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1.
用吸光度线性扩展法测定镨、钕、钐.基于待测元素特征吸收峰下的吸光度在纪录仪上线性放大,提高了测定的灵敏度、准确度,扩大了测定浓度范围.分别选用的最大吸收波长是:λPr=444.7nm,λNd=794.2nm,λSm=401.7nm;吸光度相应峰高和浓度呈线性关系的范围是:Pr3+为(0.20~8.6)×10-6mol/L;Nd3+为(0.20~2.4)×10-6mol/L;Sm为(0.20~3.0)×10-5mol/L.在选用10cm比色皿时,测定灵敏度为:Pr3+为1.1μg/mlmm,Nd3+为0.22μg/mlmn,Sm3+为4.6μg/mlmm.待测元素与稀土杂质浓度比为51时无干扰,11时只有个别元素有一定干扰.  相似文献   

2.
克拉霉素胶囊溶出度的测定   总被引:3,自引:0,他引:3  
采用盐酸溶液(16.4mL稀盐酸→1000mL)为溶出介质可获得较pH5.0醋酸钠缓冲液更好的溶出结果.用硫酸显色法在482nm波长处测定,吸收度值重现性好,结果稳定.线性范围10~100μg/mL,r=0.9997(n=6);按测定浓度的80%,100%和120%的平均回收率分别为100.9%,100.9%和99.3%,RSD分别为0.25%,0.65%和0.33%(n=6).  相似文献   

3.
在pH3.5的HCl-NaAc缓冲溶液中,钯与柠檬黄形成1∶2的配合物.在溴代十六烷基三甲铵(CTMAB)存在下,配合物的最大吸收波长为531nm,ε为1.9×104L/(mol·cm).采用1cm和3cm吸收池测定时,钯含量分别在0~1μg/mL和0~0.6μg/mL范围内服从比尔定律.方法检测限为0.068mg/L,重现性好,选择性高,适于合成矿样及钯催化剂中钯的测定  相似文献   

4.
酶光度分析法测定痕量亚硫酸盐   总被引:5,自引:0,他引:5  
在pH=3.6的NaAc-HAc介质和亚硫酸盐氧化酶存在下,亚硫酸盐被氧化成SO4^2-及H2O2,在过氧化氢氧化酶作用下,用3,3',5,5'-四甲基联苯胺(TMB)显色,在650nm波长下间接测定亚硫酸盐的含量,线性范围为0.15~20μg/mL,可用于食品中亚硫酸盐的测定。  相似文献   

5.
报道了聚氧化乙烯交联3-氨基丙基混合功能基固定相在体液直接进样HPLC分析中的应用测定了人尿中的肌酐和尿酸流动相为001mol/L磷酸盐缓冲液/10%甲醇,pH481检测波长235nm测定尿酸和肌酐的线性范围分别为3ng/mL—10μg/mL和2ng/mL—10μg/mL,精密度分别为20%和30%,回收率分别为963%和1020%  相似文献   

6.
萘啶酮酸体系导数荧光法测定铥,铽   总被引:1,自引:0,他引:1  
在PH7.5、3.0*10^-4mol/L萘啶酮酸溶液、激发波长为280nm的最佳条件下,采用一阶导数荧光技术,在荧光波长476nm处测定Tm^3+、在540nm处测定Tb^3+。由于采用导数荧光技术,不但消除了Tb^3+荧光峰对测定Tm^3+的干扰,使Tm^3+、Tb^3+的同时测定成为可能,还显著提高了Tm^3+的灵敏度,使Tm^3+的检测限达到0.01μg/mL。  相似文献   

7.
关于盐酸米诺环素胶囊溶出度测定方法和标准修订.采用紫外法,以水为溶剂,检测波长为(346±2)nm,在5~30μg/mL浓度范围内有良好线性关系(r=0.9999).平均回收率为(100.6±0.58)%,测定浓度为15μg/mL.在此条件下可得准确的结果.  相似文献   

8.
采用高效液相色谱法(HPLC)对复方康希力胶囊中氨苄青霉素和邻氯青霉素进行测定。以醋酸盐缓冲液(pH=4.5)-甲醇(55:45)为流动相,流速为1.0mL/min;YWG-C_(18)(10μm)为固定相;乙酰苯胺为内标;检测波长为254nm。氨苄青霉素、内标物和邻氯青霉素的保留时间分别为3,0、5.5和9.0min。氨苄青霉素和邻氯青霉素的回收率(n=5)分别为100.3%(RSD=0.37%)和100.9%(RSD=0.43%)。两种组分的最低检出浓度为5μg/mL。  相似文献   

9.
使用反外HPLC法测定3H状元胶囊中的1α-羟基维生素D3,固定相为C18,流动相为乙腈:水(97:3),测定波长为265nm标样线性范围为0.1~1.0μg/mL(r=0.9988,n=5)最低检出率为0.5ng,天内天间精密度分别为1.41%(n=10)和2.72%(n=3)平均回收率为99.1%(RSD=2.78%),该方法用于测定3H求元胶囊的1α-羟基维生素D3,取得较满意的结果。  相似文献   

10.
本文提出双体系双波长荧光测定方法,用于色氨酸,酪氨酸的同时测定,结果满意,测定范围分别为0 ̄10.0μg/mL和0 ̄5.0μg/mL。  相似文献   

11.
Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.  相似文献   

12.
何延凌 《科技信息》2008,(4):258-258
Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women's language from these perspectives: pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women's language, more attention should be paid to language use in social context. What's more, the linguistic phenomena in a speaking community can be understood more thoroughly.  相似文献   

13.
The discovery of the prolific Ordovician Red River reservoirs in 1995 in southeastern Saskatchewan was the catalyst for extensive exploration activity which resulted in the discovery of more than 15 new Red River pools. The best yields of Red River production to date have been from dolomite reservoirs. Understanding the processes of dolomitization is, therefore, crucial for the prediction of the connectivity, spatial distribution and heterogeneity of dolomite reservoirs.The Red River reservoirs in the Midale area consist of 3~4 thin dolomitized zones, with a total thickness of about 20 m, which occur at the top of the Yeoman Formation. Two types of replacement dolomite were recognized in the Red River reservoir: dolomitized burrow infills and dolomitized host matrix. The spatial distribution of dolomite suggests that burrowing organisms played an important role in facilitating the fluid flow in the backfilled sediments. This resulted in penecontemporaneous dolomitization of burrow infills by normal seawater. The dolomite in the host matrix is interpreted as having occurred at shallow burial by evaporitic seawater during precipitation of Lake Almar anhydrite that immediately overlies the Yeoman Formation. However, the low δ18O values of dolomited burrow infills (-5.9‰~ -7.8‰, PDB) and matrix dolomites (-6.6‰~ -8.1‰, avg. -7.4‰ PDB) compared to the estimated values for the late Ordovician marine dolomite could be attributed to modification and alteration of dolomite at higher temperatures during deeper burial, which could also be responsible for its 87Sr/86Sr ratios (0.7084~0.7088) that are higher than suggested for the late Ordovician seawaters (0.7078~0.7080). The trace amounts of saddle dolomite cement in the Red River carbonates are probably related to "cannibalization" of earlier replacement dolomite during the chemical compaction.  相似文献   

14.
理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。  相似文献   

15.
There are numerous geometric objects stored in the spatial databases. An importance function in a spatial database is that users can browse the geometric objects as a map efficiently. Thus the spatial database should display the geometric objects users concern about swiftly onto the display window. This process includes two operations:retrieve data from database and then draw them onto screen. Accordingly, to improve the efficiency, we should try to reduce time of both retrieving object and displaying them. The former can be achieved with the aid of spatial index such as R-tree, the latter require to simplify the objects. Simplification means that objects are shown with sufficient but not with unnecessary detail which depend on the scale of browse. So the major problem is how to retrieve data at different detail level efficiently. This paper introduces the implementation of a multi-scale index in the spatial database SISP (Spatial Information Shared Platform) which is generalized from R-tree. The difference between the generalization and the R-tree lies on two facets: One is that every node and geometric object in the generalization is assigned with a importance value which denote the importance of them, and every vertex in the objects are assigned with a importance value,too. The importance value can be use to decide which data should be retrieve from disk in a query. The other difference is that geometric objects in the generalization are divided into one or more sub-blocks, and vertexes are total ordered by their importance value. With the help of the generalized R-tree, one can easily retrieve data at different detail levels.Some experiments are performed on real-life data to evaluate the performance of solutions that separately use normal spatial index and multi-scale spatial index. The results show that the solution using multi-scale index in SISP is satisfying.  相似文献   

16.
王慧 《科技信息》2008,(10):240-240
Wuthering Heights, Emily Bronte's only novel, was published in December of 1847 under the pseudonym Ellis Bell. The book did not gain immediate success, but it is now thought one of the finest novels in the English language. Catherine is the key character of this masterpiece, because everybody and everything center on her though she had a short life. We can understand this masterpiece better if we know Catherine well.  相似文献   

17.
The Williston Basin is a significant petroleum province, containing oil production zones that include the Middle Cambrian to Lower Ordovician, Upper Ordovician, Middle Devonian, Upper Devonian and Mississippian and within the Jurassic and Cretaceous. The oils of the Williston Basin exhibit a wide range of geochemical characteristics defined as "oil families", although the geochemical signature of the Cambrian Deadwood Formation and Lower Ordovician Winnipeg reservoired oils does not match any "oil family". Despite their close stratigraphic proximity, it is evident that the oils of the Lower Palaeozoic within the Williston Basin are distinct. This suggests the presence of a new "oil family" within the Williston Basin. Diagnostic geochemical signatures occur in the gasoline range chromatograms, within saturate fraction gas chromatograms and biomarker fingerprints. However, some of the established criteria and cross-plots that are currently used to segregate oils into distinct genetic families within the basin do not always meet with success, particularly when applied to the Lower Palaeozoic oils of the Deadwood and Winnipeg Formation.  相似文献   

18.
As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.  相似文献   

19.
In the 19th century the society was controlled by men, and women were just appendants of them, they had not any rights and freedom. But Jane was an exception, she showed some characteristics of early feminist. Jane showed her characteristics of feminism in three aspects: rebellion, equality, and independence. These characteristics were helpful to her success, and feminism is the only way out for women of that time.  相似文献   

20.
The non-orthogonal localized molecular orbital(NOLMO)is the most localized representation of electronic degrees of freedom.As such,NOLMOs are thus potentially the most efficient for linear scaling calculations of electronic structures for large systems.However,direct ab initio calculations with NOLMO have not been fully implemented and widely used,partly because of the slow convergence issue in the optimization of NOLMO.We devel-  相似文献   

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