一维核废料污染问题的一个二阶格式

利用降价法研究了多孔介质中一维核废料污染问题，此模型由一非线性抛物－椭圆耦合偏微分方程组的初边值问题来描述，对此问题给出了一个关于时间和空间均具有二阶精度的差分格式，并进行了理论分析。     

Synthesis and Properties of Novel Copolymers Based on Fluorene and Thiophene

1 Results In this contribution we present the synthesis and characterization of novel copolymers based on fluorene and thiophene (see Scheme 1).They were synthesized by the Pd-catalyzed Suzuki coupling reaction of 9,9-dihexylfluorene-2,7-diboronic acid bis(1,3-propanediol) ester and 3-substituted (R=3-methylbutyl,hexyl,2-(pyren-1-yl)vinyl) 2,5-dibromothiophenes and characterized by GPC,IR and NMR techniques.UV-vis absorption,photoluminescence (PL) and electrochemical behavior of these polymers were also...     

固定床电化学反应器模型数值求解方法

文中给出描述固定床电化学反应器内两维电势和浓度分布的普遍化数学模型。该模型为具有混和边界条件的抛物线及椭园微分方程组。作者开发一种新的具有正交配置及有限差分二法优点的数值计算方法,求得了这组非线性偏微分方程的解。文中给出该数值方法的细节及计算程序框图。     

结构动力分析中Kuhar方法的改进和收敛性

本文介绍了结构动力分析中基于Ｋｕｈａｒ方法的动力缩减迭代法，应用矩阵摄动理论证明了其收敛性，算例说明了方法的有效性     

Zn^2＋在电解还原铕（Ⅲ）过程中的催化行为研究

本文报道微量Zn~(2+)在电解还原铕(Ⅲ)离子过程中的催化作用,研究结果表明:当阴极中含Zn~(2+)时,铕(Ⅲ)离子将缩短到达定量还原的时间,用循环伏安法监控电极过程的结果表明:电极过程是准一级的催化过程。     

pH、温度和浓度对苯酚在V掺杂MoOx-C/Ti电极上的电催化氧化的影响

采用溶胶-凝胶法合成MoOx、MoOx-V5 (x%)胶体,通过Vulcan XC-72炭黑负载制备炭载钼系氧化物电催化剂.利用循环伏安法(CV)测试手段研究苯酚在电极上的氧化降解,考察了掺杂元素、溶液pH值、苯酚浓度、扫描速率、温度对苯酚氧化性能的影响.测试结果表明:苯酚在电极上的氧化是受扩散和电子转移联合控制的复杂过程;掺杂过渡金属元素V可以降低苯酚氧化的表观活化能,提高电化学性能;溶液的pH值越低,MoOx-C/Ti电极对苯酚的催化氧化活性越高;pH在0～6,苯酚的氧化经历了相似的历程,包含了相同的电子数和质子数;苯酚氧化峰电流随着浓度、温度的增加而增加,到一定程度后趋于稳定.     

Elaboration and Properties of Nanocomposite Structures Based on Crown Modified Platinum Nanoparticles

1 Results This paper presents the development of platinum nanocomposites structures based on organically modified c.a.2 nm core platinum nanoparticles.The chemical modification of the 4-mercaptoaniline functionalized particles by various in coming molecules is evidenced and precisely quantified.The particles can be dissolved like molecules in various solvents depending on the features of the new crown and X-rays shows that the interparticle distance is affected by the crown modification.These platinum n...     

Electrochemical Preparation of WO_3 Nanowire Arrays

1 Results Ordered WO3 nanowires arrays have been fabricated by electrochemical deposition with anodic aluminum oxide (AAO) templates and annealing the W nanowire arrays in air at 400 ℃. The morphology and the chemical composition of WO3 nanowires arrays were characterized by Scanning Electron Microscopy (SEM),Transmission Electron Microscopy (TEM), X-ray Photoelectron Spectroscopy (XPS), and X-ray diffraction (XRD). The results show that the diameters of the WO3 nanowires are about 90 nm, which is in go...     

某库岸滑坡稳定分析及治理措施研究

从地质条件出发,详细分析了滑坡的成因,以大型的岩土工程数值分析软件(ADINA)为研究手段,建立有限元计算模型,用强度折减的方法分析了滑坡体在初始工况、蓄水工况、暴雨工况、水位骤降工况和地震工况下的稳定情况,根据滑坡的失稳情况,在综合考虑的基础上,提出了削坡减载和地表排水相结合的治理措施,计算结果表明,治理措施是可行的,研究结果对设计和施工具有较大的参考价值.