and adsorption affinities were carried out by static adsorption and adsorption isotherm. The qualitative and quantitative relationships between affinity constants from model study and the real ad-sorption data were explored. This study was significant to bridge the model study with the real adsorption.