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1.
研究了柠檬酸对高温固相法合成的Y2O2S:Eu^3+,Mg^2+,Ti^4+红色长余辉材料性能的影响,结果表明添加一定量的柠檬酸有利于提高Y2O2S:Eu^3+,Mg^2+,Ti^4+的发光性能,其初始亮度为1800mcd/m^2,余辉时间为8h.采用X射线衍射(XRD)、扫描电镜(SEM)、荧光光谱(PL)对样品进行了表征.  相似文献   

2.
微波法合成红色长余辉磷光粉CaWO4∶ Eu3+的研究   总被引:2,自引:0,他引:2  
采用微波法合成了新型红色长余辉发光材料CaWO4:Eu^3+,并表征了其结构以及激发、发射光谱和余辉衰减曲线.X-射线衍射分析证实其为单相的钨酸钙,用254nm紫外灯激发后,CaWO4:Eu^3+产生红色长余辉发光,余辉发射归属于Eu^3+的^5D0到^7FJ(J=0,1,2,3,4)的跃迁。  相似文献   

3.
为了讨论H1BO3对SrAl2O4:Eu^2+、Dy^3+、Nd^3+长余辉发光材料性能的影响,寻找最佳的H2BO3摩尔分数,采用燃烧法以尿素为还原剂在600℃下制备了掺入Eu^2+、Dy^3+、Nd^3+的SrAl2O4长余辉发光材料.研究了不同摩尔分数的H3BO3对磷光体晶体结构、发光光谱、初始亮度和余辉性能的影响.结果表明:随着H2BO3量的增加激发和发射光谱“蓝移”,硼酸的最佳摩尔分数为0.08.可见H2BO3的含量对SrAl2O3:Eu^2+、Dy^3+、Nd^3+长余辉发光材料的光学性质有很重要的影响.  相似文献   

4.
采用燃烧法制备出Ca12Al14O33:Eu^2+和Ca12Al14O33:Eu^2+,Re^3+(Re=Dy,La,Nd)靛蓝光长余辉发光粉。分别利用XRD和FE—SEM对产物的物相结构和形貌进行了表征,用光致发光测试(PL)和余辉衰减曲线对样品的发光性能进行了分析。结果表明上述长余辉发光粉的晶体结构属于体心立方相七铝酸十二钙;所制备的Ca12Al14O33:Eu^+、Ca12Al14O33:Eu^2+,Dy^3+、Ca12Al14O33:Eu^2+,La^3+和Ca12Al14O33:Eu^2+,Nd^3+长余辉发光粉的发射光谱均呈宽发射谱带,波长范围为390~530nm,发光峰值也均位于443nm;产物在紫外线或紫色光激发后发射靛蓝光;余辉时间分别为238,184,168和9120s.  相似文献   

5.
以H3BO3为助熔剂,在1200℃、H2还原气氛下成功制备出绿色荧光粉SrAl2O4:Eu^2+,并研究了不同H3BO3含量对SrAl2O4:Eu^2+发光性能和余辉特性的影响,结果表明随着H3BO3含量的增加,样品的发射光谱发生了“蓝移”现象,并随B^3+的掺入,Sr0.96 A12O4:0.04Eu^2+呈现出了长余辉特性,同时增强了样品的发光强度和余辉时间,最佳的H3BO3含量为15%,其余辉时间可以达到6h。  相似文献   

6.
为了规范长余辉材料余辉性能测试的标准化,采用屏幕亮度计测试了SrAl2O4:Eu^2+,Dy^3+长余辉材料的余辉性能;研究了激发光源、激发时间、样品粒度和用量对余辉性能测试的影响,结果表明在9W三基色灯下激发15min可使余辉材料发光亮度达到饱和,随着样品粒径增大和质量增加,发光强度明显增强,余辉时间也显著延长.  相似文献   

7.
采用尿素均相沉淀法合成超细Y2O3:Eu红色荧光粉,用各种方法对其中间物和最终产物进行表征,讨论了合成条件对Y2O3:Eu粒径、发光性能的关系,观察到均相沉淀法合成的Y2O3:Eu比常规固相反应法合成的Y2O3:Eu激活剂Eu^3 的临界浓度高得多,获得了平均粒径小于1μm,发光亮度与现商用品(d50=5.5μm)相当的亚微米级Y2O3:Eu红色荧光粉。  相似文献   

8.
采用高温固相法制备了Sr2MgSi2O7(SMS)、Sr2MgSi2O7:Eu^2+(SMS—E)和Sr2MgSi2O7:Eu^2+,Dy^3+(SMS—ED)粉末刑用XRD、荧光光谱仪、单光子计数器、热释光剂量计等手段对样品进行结构和发光性能分析.结果表明:所得样品的晶相结构基本一致,在发射光谱中,SMS-ED与SMS-E相比,没有明显的新发射光谱,且发光强度较弱,但余辉的亮度和余辉的时间却有了很大的提高.  相似文献   

9.
采用高温固相法制备了基质掺杂的(Y,Rn)2O2S:Sm3 ,Ti4 ,Mg2 (Rn=La,Gd,Lu,Ga,Al)红色长余辉材料,主峰均为4G5/2→6H7/2跃迁的红橙色光发射,不受基质掺杂的影响.余辉性能测试表明掺杂离子半径对余辉性能具有重要的影响:单掺时,与Y3 半径相近并略小时样品的余辉时间有正增长;双离子共掺时均为小半径的掺杂对余辉性能有显著的提高,其中之一半径较大时即具有负效应.并对可能存在的机理进行了初步探讨.  相似文献   

10.
利用低温燃烧法合成Y2O3:Eu^3+体相及纳米粉体材料,通过XRD图谱和电荷迁移(CT)激发光谱测定粉体的平均尺寸、电荷迁移能及CT激发光谱能量跨度。在理论分析与实验验证的基础上,探讨Y2O3:Eu^3+发光材料的纳米化对电荷迁移(CT)激发所需电荷迁移能的影响。结果表明:在Y2O3:Eu^3+材料发光中心CT激发的谐振子模型中,发光中心的振动频率ω(基态)及ω’(CT态)将随材料纳米尺寸的下降而下降;CT激发光谱能量跨度Espan以及CT激发中发光中心所获得的振动能量Evib将随CT态振动频率ω’的下降而下降;此外,基于发光中心零声子电荷迁移能Ezp以及发光中心振动能量Evib随Y2O3:Eu^3+纳米尺寸的下降幅度,求得CT激发所需电荷迁移能ECt的变化幅度,所得结果与实验测量值基本相符。该文揭示了Y2O3:Eu^3+材料纳米化后CT激发能的下降以及CT激发光谱能量跨度的收缩机理,具有一定的理论和实际意义。  相似文献   

11.
Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.  相似文献   

12.
何延凌 《科技信息》2008,(4):258-258
Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women's language from these perspectives: pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women's language, more attention should be paid to language use in social context. What's more, the linguistic phenomena in a speaking community can be understood more thoroughly.  相似文献   

13.
There are numerous geometric objects stored in the spatial databases. An importance function in a spatial database is that users can browse the geometric objects as a map efficiently. Thus the spatial database should display the geometric objects users concern about swiftly onto the display window. This process includes two operations:retrieve data from database and then draw them onto screen. Accordingly, to improve the efficiency, we should try to reduce time of both retrieving object and displaying them. The former can be achieved with the aid of spatial index such as R-tree, the latter require to simplify the objects. Simplification means that objects are shown with sufficient but not with unnecessary detail which depend on the scale of browse. So the major problem is how to retrieve data at different detail level efficiently. This paper introduces the implementation of a multi-scale index in the spatial database SISP (Spatial Information Shared Platform) which is generalized from R-tree. The difference between the generalization and the R-tree lies on two facets: One is that every node and geometric object in the generalization is assigned with a importance value which denote the importance of them, and every vertex in the objects are assigned with a importance value,too. The importance value can be use to decide which data should be retrieve from disk in a query. The other difference is that geometric objects in the generalization are divided into one or more sub-blocks, and vertexes are total ordered by their importance value. With the help of the generalized R-tree, one can easily retrieve data at different detail levels.Some experiments are performed on real-life data to evaluate the performance of solutions that separately use normal spatial index and multi-scale spatial index. The results show that the solution using multi-scale index in SISP is satisfying.  相似文献   

14.
理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。  相似文献   

15.
The discovery of the prolific Ordovician Red River reservoirs in 1995 in southeastern Saskatchewan was the catalyst for extensive exploration activity which resulted in the discovery of more than 15 new Red River pools. The best yields of Red River production to date have been from dolomite reservoirs. Understanding the processes of dolomitization is, therefore, crucial for the prediction of the connectivity, spatial distribution and heterogeneity of dolomite reservoirs.The Red River reservoirs in the Midale area consist of 3~4 thin dolomitized zones, with a total thickness of about 20 m, which occur at the top of the Yeoman Formation. Two types of replacement dolomite were recognized in the Red River reservoir: dolomitized burrow infills and dolomitized host matrix. The spatial distribution of dolomite suggests that burrowing organisms played an important role in facilitating the fluid flow in the backfilled sediments. This resulted in penecontemporaneous dolomitization of burrow infills by normal seawater. The dolomite in the host matrix is interpreted as having occurred at shallow burial by evaporitic seawater during precipitation of Lake Almar anhydrite that immediately overlies the Yeoman Formation. However, the low δ18O values of dolomited burrow infills (-5.9‰~ -7.8‰, PDB) and matrix dolomites (-6.6‰~ -8.1‰, avg. -7.4‰ PDB) compared to the estimated values for the late Ordovician marine dolomite could be attributed to modification and alteration of dolomite at higher temperatures during deeper burial, which could also be responsible for its 87Sr/86Sr ratios (0.7084~0.7088) that are higher than suggested for the late Ordovician seawaters (0.7078~0.7080). The trace amounts of saddle dolomite cement in the Red River carbonates are probably related to "cannibalization" of earlier replacement dolomite during the chemical compaction.  相似文献   

16.
王慧 《科技信息》2008,(10):240-240
Wuthering Heights, Emily Bronte's only novel, was published in December of 1847 under the pseudonym Ellis Bell. The book did not gain immediate success, but it is now thought one of the finest novels in the English language. Catherine is the key character of this masterpiece, because everybody and everything center on her though she had a short life. We can understand this masterpiece better if we know Catherine well.  相似文献   

17.
The Williston Basin is a significant petroleum province, containing oil production zones that include the Middle Cambrian to Lower Ordovician, Upper Ordovician, Middle Devonian, Upper Devonian and Mississippian and within the Jurassic and Cretaceous. The oils of the Williston Basin exhibit a wide range of geochemical characteristics defined as "oil families", although the geochemical signature of the Cambrian Deadwood Formation and Lower Ordovician Winnipeg reservoired oils does not match any "oil family". Despite their close stratigraphic proximity, it is evident that the oils of the Lower Palaeozoic within the Williston Basin are distinct. This suggests the presence of a new "oil family" within the Williston Basin. Diagnostic geochemical signatures occur in the gasoline range chromatograms, within saturate fraction gas chromatograms and biomarker fingerprints. However, some of the established criteria and cross-plots that are currently used to segregate oils into distinct genetic families within the basin do not always meet with success, particularly when applied to the Lower Palaeozoic oils of the Deadwood and Winnipeg Formation.  相似文献   

18.
As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.  相似文献   

19.
In the 19th century the society was controlled by men, and women were just appendants of them, they had not any rights and freedom. But Jane was an exception, she showed some characteristics of early feminist. Jane showed her characteristics of feminism in three aspects: rebellion, equality, and independence. These characteristics were helpful to her success, and feminism is the only way out for women of that time.  相似文献   

20.
The non-orthogonal localized molecular orbital(NOLMO)is the most localized representation of electronic degrees of freedom.As such,NOLMOs are thus potentially the most efficient for linear scaling calculations of electronic structures for large systems.However,direct ab initio calculations with NOLMO have not been fully implemented and widely used,partly because of the slow convergence issue in the optimization of NOLMO.We devel-  相似文献   

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