Extensive halogen-mediated ozone destruction over the tropical Atlantic Ocean

Increasing tropospheric ozone levels over the past 150 years have led to a significant climate perturbation; the prediction of future trends in tropospheric ozone will require a full understanding of both its precursor emissions and its destruction processes. A large proportion of tropospheric ozone loss occurs in the tropical marine boundary layer and is thought to be driven primarily by high ozone photolysis rates in the presence of high concentrations of water vapour. A further reduction in the tropospheric ozone burden through bromine and iodine emitted from open-ocean marine sources has been postulated by numerical models, but thus far has not been verified by observations. Here we report eight months of spectroscopic measurements at the Cape Verde Observatory indicative of the ubiquitous daytime presence of bromine monoxide and iodine monoxide in the tropical marine boundary layer. A year-round data set of co-located in situ surface trace gas measurements made in conjunction with low-level aircraft observations shows that the mean daily observed ozone loss is approximately 50 per cent greater than that simulated by a global chemistry model using a classical photochemistry scheme that excludes halogen chemistry. We perform box model calculations that indicate that the observed halogen concentrations induce the extra ozone loss required for the models to match observations. Our results show that halogen chemistry has a significant and extensive influence on photochemical ozone loss in the tropical Atlantic Ocean boundary layer. The omission of halogen sources and their chemistry in atmospheric models may lead to significant errors in calculations of global ozone budgets, tropospheric oxidizing capacity and methane oxidation rates, both historically and in the future.     

Advancing decadal-scale climate prediction in the North Atlantic sector

The climate of the North Atlantic region exhibits fluctuations on decadal timescales that have large societal consequences. Prominent examples include hurricane activity in the Atlantic, and surface-temperature and rainfall variations over North America, Europe and northern Africa. Although these multidecadal variations are potentially predictable if the current state of the ocean is known, the lack of subsurface ocean observations that constrain this state has been a limiting factor for realizing the full skill potential of such predictions. Here we apply a simple approach-that uses only sea surface temperature (SST) observations-to partly overcome this difficulty and perform retrospective decadal predictions with a climate model. Skill is improved significantly relative to predictions made with incomplete knowledge of the ocean state, particularly in the North Atlantic and tropical Pacific oceans. Thus these results point towards the possibility of routine decadal climate predictions. Using this method, and by considering both internal natural climate variations and projected future anthropogenic forcing, we make the following forecast: over the next decade, the current Atlantic meridional overturning circulation will weaken to its long-term mean; moreover, North Atlantic SST and European and North American surface temperatures will cool slightly, whereas tropical Pacific SST will remain almost unchanged. Our results suggest that global surface temperature may not increase over the next decade, as natural climate variations in the North Atlantic and tropical Pacific temporarily offset the projected anthropogenic warming.     

Arctic sea ice bordering on the North Atlantic and interannual climate variations

Variations of winter Arctic sea ice bordering on the North Atlantic are closely related to climate variations in the same region. When winter North Atlantic Oscillation (NAO) index is positive (negative) anomaly phase, Icelandic Low is obviously deepened and shifts northwards (southwards). Simultaneously, the Subtropical High over the North Atlantic is also intensified, and moves northwards (southwards). Those anomalies strengthen (weaken) westerly between Icelandic Low and the Subtropical High, and further result in positive (negative) sea surface temperature (SST) anomalies in the mid-latitude of the North Atlantic, and increase (decrease) the warm water transportation from the mid-latitude to the Barents Sea, which causes positive (negative) mixed-layer water temperature anomalies in the south part of the Barents Sea. Moreover, the distribution of anomaly air temperature clearly demonstrates warming (cooling) in northern Europe and the subarctic regions (including the Barents Sea) and cooling (warming) in Baffin Bay/Davis Strait. Both of distributions of SST and air temperature anomalies directly result in sea ice decrease (increase) in the Barents/Kara Seas, and sea ice increase (decrease) in Baffin Bay/Davis Strait. :     

Large contribution of sea surface warming to recent increase in Atlantic hurricane activity

Atlantic hurricane activity has increased significantly since 1995 (refs 1-4), but the underlying causes of this increase remain uncertain. It is widely thought that rising Atlantic sea surface temperatures have had a role in this, but the magnitude of this contribution is not known. Here we quantify this contribution for storms that formed in the tropical North Atlantic, Caribbean Sea and Gulf of Mexico; these regions together account for most of the hurricanes that make landfall in the United States. We show that a statistical model based on two environmental variables--local sea surface temperature and an atmospheric wind field--can replicate a large proportion of the variance in tropical Atlantic hurricane frequency and activity between 1965 and 2005. We then remove the influence of the atmospheric wind field to assess the contribution of sea surface temperature. Our results indicate that the sensitivity of tropical Atlantic hurricane activity to August-September sea surface temperature over the period we consider is such that a 0.5 degrees C increase in sea surface temperature is associated with a approximately 40% increase in hurricane frequency and activity. The results also indicate that local sea surface warming was responsible for approximately 40% of the increase in hurricane activity relative to the 1950-2000 average between 1996 and 2005. Our analysis does not identify whether warming induced by greenhouse gases contributed to the increase in hurricane activity, but the ability of climate models to reproduce the observed relationship between hurricanes and sea surface temperature will serve as a useful means of assessing whether they are likely to provide reliable projections of future changes in Atlantic hurricane activity.     

Increasing destructiveness of tropical cyclones over the past 30 years

Theory and modelling predict that hurricane intensity should increase with increasing global mean temperatures, but work on the detection of trends in hurricane activity has focused mostly on their frequency and shows no trend. Here I define an index of the potential destructiveness of hurricanes based on the total dissipation of power, integrated over the lifetime of the cyclone, and show that this index has increased markedly since the mid-1970s. This trend is due to both longer storm lifetimes and greater storm intensities. I find that the record of net hurricane power dissipation is highly correlated with tropical sea surface temperature, reflecting well-documented climate signals, including multi-decadal oscillations in the North Atlantic and North Pacific, and global warming. My results suggest that future warming may lead to an upward trend in tropical cyclone destructive potential, and--taking into account an increasing coastal population--a substantial increase in hurricane-related losses in the twenty-first century.     

Detection of human influence on sea-level pressure

Greenhouse gases and tropospheric sulphate aerosols--the main human influences on climate--have been shown to have had a detectable effect on surface air temperature, the temperature of the free troposphere and stratosphere and ocean temperature. Nevertheless, the question remains as to whether human influence is detectable in any variable other than temperature. Here we detect an influence of anthropogenic greenhouse gases and sulphate aerosols in observations of winter sea-level pressure (December to February), using combined simulations from four climate models. We find increases in sea-level pressure over the subtropical North Atlantic Ocean, southern Europe and North Africa, and decreases in the polar regions and the North Pacific Ocean, in response to human influence. Our analysis also indicates that the climate models substantially underestimate the magnitude of the sea-level pressure response. This discrepancy suggests that the upward trend in the North Atlantic Oscillation index (corresponding to strengthened westerlies in the North Atlantic region), as simulated in a number of global warming scenarios, may be too small, leading to an underestimation of the impacts of anthropogenic climate change on European climate.     

青藏高原对全球大气温度和水汽分布的影响

利用耦合的气候模式CESM, 定量研究青藏高原对全球大气温度和水汽分布的影响。通过对比采用真实地形的参考实验(Real)和去掉青藏高原的敏感性实验(NoTibet)发现, 去掉青藏高原会使北半球大气变冷、变干, 对南半球的影响不明显。北半球中高纬度从地表至平流层均有强烈降温, 地表的降温中心在北大西洋, 年平均降温幅度达5ºC, 高空的降温中心在100 hPa的平流层, 年平均降温幅度达2ºC。北大西洋和南亚地区湿度减少, 南大西洋和东非地区湿度增加。北半球变冷主要是海洋向北经向热量输送减少的结果, 一方面增强了北半球的经向温度梯度, 导致Hadley环流增强, 加强了中低纬地区向北的大气热量输送, 部分补偿了海洋向北减少的热量输送, 维持了北半球中低纬度的能量平衡; 另一方面, 使得北半球中高纬度蒸发作用减弱, 大气中水汽含量减少, 北半球变得寒冷干燥。初步的研究表明, 青藏高原对北半球气候有重大影响, 影响范围可达北半球高纬度地区。     

Moisture transport across Central America as a positive feedback on abrupt climatic changes

Moisture transport from the Atlantic to the Pacific ocean across Central America leads to relatively high salinities in the North Atlantic Ocean and contributes to the formation of North Atlantic Deep Water. This deep water formation varied strongly between Dansgaard/Oeschger interstadials and Heinrich events-millennial-scale abrupt warm and cold events, respectively, during the last glacial period. Increases in the moisture transport across Central America have been proposed to coincide with northerly shifts of the Intertropical Convergence Zone and with Dansgaard/Oeschger interstadials, with opposite changes for Heinrich events. Here we reconstruct sea surface salinities in the eastern equatorial Pacific Ocean over the past 90,000 years by comparing palaeotemperature estimates from alkenones and Mg/Ca ratios with foraminiferal oxygen isotope ratios that vary with both temperature and salinity. We detect millennial-scale fluctuations of sea surface salinities in the eastern equatorial Pacific Ocean of up to two to four practical salinity units. High salinities are associated with the southward migration of the tropical Atlantic Intertropical Convergence Zone, coinciding with Heinrich events and with Greenland stadials. The amplitudes of these salinity variations are significantly larger on the Pacific side of the Panama isthmus, as inferred from a comparison of our data with a palaeoclimate record from the Caribbean basin. We conclude that millennial-scale fluctuations of moisture transport constitute an important feedback mechanism for abrupt climate changes, modulating the North Atlantic freshwater budget and hence North Atlantic Deep Water formation.     

青藏高原对非洲北部降水影响的模拟研究

利用耦合模式CESM1.0, 研究青藏高原地形对非洲北部降水的影响。敏感性试验结果表明, 去掉青藏高原地形后, 首先, 大气环流迅速做出调整, 出现自热带大西洋向东北方向至北非的水汽输送异常和自印度洋向西至北非的水汽输送异常, 造成北非大气水汽含量增加和水汽辐合增强, 降水增多。然后, 当海洋环流调整到准平衡态时, 北大西洋海表温度降低, 南大西洋海表温度升高, 地表大气温度也发生相应的变化。在南北温度梯度的影响下, 原本由热带大西洋向北非的水汽输送发生转向, 导致北非的水汽含量减少和水汽辐合减弱, 使得降水比前一阶段减少。即便如此, 在没有青藏高原的试验中, 当海洋环流调整到平衡态时, 北非大部分区域水汽辐合仍然强于有青藏高原的真实地形试验, 区域平均降水也增多。结果表明, 青藏高原的隆升可能在一定程度上加剧了北非的干旱化。     

Millennial-scale phase relationship between North Atlantic deep-level temperature and Qinghai-Tibet Plateau temperature and its evolution since the Last Interglaciation

This study employed proxy data to investigate the phase relationship between the North Atlantic deep-level temperature and the Qinghai-Tibet Plateau （TP） surface air temperature （TP temperature） and its evolution at the mil- lennial scale since the Last Interglaciation. The results indicate the alternation of in-phase and anti-phase relation- ships since the Last Interglaciation, with the in-phase rela- tionships showing a shorter duration than the anti-phase relationships. Alternations between the in-phase and anti- phase relationships occurred more frequently during the Last Interglaciation than during the Last Glaciation. The phase relationship between the North At/antic deep-level temperature and the TP temperature was broadly illustrated by that between the North Atlantic temperature （based on oxygen isotope data from the Greenland ice core） and TP temperature. Furthermore, the North Atlantic deep-level temperature and the TP temperature may be connected through the North Atlantic sea surface temperature.     

不同平均强度热盐环流的年代际波动特征

基于美国国家大气研究中心的CCSM3(community climate system model version 3)模式,对淡水扰动试验下不同平均强度热盐环流(thermohline circulation,THC)的年代际波动特征及北大西洋气候响应特征进行研究。结果表明,百年以上尺度的THC变化对其年代际尺度波动产生显著影响,高平均强度下THC的年代际波动周期更长、更显著。对不同平均强度下北大西洋海、气要素与THC在年代际尺度上的相关分布进行分析,发现在高平均强度下,THC与海表温度(sea surface temperature,SST)的相关呈现为经向三核型分布,与海平面气压(sea lever pressure,SLP)的相关呈现为类NAO(North Atlantic oscillation)分布,而在低平均强度下,则不存在这2种模态分布;同时,在不同平均强度下,THC与各要素间的相关程度也不同,高平均强度下相关程度更高。     

Interdecadal variations of the East Asian winter surface air temperature and possible causes

Using the NCEP/NCAR and JRA-25 monthly analysis data from 1979 to 2011, this paper analyzes the interdecadal variations of winter (Dec.–Feb.) mean surface air temperature (SAT) over East Asia by means of the empirical orthogonal function (EOF) analysis method. Two dominant modes were extracted, with the leading mode basically depicting a sign consistent SAT variation and the second mode describing a meridional dipole structure between the northern and southern parts of East Asia. These two modes can explain more than 60% of the variance. The leading mode is closely related to the intensity of Siberian high and the East Asian winter monsoon. The second mode exhibits a notable interdecadal shift in the late 1990s, with a turning point around 1996/1997. Winter SAT in the northern (southern) part of East Asia tends to be cooler (warmer) since the late 1990. Winter sea level pressure (SLP) differences between 1997–2011 and 1979–1996 show negative (positive) anomalies over southern (northern) Eurasia. At 500-hPa, an anomalous blocking high occurs over northern Eurasia, while a cyclone anomaly appears over northern East Asia. In addition, the upper-level East Asian jet stream tends to shift northward and become stronger after the late 1990. Indeed, the interdecadal shift of winter SAT over East Asia is dynamical consistent with changes of the large-scale atmospheric circulation in the late 1990s. The result indicates that previous autumn sea surface temperature (SST) in the North Atlantic Ocean, the Northern Indian Ocean and the western North Pacific Ocean, as well as sea ice concentration (SIC) in the northern Eurasia marginal seas and the Beaufort Sea also experienced obvious changes in the late 1990s. In particular, the interdecadal shifts of both SST in the North Atlantic Ocean and SIC in the Arctic Ocean and its marginal seas are well coherent with that of the winter SAT over East Asia. The results indicate that the interdecadal shift of East Asian winter SAT may be related to changes in the North Atlantic SST and the Arctic SIC in the late 1990s.     

北半球仲春平流层行星波活动对臭氧总量分布的影响

采用NCEP/NCAR再分析资料和TOMS臭氧总量资料,分析了1979～2003年4月份平流层行星波1波和2波的变化,及其对北半球中高纬臭氧总量分布的影响.结果表明,在通常情况下,4月份平流层中下层行星波1波强于2波,对应的位势高度场在欧亚大陆北部为一低压涡旋,而北美北部为一高压区.此时,从东北亚到北加拿大为臭氧总量的高值区,而北欧至格陵兰一带为臭氧的低值区.但在有些年份,2波比较强时,相应的位势高度场在极地为一明显的低压涡旋,此时在极地附近会出现臭氧低值区.个别年份如1997年,1波在25年中最强,2波也很强,强低涡中心比常年更靠近北极点,在与之位置相同的地方出现了25年中最明显的臭氧洞.还有一些年份,北极地区主要由高压控制,臭氧总量的高值区基本上出现在北极及其附近.     

Low Atlantic hurricane activity in the 1970s and 1980s compared to the past 270 years

Hurricane activity in the North Atlantic Ocean has increased significantly since 1995 (refs 1, 2). This trend has been attributed to both anthropogenically induced climate change and natural variability, but the primary cause remains uncertain. Changes in the frequency and intensity of hurricanes in the past can provide insights into the factors that influence hurricane activity, but reliable observations of hurricane activity in the North Atlantic only cover the past few decades. Here we construct a record of the frequency of major Atlantic hurricanes over the past 270 years using proxy records of vertical wind shear and sea surface temperature (the main controls on the formation of major hurricanes in this region) from corals and a marine sediment core. The record indicates that the average frequency of major hurricanes decreased gradually from the 1760s until the early 1990s, reaching anomalously low values during the 1970s and 1980s. Furthermore, the phase of enhanced hurricane activity since 1995 is not unusual compared to other periods of high hurricane activity in the record and thus appears to represent a recovery to normal hurricane activity, rather than a direct response to increasing sea surface temperature. Comparison of the record with a reconstruction of vertical wind shear indicates that variability in this parameter primarily controlled the frequency of major hurricanes in the Atlantic over the past 270 years, suggesting that changes in the magnitude of vertical wind shear will have a significant influence on future hurricane activity.     

云南5月雨量与全球海温的关系分析研究

 通过对海温与云南全省、云南东部和云南西部5月雨量的相关分析发现:海温对云南5月降水在时空上有很好的相关.5月降水与头年11月和同期太平洋海表温度存在有相同的‘-+-+’的相关分布型.印度洋北部对云南东部的影响更显著,而大西洋北部对西部的影响更显著.西部5月雨量与海表温度的相关总体不如东部的好,西部与东部最大的差异是在热带太平洋上.通过头年1月南大西洋海温可对来年云南5月降水进行预测.     

The responses of East Asian Summer monsoon to the North Atlantic Meridional Overturning Circulation in an enhanced freshwater input simulation

We investigated the response of the East Asian Summer Monsoon （EASM） to a weakened Atlantic Meridional Overturning Circulation （AMOC） and its mechanism in an enhanced freshwater input experiment （FW） by using a fully-coupled climate model. The response was a weakened EASM and the mechanisms can be explained as follows. The simulated weakened AMOC resulted in a drop in sea surface temperature （SST） in the North Atlantic （NA） and, correspondingly, an anomalous high sea level pressure （SLP） over the North American regions, which in turn increased the northeast surface winds across the equator in the eastern tropical Pacific （ETP）. The anomalous northeast winds then induced further upwelling in the ETP and stronger air/sea heat exchange, therefore leading to an anomalous cooling of the eastern tropical sea surface. As a result, the climatologic Hadley Circulation （HC） was weakened due to an anomalous stronger sinking of air in the ETP north of the equator, whereas the Walker Circulation （WC） in the western tropical Pacific （WTP） north of the equator was strengthened with an eastward-shifted upwelling branch. This feature was in agreement with the anomalous convergent winds in the WTP, and led to a weakened EASM and less East Asian summer precipitation （EASP）. Furthermore, comparison with previous freshwater experiments indicates that the strength of EASP could be influenced by the magnitude of the added freshwater.     

卫星遥感监测大气臭氧总量分布和变化

 利用卫星紫外仪器TOMS、OMI和TOU的臭氧总量数据(1979-2014年),研究了全球及关键地区臭氧总量的分布及变化。讨论了南北半球臭氧总量分布和变化的差异,探讨了影响臭氧分布和变化的可能因子。重点分析了中国区域、青藏高原和极地的臭氧变化,并利用FY-3数据对南极臭氧洞和北极臭氧低值进行了监测。结果表明,臭氧总量的分布和变化在中高纬度地区具有很强的不均匀性,极地臭氧损耗依然明显,青藏高原的臭氧增长大于同纬度其他地区,其机制更加复杂。     

The search for signs of recovery of the ozone layer

Evidence of mid-latitude ozone depletion and proof that the Antarctic ozone hole was caused by humans spurred policy makers from the late 1980s onwards to ratify the Montreal Protocol and subsequent treaties, legislating for reduced production of ozone-depleting substances. The case of anthropogenic ozone loss has often been cited since as a success story of international agreements in the regulation of environmental pollution. Although recent data suggest that total column ozone abundances have at least not decreased over the past eight years for most of the world, it is still uncertain whether this improvement is actually attributable to the observed decline in the amount of ozone-depleting substances in the Earth's atmosphere. The high natural variability in ozone abundances, due in part to the solar cycle as well as changes in transport and temperature, could override the relatively small changes expected from the recent decrease in ozone-depleting substances. Whatever the benefits of the Montreal agreement, recovery of ozone is likely to occur in a different atmospheric environment, with changes expected in atmospheric transport, temperature and important trace gases. It is therefore unlikely that ozone will stabilize at levels observed before 1980, when a decline in ozone concentrations was first observed.     

Interannual atmospheric variability forced by the deep equatorial Atlantic Ocean

Climate variability in the tropical Atlantic Ocean is determined by large-scale ocean-atmosphere interactions, which particularly affect deep atmospheric convection over the ocean and surrounding continents. Apart from influences from the Pacific El Ni?o/Southern Oscillation and the North Atlantic Oscillation, the tropical Atlantic variability is thought to be dominated by two distinct ocean-atmosphere coupled modes of variability that are characterized by meridional and zonal sea-surface-temperature gradients and are mainly active on decadal and interannual timescales, respectively. Here we report evidence that the intrinsic ocean dynamics of the deep equatorial Atlantic can also affect sea surface temperature, wind and rainfall in the tropical Atlantic region and constitutes a 4.5-yr climate cycle. Specifically, vertically alternating deep zonal jets of short vertical wavelength with a period of about 4.5?yr and amplitudes of more than 10?cm?s(-1) are observed, in the deep Atlantic, to propagate their energy upwards, towards the surface. They are linked, at the sea surface, to equatorial zonal current anomalies and eastern Atlantic temperature anomalies that have amplitudes of about 6?cm?s(-1) and 0.4?°C, respectively, and are associated with distinct wind and rainfall patterns. Although deep jets are also observed in the Pacific and Indian oceans, only the Atlantic deep jets seem to oscillate on interannual timescales. Our knowledge of the persistence and regularity of these jets is limited by the availability of high-quality data. Despite this caveat, the oscillatory behaviour can still be used to improve predictions of sea surface temperature in the tropical Atlantic. Deep-jet generation and upward energy transmission through the Equatorial Undercurrent warrant further theoretical study.     

全球地表温度大气遥相关路径研究

基于复杂网络方法,分析不同区域地表温度之间存在的相关关系及其时滞,建立了体现大气遥相关的全球地表温度网络,进而给出地表温度网络遥相关路径．研究表明:网络连接的空间距离在3 500和7 000 km处有1个峰值,这与大气Rossby波的1/2和1倍波长一致．地表温度网络中,影响传播的主导节点在北半球分布在东亚、向西延伸的北太平洋、美国东海岸及邻接的北大西洋地区;在南半球分布在50° S纬度带．遥相关现象在南半球比北半球更显著,典型遥相关路径与不同的环流作用有明确对应:1）北太平洋中部到墨西哥的连接反映了西风带的作用;2）北大西洋传播到非洲北部、格陵兰岛到里海的连接,均属于连接北大西洋到欧亚大陆的跨欧亚波列的一部分;3）俄罗斯喀拉海到北太平洋的连接与北大西洋涛动（NAO）密切关联;4）南半球的连接反映了大气西风带和Rossby波的影响．大气遥相关路径分析有利于深化对地表温度变化的认识,可为减缓气候全球变化提供理论基础．