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1.
PP纤维辐射接枝4—乙烯基吡啶的反应动力学   总被引:2,自引:0,他引:2  
对聚丙烯(PP)纤维辐射接枝4_乙烯基吡啶(4VP)的反应动力学进行了研究.建立了接枝反应速率方程:Rg=k[M]1.17D0.56.求得接枝反应的表观活化能和表观碰撞频率因子分别为7.95kJ/mol和65.6,并建立了如下公式:lnRg=1.17ln[M]+0.56lnD-792.64/T+4.18  相似文献   

2.
研究了在聚乙烯醇(PVA)存在下,钯与钨酸钠和丁基罗丹明B(BRB)反应形成的有色离子缔合物用于痕量钯的光度法测定.最佳条件为:[H2SO4]=1.2mol·L-1,[WO2-4]=9.1×10-5mol·L-1,[BRB]=3.0×10-5mol·L-1.缔合物的最大吸收位于575nm处,表观摩尔吸光系数ε=7.98×107L·mol-1·cm-1.钯量在0~10ng/25ml范围内服从比尔定律.体系至少稳定140h,检测限(3σ)0.048μg·L-1(n=10),对0.40μg·L-1Pd(Ⅱ)测定的相对标准偏差为3.39%(n=11).缔合物的摩尔比为Pd∶BRB=1∶4.考察了50多种共存离子的影响.本法已用于炭基和铝基钯催化剂中微量钯的测定,结果满意  相似文献   

3.
合成标题化合物[(seda)Cu]·EtOH,并得到单晶[seda=N,N′-二水杨叉基-1,2-二-(4-甲氧基苯基)乙二胺].X-衍射结构分析表明,晶体属正交晶系,空间群Pbca,晶体学数据:a=2.0115(4)nm,b=1.3196(3)nm,c=2.1057(4)nm,晶胞体积V=5.589(3)nm3,分子量588.16,Z=8,Dx=1.398g/cm3,μ=8.239cm-1,F(000)=2465,最终偏离因子R=0.079,Rw=0.083,(Δ/σ)max=0.68.结构分析表明,配体中二个偶氮甲碱中氮原子和二个酚氧原子与中心Cu原子配位,形成规则的菱形平面结构.  相似文献   

4.
用反相气相色谱法测定了聚己烯-1与8种溶剂的Flory-Huggins相互作用参数X1和聚乙烯-1的溶解度参数,确定了X1与温度的数学关系式:X1=0.923-256.4/T。测定结果表明聚己烯-1溶于正辛烷是一个放热过程,而且X1随着溶剂中碳数的增加而减小。同时也根据X1值和溶剂的溶解度参数δ1计算出了聚己烯-1的溶解度参数δ,其值为27.50(J/mL)1/2。  相似文献   

5.
在PH=5.0HAc-NaAc缓冲介质中,溴化十六烷基吡啶(CPB)存在下,Te(IV)与过量的二磺基苯基荧光酮(DSF)生成1:4稳定络合物,λmax=555nm,ε=1.35*10^5L.mol^-1.cm^-1,Te(IV)在0-10μg/25mL内符合比尔定律。方法用于硒中微量碲的测定,结果令人满意。  相似文献   

6.
研究了1-[(2-吡啶)]偶氮-2-萘酚-磺酸(简称PAN-S)与锰显色反应的最佳条件。在pH9硼砂-HC1介质中,锰与PAN-S形成1:2红色配合物,λmax=535um,ε535=2.66×104L·mol-1·cm-1.0~50μgMn/25mL符合比尔定律。本法可满意地用于测定碳素比色钢、低合金钢和碳素钢。  相似文献   

7.
本文以过硫酸钾与硫代硫酸钠组成KPS—Na2S2O3氧化还原z引发体系,首次研究了丙烯酸乙酯(EA)一醋酸乙烯酯(VAC)与玉米淀粉的乳液共接枝反应规律,IR、SEM表征了产物的结构.当[KPS]=6×10-3M,[VAC]=1.5×10-1M,[EA]=2×10-2M,S:L=4:100,CE=0.6g/100ml,60℃,反应6h时,可以得到最佳的G%及E%值,文献中未见有与本文相同的报道.  相似文献   

8.
通过盐消除反应合成了双核镍的加合物[Ni(hmtade)][Ni(cdc)2],其中hmtade=5,7,7,12,14,14-六甲基-1,4,8,11-四氮杂环十四-4,11-二烯,cdc=N-氰基亚氨基二硫代甲酸根。用元素分析、红外光谱、电子光谱和磁化率对它进行了表征。用X-射线测定了单晶的晶体结构,晶体属单斜晶系,空间群为C2/C,晶胞参数a=11.883(2)A,b=11.753(2)A,C=20.482(4)A,a=90°,β=100.19(1)°,r=90°,V=2815.4A3,M=628.19,Dx=1.482g/cm2,Z=4,R=0.047,Rw=0.054。正离子的[NiN4]为近似平面构型,整个正离子的外形是马鞍型;负离子的[NiS4]为绝对平面。在N(1)和N(11)之间形成了氢键,使得加合物呈一维线性链结构。  相似文献   

9.
王冬梅  刘绍文 《河南科学》1996,14(4):367-369
室温下,金属铜粉和2-噻吩甲酰三氟丙酮在甲醇溶剂中反应生成铜配合物[Cu(C8H4O2SF3)2]通过元素分析,红外光谱、热重、X-射线粉末衍射对其进行表征,并经X-射线单晶测试该配合物为单斜晶体,空间群为P21/C,晶胞参数a=10.582(1),b=11.169(2),c=8.044(3);β=104.61(2)°;V=916.73;z=2;Dc=1.833g·cm-3;R=0.082,Rw=0.092。铜原子与四个氧原子配位,形成四方平面  相似文献   

10.
本文考虑定常的奇异摄动系统(1.1)dx/dt=f(x,y,ε),εdy/dt=g(x,y,ε)及其退化 系统(1.2)dx/dt=f(x,y,0),0=g(x,y,0).假设系统(1.2)有一个非常数的概周期解(1.3) x=u(t),u=V(t).当系统(1.2)关于(1.3)的第一变分方程系恰具有一个广义零特征指 数时,我们在适当的条件下证明了对充分小的ε,系统(1.1)有唯一的概周期解x=x(t,ε), y=y(t,ε)使得当ε→o时,对一切t有||x(t,ε)-u(t)||+||y(t,ε)-v(t)||→0。 在证明中,我们首先推广了法坐标变换,进而建立指数型二分法,然后把问题化为非定常系统的 相应问题,从而利用K.W.Chang[5]的结果加以解决.  相似文献   

11.
Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.  相似文献   

12.
何延凌 《科技信息》2008,(4):258-258
Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women's language from these perspectives: pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women's language, more attention should be paid to language use in social context. What's more, the linguistic phenomena in a speaking community can be understood more thoroughly.  相似文献   

13.
王慧 《科技信息》2008,(10):240-240
Wuthering Heights, Emily Bronte's only novel, was published in December of 1847 under the pseudonym Ellis Bell. The book did not gain immediate success, but it is now thought one of the finest novels in the English language. Catherine is the key character of this masterpiece, because everybody and everything center on her though she had a short life. We can understand this masterpiece better if we know Catherine well.  相似文献   

14.
The Williston Basin is a significant petroleum province, containing oil production zones that include the Middle Cambrian to Lower Ordovician, Upper Ordovician, Middle Devonian, Upper Devonian and Mississippian and within the Jurassic and Cretaceous. The oils of the Williston Basin exhibit a wide range of geochemical characteristics defined as "oil families", although the geochemical signature of the Cambrian Deadwood Formation and Lower Ordovician Winnipeg reservoired oils does not match any "oil family". Despite their close stratigraphic proximity, it is evident that the oils of the Lower Palaeozoic within the Williston Basin are distinct. This suggests the presence of a new "oil family" within the Williston Basin. Diagnostic geochemical signatures occur in the gasoline range chromatograms, within saturate fraction gas chromatograms and biomarker fingerprints. However, some of the established criteria and cross-plots that are currently used to segregate oils into distinct genetic families within the basin do not always meet with success, particularly when applied to the Lower Palaeozoic oils of the Deadwood and Winnipeg Formation.  相似文献   

15.
There are numerous geometric objects stored in the spatial databases. An importance function in a spatial database is that users can browse the geometric objects as a map efficiently. Thus the spatial database should display the geometric objects users concern about swiftly onto the display window. This process includes two operations:retrieve data from database and then draw them onto screen. Accordingly, to improve the efficiency, we should try to reduce time of both retrieving object and displaying them. The former can be achieved with the aid of spatial index such as R-tree, the latter require to simplify the objects. Simplification means that objects are shown with sufficient but not with unnecessary detail which depend on the scale of browse. So the major problem is how to retrieve data at different detail level efficiently. This paper introduces the implementation of a multi-scale index in the spatial database SISP (Spatial Information Shared Platform) which is generalized from R-tree. The difference between the generalization and the R-tree lies on two facets: One is that every node and geometric object in the generalization is assigned with a importance value which denote the importance of them, and every vertex in the objects are assigned with a importance value,too. The importance value can be use to decide which data should be retrieve from disk in a query. The other difference is that geometric objects in the generalization are divided into one or more sub-blocks, and vertexes are total ordered by their importance value. With the help of the generalized R-tree, one can easily retrieve data at different detail levels.Some experiments are performed on real-life data to evaluate the performance of solutions that separately use normal spatial index and multi-scale spatial index. The results show that the solution using multi-scale index in SISP is satisfying.  相似文献   

16.
The discovery of the prolific Ordovician Red River reservoirs in 1995 in southeastern Saskatchewan was the catalyst for extensive exploration activity which resulted in the discovery of more than 15 new Red River pools. The best yields of Red River production to date have been from dolomite reservoirs. Understanding the processes of dolomitization is, therefore, crucial for the prediction of the connectivity, spatial distribution and heterogeneity of dolomite reservoirs.The Red River reservoirs in the Midale area consist of 3~4 thin dolomitized zones, with a total thickness of about 20 m, which occur at the top of the Yeoman Formation. Two types of replacement dolomite were recognized in the Red River reservoir: dolomitized burrow infills and dolomitized host matrix. The spatial distribution of dolomite suggests that burrowing organisms played an important role in facilitating the fluid flow in the backfilled sediments. This resulted in penecontemporaneous dolomitization of burrow infills by normal seawater. The dolomite in the host matrix is interpreted as having occurred at shallow burial by evaporitic seawater during precipitation of Lake Almar anhydrite that immediately overlies the Yeoman Formation. However, the low δ18O values of dolomited burrow infills (-5.9‰~ -7.8‰, PDB) and matrix dolomites (-6.6‰~ -8.1‰, avg. -7.4‰ PDB) compared to the estimated values for the late Ordovician marine dolomite could be attributed to modification and alteration of dolomite at higher temperatures during deeper burial, which could also be responsible for its 87Sr/86Sr ratios (0.7084~0.7088) that are higher than suggested for the late Ordovician seawaters (0.7078~0.7080). The trace amounts of saddle dolomite cement in the Red River carbonates are probably related to "cannibalization" of earlier replacement dolomite during the chemical compaction.  相似文献   

17.
理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。  相似文献   

18.
As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.  相似文献   

19.
In the 19th century the society was controlled by men, and women were just appendants of them, they had not any rights and freedom. But Jane was an exception, she showed some characteristics of early feminist. Jane showed her characteristics of feminism in three aspects: rebellion, equality, and independence. These characteristics were helpful to her success, and feminism is the only way out for women of that time.  相似文献   

20.
Location based services is promising due to its novel working style and contents.A software platform is proposed to provide application programs of typical location based services and support new applications developing efficiently. The analysis shows that this scheme is easy implemented, low cost and adapt to all kinds of mobile nework system.  相似文献   

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