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1.
从烧结过程燃料用量、混合料水分、烧结矿碱度及混合料含硫量研究烧结工艺参数对烧结烟气中SO2排放的影响,发现烧结过程SO2的排放不受烧结工艺参数及原料含硫变化的影响,在烧结终点前始终存在一个排放浓度峰值区间,揭示烧结烟气SO2排放的自持性规律是由于烧结料层有选择性吸附SO2作用所导致,SO2的排放遵循硫化物、硫酸盐热分解生成-料层吸附-再分解-解吸的迁移及循环富集排放机理。  相似文献   

2.
唐勇  闫海青  李华杰 《科技资讯》2012,(14):106-106
在烧结过程中由于燃料的燃烧产生大量的氮氧化物,通过改变燃烧条件可以控制NOx的生成,这种技术称为低NOx燃烧技术;但这种技术NOx降低率不高,一般不超过75%,要进一步降低NOx的排放,就必须采用烟气脱硝技术。通过多种脱硝技术的比较,本文分别从反应机理、反应过程、反应使用的催化剂及还原剂、影响因素等几个方面重点分析了比较成熟的SCR(选择性催化还原)技术。  相似文献   

3.
通过烧结杯试验对2种木炭、1种固体成型锯末替代焦粉进行研究。研究结果表明:随着生物质燃料替代焦粉质量分数的提高,烧结适宜水分呈增加趋势,且生物质燃烧速度快使垂直烧结速度提高,而料层最高温度降低使烧结矿熔融区铁酸钙质量分数减小,大孔薄壁结构增加,造成烧结矿成品率和转鼓强度降低;当此3种生物质燃料分别替代质量分数为40%的焦粉进行烧结时,烧结速度均升高,但烧结矿成品率和转鼓强度降低,且生物质的燃料比(即固定碳与挥发分的质量比)越低,其替代焦粉的适宜质量分数也越低,经过炭化的生物质能获得更好的烧结指标;通过降低生物质燃料的热量置换比以及适当提高生物质的平均粒径,提高了料层的最高温度,从而强化生物质燃料的铁矿烧结,提高了烧结矿产量和质量。  相似文献   

4.
提出了一个基于熔融盐循环热载体的无烟燃烧技术,即把一个燃烧过程分为氧化剂生成和燃料燃烧两个步骤进行,燃烧过程能使助燃空气中的N2和燃烧产生的CO2在一套反应装置中进行分离,得到较高纯度的N2和CO2,N2可回收利用,CO2则可捕集起来安全封存。整个燃烧过程避免了向大气排放有害气体;以CuO为催化剂,对CH4在Li2CO3-K2CO3-Na2SO4熔盐体系中的熔融燃烧过程进行的试验研究结果表明,CH4能在该熔融盐体系中能完成无烟燃烧过程并放出热,失去晶格氧的CuO能与空气反应重新恢复其晶格氧,气相色谱分析结果显示,理想的反应条件下, 得到的N2的纯度为99.3%以上,CO2的纯度为95.1%以上。  相似文献   

5.
因燃烧化石燃料而排放的温室气体所导致的环境问题已经成为全球性问题。在这些温室气体中,CO2所占的比例最高。与此同时,CO2在化学工业中有很大的用途。因此,从烟气中分离CO2并将其资源化利用具有十分重要的意义。本文从燃料的前期处理、CO2的分离和捕集、后期封存及其资源化利用三个方面介绍了CO2减排及其资源化利用的途径和方法,并对各减排方法进行了分析和比较,总结了各方法的优劣性及其适用范围,对CO2减排技术的发展前景和面临的挑战进行了展望。  相似文献   

6.
O2/CO2气氛下燃煤过程中NOx排放特性实验研究   总被引:2,自引:2,他引:2  
利用沉降炉在O2/CO2和O2/N2气氛下对煤粉燃烧过程中NOx排放特性进行实验,研究了不同停留时间、燃料/氧化学当量比、温度等因素对燃煤过程中NOx的排放特性的影响,并对2种燃烧方式下NOx的排放特性进行对比.结果表明:在O2/CO2气氛下NOx的生成量远远低于空气气氛下NOx的生成量,其主要原因是在O2/CO2气氛中高CO2质量浓度导致气氛中生成较高含量的CO,从而在未燃烧碳表面发生NO/CO/Char的反应,促进了NO还原为N2;O2/CO2气氛中没有N2,避免了热力型NOx和快速型NOx的生成;约80%的再循环烟气致使NOx的停留时间大为增加,即延长了NOx的还原反应时间,从而降低了NOx的排放.  相似文献   

7.
不同料层高度烧结过程尾气排放规律   总被引:2,自引:0,他引:2  
研究了不同料层高度下烧结过程中尾气成分(O2、CO2、SO2和NO)的变化规律.结果表明:随着烧结历程的推进,尾气中O2含量降低而CO2含量升高,这主要是因为固体燃料燃烧量逐渐增多;尾气中SO2、NO的含量亦呈升高趋势,但幅度很小,这主要是因为烧结料层对SO2有吸收作用,而燃烧带的CO气体则可以还原使部分NO分解;在临近烧结终点时,因料层对SO2的吸收作用消失而使析出作用强化,导致尾气中SO2含量急剧升高.另外,随着料层高度的增加,因固体燃料配比相应减小,尾气中CO2、SO2和NO的含量降低,而O2含量增加.因此,控制高温区宽度的厚料层烧结技术是我国开展减少烧结尾气中气体污染物(CO2、SO2和NO)的有效措施.  相似文献   

8.
提出将氧燃料燃烧方式用于油田注汽锅炉捕集CO2,并将产品资源化利用的多联产工艺实现有效驱油的同时封存CO2,减少污染物排放。以额定蒸汽量15 t/h的油田注汽锅炉为研究对象,分析采用氧燃料燃烧多联产工艺捕集CO2的可行性。结果表明:该工艺采用深冷空分制氧产生的N2可以在油田大量应用,O2和富含CO2的循环烟气作为燃烧的氧化剂,液氮、液氧和液氩作为副产品售出,锅炉尾部烟气中CO2得到富集,通过较小代价的压缩冷凝即可得到99%的液态CO2,同时可以进行SO2和NOx的回收利用。另外,该工艺具有很好的环境效益和经济效益。  相似文献   

9.
氨法脱除烟气中气态污染物的应用分析   总被引:2,自引:0,他引:2  
降低工业生产过程中污染物的排放,是实现清洁生产即可持续发展的基本需要.化石燃料的直接燃烧是气态污染物(NOX、SO2、CO2)和可吸入细颗粒物等污染物的主要排放源.本文对使用氨(NH3)脱除烟气中气态污染物的技术进行了分析和总结,并对其应用于脱除燃煤电站锅炉烟气中气态污染物的前景进行了分析和预测.使用氨洗涤法洗涤净化烟气所得副产品可用于农业生产,或气体回收利用,进而可以实现能源生产过程污染物的近零排放.  相似文献   

10.
在烧结烟气脱硫治理取得成效之后,烟气脱硝迅即摆上钢铁企业的环保治理议程.在尚无经济有效的末端治理脱硝工艺的前提下,有必要在烧结生产中进行工序过程控制,从而保持烧结烟气NOx排放质量浓度处于较低水平.本文通过统计解析的研究方法,系统分析了2013至2014年宝钢实际烧结过程中原燃料条件参数、工艺条件参数对烟气中NOx排放质量浓度的影响规律.研究结果表明:适当降低赤铁矿的使用比例,提高烧结粉、返矿的配比,提高钙质熔剂中石灰石的使用比例,降低镁质熔剂使用比例,保持烧结矿较高的碱度水平,强化制粒提高料层透气性,坚持厚料层烧结等措施均有利于抑制烧结烟气NOx的排放质量浓度水平.  相似文献   

11.
A new process called’NOx reduction by coupling combustion with recycling flue gas(RCCRF)’was proposed to decrease NOx emission during the iron ore sintering process.The simulation test of NOx reduction was performed over sintered ore and in the process of coke combustion.Experimentally,NOx reduction was also carried out by sintering pot test.For sintered ore,the amount of NOx emission is reduced by 15wt%-25wt% at 400-550oC using 2.0vol% H2 or 2.0vol% CO,or reduced by 10wt%-30wt% at 560-720oC using 0.15vol% NH3.NOx reduction is around 10wt% by coupling combustion of pyrolysis gas and coke,or around 16wt% by recycling flue gas into coke combustion.By RCCRF,the maximum NOx reduction ratio is about 23wt% in coke combustion experiment and over 40wt% in sintering pot test.  相似文献   

12.
A new process called ‘NO x reduction by coupling combustion with recycling flue gas (RCCRF)’ was proposed to decrease NO x emission during the iron ore sintering process. The simulation test of NO x reduction was performed over sintered ore and in the process of coke combustion. Experimentally, NO x reduction was also carried out by sintering pot test. For sintered ore, the amount of NO x emission is reduced by 15wt%–25wt% at 400–550°C using 2.0vol% H2 or 2.0vol% CO, or reduced by 10wt%–30wt% at 560–720°C using 0.15vol% NH3. NO x reduction is around 10wt% by coupling combustion of pyrolysis gas and coke, or around 16wt% by recycling flue gas into coke combustion. By RCCRF, the maximum NO x reduction ratio is about 23wt% in coke combustion experiment and over 40wt% in sintering pot test.  相似文献   

13.
The iron ore sintering process is the main source of SO2 emissions in the iron and steel industry. In our previous research, we proposed a novel technology for reducing SO2 emissions in the flue gas in the iron ore sintering process by adding urea at a given distance from the sintering grate bar. In this paper, a pilot-scale experiment was carried out in a commercial sintering plant. The results showed that, compared to the SO2 concentration in flue gas without urea addition, the SO2 concentration decreased substantially from 694.2 to 108.0 mg/m3 when 0.10wt% urea was added. NH3 decomposed by urea reacted with SO2 to produce (NH4)2SO4, decreasing the SO2 concentration in the flue gas.  相似文献   

14.
采用焦炉煤气和水蒸气作为氢系喷吹介质,研究了喷吹介质、喷吹方式、气体喷吹量等因素对烧结过程典型污染物释放规律的影响.结果表明,氢系气体喷吹使烧结料层温度分布明显改善,1200~1300℃的高温区间明显拓宽;喷吹0.6%(体积分数)的焦炉煤气后,烟气中的NOx峰值质量浓度最高降低了约100mg/m3,平均质量浓度降低21.1%,这主要是由于燃气喷吹拓宽了有利于复合铁酸钙生成的温度区间,而蒸汽喷吹对CO的减排有明显效果.蒸汽喷吹后水蒸气与烧结原料中的碳发生水煤气反应,烧结烟气中的CO从11690mg/m3最低降至9918mg/m3,降幅达29.4%;烧结料表面同时喷吹焦炉煤气和水蒸气可以实现NOx和CO的综合减排.  相似文献   

15.
A new process, NOx reduction with recycling flue gas and modifying coke breeze, was proposed. The effects of modified coke breeze and recycled flue gas on NOx reduction were investigated by sinter pot tests. The results show that the NOx reduction rate is over 10wt% in the sintering of modified coke breeze, the effects of the additives on NOx reduction are: CeO2>CaO>K2CO3. The NOx reduction rate increases with the amount of recycled flue gas, and is 22.35wt% in the sintering with recycling 30vol% of the flue gas. When 30vol% of the flue gas is recycled into the sintering of CeO2, CaO, and K2CO3 modified coke breeze, the NOx reduction rates are 36.10wt%, 32.56wt%, and 32.17wt%, respectively.  相似文献   

16.
Reducing NO_x emission of iron ore sintering process in a cost effective manner is a challenge for the iron and steel industry at present. Effects of the proportion of mill scale and coke breeze on the NO_x emission, strength of sinter, and sinter indexes were studied by combustion and sinter pot tests. Results showed that the peak value of NO concentration, total of NO emission, and fuel-N conversion rate gradually decreased as the proportions of the mill scale increased because NO was reduced to N_2 by Fe_3O_4, FeO, and Fe in the mill scale. The strength of sinter reached the highest value at 8.0 wt% mill scale due to the formation of minerals with low melting point. The fuel-N conversion rate slightly fluctuated and total NO_x emission significantly decreased with the decreased proportions of coke breeze because CO formation and content of N element in the sintered mixture decreased. However, the sinter strength also decreased due to the decrease in the amount of the melting minerals. Furthermore, results of the sinter pot tests indicated that NO_x emission decreased. The sinter indexes performed well when the proportions of mill scale and coke breeze were 8.0 wt% and 3.70 wt% respectively in the sintered mixture.  相似文献   

17.
烧结生产过程产生了包含颗粒物、二氧化硫、氮氧化物和二口恶英的高温烧结废气.为减少烧结污染物排放,制备新型生物质燃料取代烧结矿石燃料,通过生物质炭化、生物质成型等对比实验确定优化生物质燃料最优实验条件.实验结果表明:锯末炭化分为两个阶段,在室温(25℃)~400℃适宜炭化升温速率为5℃/min,在400~600℃适宜炭化升温速率为20℃/min,锯末燃料适宜成型压力为50 M Pa.通过对适宜条件下制备的生物质烧结燃料与烟煤和焦炭进行对比实验,其比表面积、孔容孔径和燃料燃烧性能大幅改善,接近矿石燃料.  相似文献   

18.
以典型钢铁生产企业为研究对象,基于企业实际生产数据,采用物质流分析法(MFA),构建物质代谢模型.建立了能源、资源利用和污染物排放分析指标,定量描述了钢铁企业的资源能源消耗及烟粉尘排放情况.结果表明:企业层面,高炉-转炉长流程吨钢总资源消耗量为208.6 t,燃料能消耗量占能源消耗总量的93.9%,吨钢烟粉尘排放量为648.08 g,烧结和炼铁工序贡献最大,分别占总排放量的45%和36%.电炉短流程总资源消耗量为1.31 t,电能消耗量占能源消耗总量的96.7%,吨钢烟粉尘排放量67 g.工序层面,烧结、炼焦和炼铁三个主排放工序的排放量分别为222.50 g/t烧结矿、118.20 g/t焦、245.27 g/t铁.据此,提出企业节能减排和产业结构调整的方向性建议,以减少环境压力,实现钢铁企业的可持续发展.  相似文献   

19.
Reducing NOx emission of iron ore sintering process in a cost effective manner is a challenge for the iron and steel industry at present. Effects of the proportion of mill scale and coke breeze on the NOx emission, strength of sinter, and sinter indexes were studied by combustion and sinter pot tests. Results showed that the peak value of NO concentration, total of NO emission, and fuel-N conversion rate gradually decreased as the proportions of the mill scale increased because NO was reduced to N2 by Fe3O4, FeO, and Fe in the mill scale. The strength of sinter reached the highest value at 8.0wt% mill scale due to the formation of minerals with low melting point. The fuel-N conversion rate slightly fluctuated and total NOx emission significantly decreased with the decreased proportions of coke breeze because CO formation and content of N element in the sintered mixture decreased. However, the sinter strength also decreased due to the decrease in the amount of the melting minerals. Furthermore, results of the sinter pot tests indicated that NOx emission decreased. The sinter indexes performed well when the proportions of mill scale and coke breeze were 8.0wt% and 3.70wt% respectively in the sintered mixture.  相似文献   

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