M_2Cl_4(PH_3)_4(M=Cr、Mo、W)分子的DFT计算

采用密度泛函理论(DFT)研究M_2Cl_4(PH_3)_4(M=Cr、Mo、W)分子,在D_(2d)对称约束下进行结构优化和能量解析,三种化合物的M—M键长分别是C—Cr1.737A,Mo—Mo2.157A,W—W2.286A.能量解析表明:E_(Cr—Cr)相似文献   

Automatic evolutionary modeling by the Lattice-Boltzmann method

The Lattice-Boltzmann method is an effective tool for solving fluid mechanics problems, but there isn’t still a good scheme to determinate some parameters in Boltzmann equations. In this paper, a technique using evolutionary algorithm to automatically model Boltzmann equations is introduced. Numerical simulation shows that the designed scheme is fast and efficient. Biography: Chen Ju-hua ( 1963-), male, Associate professor, research direction: Lattice-Boltzmann method, evolutionary algorithm.     

Stress corrosion cracking and its anisotropy of a PZT ferroelectric ceramics

It is known that some types of ceramics, like Al2O3 and ZrO2, undergo stress corrosion cracking (SCC) or static fatigue fracture under static loading, ever in a rela-tively mild environment, such as moist atmosphere or water at room temperature, which leads to a time-dependent fracture[1—4]. For a transmission electron microscopy specimen of YBa2Cu3O7-x ceramics superconductor, SCC induced by residual stress can occur in an atmosphere with low moisture content[5]. For a lead zirconate ti…     

Do multiple cycles of aeolian deposit-pedogenesis exist in the reticulate red clay sections in southern China?

Since the Quaternary scientists successfully dis-closed the paleoclimatic significance of the loess-paleo- sol sequence in the Loess Plateau, Northwest China, the loess-paleosol sequence has become well-known terres-trial materials revealing the multiple cyclic changes of Quaternary climates. As a carrier of paleoenvironmental information, it could compare beauty with the deep ocean deposit[8]. In recent years, however, the researchers began to put their sights to southern China. They try t…     

The age of formation of the mirabilite and sand wedges in the Hexi Corridor and their paleoclimatic interpretation

The Hexi Corridor is located at the transition zone of the Asian summer monsoon and westerly airflow, and lies in an important position in terms of its ecological fragility and climatic sensitivity. During a recent field expedition to this region, we found a sedimentary mirabilite layer in a number of localities including Suwushan, Yanchi, Baitujing, Yanchi Gaotai, Huahai, Yumen, Halanuo扙r, and Dunhuang (Fig. 1), which have the potential to provide important information about environmenta…     

Temperature variations on the Tibetan Plateau over the last two millennia

The paleoclimate data recovered from ice cores,tree rings and lake sediments indicate regional features of cfimatic change on the Tibeta n Plateau (TP) during the last 2000 years. The composite temperature reconstructions in-dicate that several main climatic episodes, such as the “LittleIce Age“ between 1400 and 1900, the “Medieval Warm Pe-riod“ in 1150-1400, a less warm period in 800-1100, and an earlier cold period between the 3rd and 5th centuries,occurred in the TP. In addition, temperature varied from region to region. The period from AD 800 to 1100, which waswarm in northeastern TP, was contemporaneous with cool-ing in the western and southern TP. The southern TP ex-perienced warming between 1150 and 1400. For western TP,the δ^18O records of the Guliya ice core indicate that the pe-Hod 1250-1500 witnessed a clear warming. Large-scaletrends in the temperature history from northeastern TP aremore similar to those in eastern China than are the trendsfrom the Guliya ice cap far to the west and southern TP. The most prominent similarities between the temperature varia-tions of the TP and eastern China are such cold phases as 1100-1150, 1500-1550, 1650-1700 and 1800-1850, andthe latter three cold events match with three widespreadg lacial advances which occurred on the TP during the Little Ice A2e.     

Time-division phase modulated single-photon interference in a Sagnac interferometer

We introduce a stable, long-distance singlephoton Sagnac interferometer, which has a balanced configuration to efficiently compensate phase drift caused by change of the fiber-optic path. By using time-division phase modulation, single-photon interference was realized at 1550nm in a 5-km-long as well as 27-km-long Sagnac fiber loops,with a fringe visibility higher than 90% and long-term stability. The stable performance of the single-photon interference indicated that the time-division phase-modulated Sagnac interferometer might readily lead to practical applications in single-photon routing and quantum cryptography.     

Expression of human clotting factor Ⅸ mediated by recom- binant lentiviral vector in cultured cells and hemophilia B mice

To explore the expression of human clotting factor Ⅸ (hFⅨ) cDNA in vitro and the feasibility of gene therapy for hemophilia B mice mediated by recombinant lentiviral vector, a recombinant hFⅨ lentiviral vector driven by ubiquitin-C promoter, FUXW, and by ABP liver specific promoter, FAXW, was constructed respectively. Recombinant lentivirus was harvested from 293T cells by calcium phosphate-mediated transient cotransfection of three plasmids (transgene vector, CMV腞8.2, VSV-G). hFⅨ expression was detected in supernatant of 293T, BHK and L-02 cells infected with FUXW virus, whereas higher expression of hFⅨ levels (630 ng/106 cells/48 h) was detected only in L-02 cells infected with FAXW virus. Serum hFⅨ antigen was detected in all hemophilia B mice treated with FAXW virus by tail vein injection, an efficiency level of hFⅨ was observed (45 ng/mL, approximately 1% of normal human levels), the expression lasted for more than 60 d. The results indicated that HIV-based lentiviral vectors offer a promising approach to the gene therapy of hemophilia B.     

尕斯油田N_2~1油藏南区储层非均质性研究

针对尕斯油田N21油藏南区储层非均质性严重的特点,从层间、层内及平面非均质性3个方面进行了系统研究.层间非均质性相对较弱,层间隔层分布较为稳定,各油组砂层发育情况差别不大.层内非均质性较强,并且与沉积微相密切相关.单砂层垂向上渗透率的变化以正韵律和复合韵律模式为主,局部发育反韵律模式.按照非均质性的强弱,沉积微相依次为:分流河道、河口砂坝、分流间湾、远砂坝.统计了平面上不同微相砂体的几何形状,并且采用流动单元法综合评价储层的平面展布特征.