铜离子金属胶束介质中PNPA水解的动力学研究

研究了25℃时，铜离子与二胺类配体DMEA和DMPA(DMEA为N，N－二甲基乙二胺，DMPA为N，N－二甲基－1,3－丙二胺)形成的配合物对PNPA(对硝基苯酚乙酸酯)催化水解的动力学，并通过了胶束催化的二元复合物动力学模型对其进行定量处理，结果表明，铜离子与不同的二胺类配体形成的配合物在CTAB胱束溶液中对PNPA的催化水解表现出不同的催化效果，而催化的机理则可能是由于与铜离子配位的水分子去质子化以后形成的亲核体对PNPA进行亲核进攻的结果。     

SPN结构线性层的设计

SPN结构是一种流行的分组密码总体结构；差分和线性分析是攻击分组密码的最强有力的方法．章介绍了SPN结构研究的最新进展，着重论述如何用矩阵方法设计抗差分和线性分析的线性层．     

攀枝花地区昔格达土中钒的含量及分布

对母质为昔格达组粘土的攀枝花土壤样品数据进行了分析研究。结果表明，该区土壤中的钒普遍具有一定的地带性分布规律及剖面分布特征。一般来说，矿区土壤中的钒含量明显高于非矿区，表明该区土壤主要受采矿污染的影响；水田土壤中钒含量明显高于旱地，表明水是钒元素迁移的重要介质（载体）。钒含量在土壤剖面上的空间分布呈底层富集型，反映了成土因素的综合影响。     

准噶尔盆地南缘西部地区原油地球化学特征及油源对比

对准噶尔盆地南缘南西部地区各钻井的原油、地面油气苗、以及油砂样品进行分析化验，从其物理性质、轻烃特征、碳同位素以及生物标志物等地球化学特征进行了详尽的分析，进而通过原油及油砂、烃源岩在物理性质、轻烃特征、碳同位素以及生物标志物和成熟度等方面进行了系统的对比分析。认为准噶尔盆地南缘西部地区第三系—白垩系原油更可能是侏罗系煤系烃源岩生成的油与二叠系湖相烃源岩生成的油通过断裂或各种裂隙向上运移混合的结果。     

监控量测技术在通渝隧道出口段中的应用

重庆通渝隧道是“八小时重庆”工程的控制性工程，地质条件复杂，集涌水、岩爆、瓦斯、有害气体、塑性变形、高应力于一身，是典型的复杂条件下的长大公路隧道。在施工过程中，严格进行了新奥法监控量测指导施工，通过开挖面地质素描、拱顶下沉、水平收敛、锚杆轴向力、喷层应力、格栅拱架压力、围岩内变形、二衬应力等多项涉及围岩稳定性及支护合理与否的参数的跟踪量测，并及时将量测数据的散点、回归图等处理信息反馈给施工，以了解隧道开挖后围岩的稳定情况及采取相应的支护措施，实践证明效果可靠，隧道出口段掘进已突破l500m大关。     

一种还原糖自动检测系统

根据生化反应的基本原理,利用MCS-51单片机开发设计了一种还原糖自动检测系统.介绍了该系统的硬件和软件设计模式,其特点是结构简单、操作方便,是还原糖检测的一种新方法.     

Initial organic geochemical investigation on Late Neoproterozoic-Early Cambrian sediments in the Yangtze region, China

Totally 19 samples of typical Upper Proterozoic-Lower Cambrian sedimentary rocks were collected and analyzed for an organic geochemical investigation. Almost all these rocks have high TOCs, super-maturities and similar biomarker distribution. As an exception, however, the Sinian Nantuo Tillite shows much lower TOCs and little phytane and pristane in comparison with those in other strata, which implies a very faint photosynthetic process, and a restricted euphotic zone and quite limited sunlight within the sedimentary water column during the Sinian glaciation age in the western Yangtze region providing an evidence for palaeo-oceanic environment of the Neoproterozoic Snowball Earth age.     

从果子狸谈起——从SARS的流行省思人与自然的关系

果子狸是SARS病毒的宿主之一 ,野生动物是人类SARS的毒源。人工驯养野生动物 ,让人造的化学成分进入了大自然本来的生物过程 ,其产生的危害给世人带来了生态性的灾难。人类要善待自然 ,慎用科技 ,让人的自然体在大自然中正常生息才能达致人与自然的和谐。     

Dependence of mutual information of big protein sequence

The mutual information function is used to describe the auto-correlation of amino acids in protein. We find two interesting phenomenon: (1) for any given big protein, the mutual information function l(k) is almost a const, where k is the length of gap. (2) for any two sequence similar proteins, the mutual information are nearly the same. As a consequent, we may use mutual information of protein as a character for sequences comparison. Foundation item: Supported by the National Natural Science Foundation of China (30170214) Biography: Shi Feng ( 1966-), male, Ph. D, Associate professor, research direction: bioinformatics.     

Combustion energies and standard molar enthalpies of formation for the complexes of the first-row transitional metal chlorides withL-α-histidine

Seven novel solid complexes of the first-row transitional metal with L-α-histidine were synthesized, and their compositions were determined. The constant-volume combustion energies of the complexes were measured by a precision rotation bomb calorimeter. The standard molar enthalpies of combustion and the standard molar enthalpies of formation were calculated. The results indicated that the plots of the standard enthalpies of formation against the atomic number of the metal show a regularity of zigzag.