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1.
新型双氧钒—西佛碱酸合物的合成及晶体结构研究   总被引:1,自引:0,他引:1  
本文以苯酰丙酮,吉拉尔特试剂T及(C2H5)4NVO3为原料在无水乙醇溶液中合成了一种新型的钒-西佛碱配合物,用DMSO溶剂进行重结晶,得到结构式为[VO2(PhC(O)CHC(CH3)NNC(O)CH2N(CH3)3)]0.5DMSO的黄色晶体,该晶体属三斜晶系,空间群为P1,晶胞参数a=9.843(2),b=14.130(2),c=15.940(3)A;α=67.37(2),β=80.08(3  相似文献   

2.
研究了四苯基卟啉钆配合物在CH2Cl2,DMSO及混合溶剂DMSO-H2Cl2,DMSO-H2O中的可见光谱。测定了在CH2Cl2溶剂中配合物与DMSO反应的平衡常数及配比。  相似文献   

3.
DISCOVERYOFMICROFOSSILSFROMTHE1848-MA-OLDCHANGZHOUGOUFORMATION,JIXIANSECTION,NORTHCHINAZhangZhongying(DepartmentofEarthScienc...  相似文献   

4.
冷冻真空干燥小舌鳎鱼片技术的研究夏达金,陈小娥,方旭波,曹海军,薄竣STUDYONSMALLTONGUEFISHFILLETSADOPTINGVACCUMFREEZE-DRYTECHNIQUEXiaDajinChenXiao'eFangXuboCao...  相似文献   

5.
TECTONICDEVELOPMENTOFTHEMETAMORPHICCORECOMPLEXOFTHEWUGONGSHANINTHENORTHERNJIANGXIPROVINCESunYan1)ShuLiangshu1)M.Faure2)J.Cha...  相似文献   

6.
应用Corning一价阳离子选择性电极(M+-ISE)和固态氯离子选择性电极(Cl--ISE)组成可逆电池,通过测定电池的标准电动势(Eom)求得了RbCl由H2O至(H2O-MeOH)和(H2O-DMF)混合溶剂的标准迁移自由能(ΔGot),并对ΔGot的某些变化规律进行了初步的讨论.  相似文献   

7.
草鱼同工酶的组织分布及遗传结构分析   总被引:19,自引:0,他引:19  
采用聚丙烯酰胺垂直板状连续电泳的方法,对草鱼(Ctenopoharyngodonidelus)的脑(B)、晶体(E)、心脏(H)、肾脏(K)、肝脏(L)、肌肉(M)等六种组织进行了十一种同工酶(α-AMY,EST,GOT,G3PD,G6PD,IDH,LDH,MDH,ME,POX,SOD)的电泳研究,并对各种酶的同工酶位点及酶谱表型进行了分析,其中α-AMY和POX还未见报道。结果表明α-AMY,EST,G3PD,LDH,MDH,ME,POX,SOD存在不同程度的组织特异性,GOT和G6PD则无明显组织差异。对草鱼的α-AMY,G3PDY和POX的遗传基础、亚基组成及LDH特殊的酶谱表达模式等问题进行了讨论。  相似文献   

8.
以Meyer反应为出发点,研究了MX-REX3-HX-H2O和MX-REX3-HOAc-H2O四元体系(M=K,Rb,Cs;RE=La,Pr,Nd,Sm,Gd,Dy;X=Cl,Br)。对Meyer反应的机理提出了新的解释,并给出了相应的反应式;发现在四元体系中醋酸水溶液可作为等效介质替代盐酸水溶液,而表现出相同的相化学行为;发现氯化物和溴化物的Meyer反应有显著不同的相化学关系和不同的反应机理,首次依照四元体系的相化学关系,设计了一系列合成不同摩尔比的MX和REX3的化合物的新的无机合成反应。  相似文献   

9.
本文采用XRD,TPR和以H2,CO为探针分子的TPD—MS,TPSR-MS技术研究了Ni-CU合金负载于氧化物SiO2,MgO和γ-Al2O3上的性质变化,以及对CO加氢反应性能的影响。实验结果表明,各种载体对于负载于其上的活性组分均具有良好的分散性能;SiO2对金属相的结构和电子状态不产生影响,而γ-Al2O3和MgO对金属相则有不同程度的影响,这种相互作用主要表现在活性组分对H2和CO吸附能力的变化和CO加氢的活性和选择性的变化上。  相似文献   

10.
SA-高吸水树脂对玉米生长及增产效果的试验研究栾树梅,王欣葵(吉林省吉林市农业机械研究所吉林,132012)EXPERIMENTALRESEARCHOFTHEEFFECTOFSA-HIGHABSORPTIONRESINSONYIELDINCREASE...  相似文献   

11.
Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.  相似文献   

12.
何延凌 《科技信息》2008,(4):258-258
Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women's language from these perspectives: pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women's language, more attention should be paid to language use in social context. What's more, the linguistic phenomena in a speaking community can be understood more thoroughly.  相似文献   

13.
The discovery of the prolific Ordovician Red River reservoirs in 1995 in southeastern Saskatchewan was the catalyst for extensive exploration activity which resulted in the discovery of more than 15 new Red River pools. The best yields of Red River production to date have been from dolomite reservoirs. Understanding the processes of dolomitization is, therefore, crucial for the prediction of the connectivity, spatial distribution and heterogeneity of dolomite reservoirs.The Red River reservoirs in the Midale area consist of 3~4 thin dolomitized zones, with a total thickness of about 20 m, which occur at the top of the Yeoman Formation. Two types of replacement dolomite were recognized in the Red River reservoir: dolomitized burrow infills and dolomitized host matrix. The spatial distribution of dolomite suggests that burrowing organisms played an important role in facilitating the fluid flow in the backfilled sediments. This resulted in penecontemporaneous dolomitization of burrow infills by normal seawater. The dolomite in the host matrix is interpreted as having occurred at shallow burial by evaporitic seawater during precipitation of Lake Almar anhydrite that immediately overlies the Yeoman Formation. However, the low δ18O values of dolomited burrow infills (-5.9‰~ -7.8‰, PDB) and matrix dolomites (-6.6‰~ -8.1‰, avg. -7.4‰ PDB) compared to the estimated values for the late Ordovician marine dolomite could be attributed to modification and alteration of dolomite at higher temperatures during deeper burial, which could also be responsible for its 87Sr/86Sr ratios (0.7084~0.7088) that are higher than suggested for the late Ordovician seawaters (0.7078~0.7080). The trace amounts of saddle dolomite cement in the Red River carbonates are probably related to "cannibalization" of earlier replacement dolomite during the chemical compaction.  相似文献   

14.
There are numerous geometric objects stored in the spatial databases. An importance function in a spatial database is that users can browse the geometric objects as a map efficiently. Thus the spatial database should display the geometric objects users concern about swiftly onto the display window. This process includes two operations:retrieve data from database and then draw them onto screen. Accordingly, to improve the efficiency, we should try to reduce time of both retrieving object and displaying them. The former can be achieved with the aid of spatial index such as R-tree, the latter require to simplify the objects. Simplification means that objects are shown with sufficient but not with unnecessary detail which depend on the scale of browse. So the major problem is how to retrieve data at different detail level efficiently. This paper introduces the implementation of a multi-scale index in the spatial database SISP (Spatial Information Shared Platform) which is generalized from R-tree. The difference between the generalization and the R-tree lies on two facets: One is that every node and geometric object in the generalization is assigned with a importance value which denote the importance of them, and every vertex in the objects are assigned with a importance value,too. The importance value can be use to decide which data should be retrieve from disk in a query. The other difference is that geometric objects in the generalization are divided into one or more sub-blocks, and vertexes are total ordered by their importance value. With the help of the generalized R-tree, one can easily retrieve data at different detail levels.Some experiments are performed on real-life data to evaluate the performance of solutions that separately use normal spatial index and multi-scale spatial index. The results show that the solution using multi-scale index in SISP is satisfying.  相似文献   

15.
王慧 《科技信息》2008,(10):240-240
Wuthering Heights, Emily Bronte's only novel, was published in December of 1847 under the pseudonym Ellis Bell. The book did not gain immediate success, but it is now thought one of the finest novels in the English language. Catherine is the key character of this masterpiece, because everybody and everything center on her though she had a short life. We can understand this masterpiece better if we know Catherine well.  相似文献   

16.
The Williston Basin is a significant petroleum province, containing oil production zones that include the Middle Cambrian to Lower Ordovician, Upper Ordovician, Middle Devonian, Upper Devonian and Mississippian and within the Jurassic and Cretaceous. The oils of the Williston Basin exhibit a wide range of geochemical characteristics defined as "oil families", although the geochemical signature of the Cambrian Deadwood Formation and Lower Ordovician Winnipeg reservoired oils does not match any "oil family". Despite their close stratigraphic proximity, it is evident that the oils of the Lower Palaeozoic within the Williston Basin are distinct. This suggests the presence of a new "oil family" within the Williston Basin. Diagnostic geochemical signatures occur in the gasoline range chromatograms, within saturate fraction gas chromatograms and biomarker fingerprints. However, some of the established criteria and cross-plots that are currently used to segregate oils into distinct genetic families within the basin do not always meet with success, particularly when applied to the Lower Palaeozoic oils of the Deadwood and Winnipeg Formation.  相似文献   

17.
In the 19th century the society was controlled by men, and women were just appendants of them, they had not any rights and freedom. But Jane was an exception, she showed some characteristics of early feminist. Jane showed her characteristics of feminism in three aspects: rebellion, equality, and independence. These characteristics were helpful to her success, and feminism is the only way out for women of that time.  相似文献   

18.
理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。  相似文献   

19.
As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.  相似文献   

20.
The non-orthogonal localized molecular orbital(NOLMO)is the most localized representation of electronic degrees of freedom.As such,NOLMOs are thus potentially the most efficient for linear scaling calculations of electronic structures for large systems.However,direct ab initio calculations with NOLMO have not been fully implemented and widely used,partly because of the slow convergence issue in the optimization of NOLMO.We devel-  相似文献   

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