氧化锌矿物浸出渣中铅、锶的提取及动力学分析

NH₄HCO₃ conversion followed by HCl leaching was performed and proven to be effective in extracting Pb and Sr from zinc extracted residual. The mechanism and operating conditions of NH₄HCO₃ conversion, including molar ratio of NH₄HCO₃ to zinc extracted residual, NH₄HCO₃ concentration, conversion temperature, conversion time, and stirring velocity, were discussed, and operating conditions were optimized by the orthogonal test. Experimental results indicate that NH₄HCO₃ conversion at temperatures ranging from 25 to 85°C follows the shrinking unreacted core model and is controlled by inner diffusion through the product layer. The extraction ratios of Pb and Sr under optimized conditions reached 85.15% and 87.08%, respectively. Moreover, the apparent activation energies of Pb and Sr were 13.85 and 13.67 kJ·mol?1, respectively.     

基于响应曲面法的铁焦冶金性能多目标协同优化

Iron carbon agglomerates (ICA) are used to realize low-carbon blast furnace ironmaking. In this study, the central composite design based on response surface methodology was used to synergistically optimize the compressive strength, reactivity, and post-reaction strength of ICA. Results show that the iron ore addition ratio significantly influences the compressive strength, reactivity, and post-reaction strength of ICA. The iron ore addition ratio and carbonization temperature or the iron ore addition ratio and carbonization time exert significant interaction effects on the compressive strength and reactivity of ICA, but it has no interaction effects on the post-reaction strength of ICA. In addition, the optimal process parameters are as follows: iron ore addition ratio of 15.30wt%, carbonization temperature of 1000°C, and carbonization time of 4.27 h. The model prediction results of compressive strength, reactivity, and post-reaction strength are 4026 N, 55.03%, and 38.24%, respectively, which are close to the experimental results and further verify the accuracy and reliability of the models.     

皮秒Nd:YAG激光对生物金属纯Ti和Ti–13Nb–13Zr合金的表面改性

The effects of picosecond Nd:YAG laser irradiation on chemical and morphological surface characteristics of the commercially pure titanium and Ti–13Nb–13Zr alloy in air and argon atmospheres were studied under different laser output energy values. During the interaction of laser irradiation with the investigated materials, a part of the energy was absorbed on the target surface, influencing surface modifications. Laser beam interaction with the target surface resulted in various morphological alterations, resulting in crater formation and the presence of microcracks and hydrodynamic structures. Moreover, different chemical changes were induced on the target materials’ surfaces, resulting in the titanium oxide formation in the irradiation-affected area and consequently increasing the irradiation energy absorption. Given the high energy absorption at the site of interaction, the dimensions of the surface damaged area increased. Consequently, surface roughness increased. The appearance of surface oxides also led to the increased material hardness in the surface-modified area. Observed chemical and morphological changes were pronounced after laser irradiation of the Ti–13Nb–13Zr alloy surface.     

汽车用废弃锂离子电池的减量化、再生及回收研究进展

The demand for Li-ion batteries (LIBs) for vehicles is increasing. However, LIBs use valuable rare metals, such as Co and Li, as well as environmentally toxic reagents. LIBs are also necessary to utilize for a long period and to recycle useful materials. The reduction, reuse, and recycle (3R) of spent LIBs is an important consideration in constructing a circular economy. In this paper, a flowsheet of the 3R of LIBs is proposed and methods to reduce the utilization of valuable rare metals and the amount of spent LIBs by remanufacturing used parts and designing new batteries considering the concept of 3R are described. Next, several technological processes for the reuse and recycling of LIBs are introduced. These technologies include discharge, sorting, crushing, binder removal, physical separation, and pyrometallurgical and hydrometallurgical processing. Each process, as well as the related physical, chemical, and biological treatments, are discussed. Finally, the problem of developed technologies and future subjects for 3R of LIBs are described.     

传统加热和微波加热下氧化锰矿的碳热还原行为研究

For the purpose of exploring a potential process to produce FeMn, the effects of microwave heating on the carbothermal reduction characteristics of oxidized Mn ore was investigated. The microwave heating curve of the mixture of oxidized Mn ore and coke was analyzed in association with the characterization of dielectric properties. The comparative experiments were conducted on the carbothermal reductions through conventional and microwave heatings at temperatures ranging from 973 to 1373 K. The thermogravimetric analysis showed that carbothermal reactions under microwave heating proceeded to a greater extent and at a faster pace compared with those under conventional heating. The metal phases were observed in the microstructures only under microwave heating. The carbothermal reduction process under microwave heating was discussed. The electric and magnetic susceptibility differences were introduced into the thermodynamics analysis for the formation of metal Mn. The developed thermodynamics considered that microwave heating could make the reduction of MnO to Mn more accessible and increase the reduction extent.     

机械合金化法制备的Cu/SiC纳米复合材料的组织、热性能和力学性能评估

Nano-sized silicon carbide (SiC: 0wt%, 1wt%, 2wt%, 4wt%, and 8wt%) reinforced copper (Cu) matrix nanocomposites were manufactured, pressed, and sintered at 775 and 875°C in an argon atmosphere. X-ray diffraction (XRD) and scanning electron microscopy were performed to characterize the microstructural evolution. The density, thermal expansion, mechanical, and electrical properties were studied. XRD analyses showed that with increasing SiC content, the microstrain and dislocation density increased, while the crystal size decreased. The coefficient of thermal expansion (CTE) of the nanocomposites was less than that of the Cu matrix. The improvement in the CTE with increasing sintering temperature may be because of densification of the microstructure. Moreover, the mechanical properties of these nanocomposites showed noticeable enhancements with the addition of SiC and sintering temperatures, where the microhardness and apparent strengthening efficiency of nanocomposites containing 8wt% SiC and sintered at 875°C were 958.7 MPa and 1.07 vol%?1, respectively. The electrical conductivity of the sample slightly decreased with additional SiC and increased with sintering temperature. The prepared Cu/SiC nanocomposites possessed good electrical conductivity, high thermal stability, and excellent mechanical properties.     

空冷条件下钛渣颗粒的氧化路径及氧化动力学

The oxidation pathway and kinetics of titania slag powders in air were analyzed using differential scanning calorimetry (DSC) andthermogravimetry (TG). The oxidation pathway of titania slag powder in air was divided into three stages according to their three exothermic peaks and three corresponding mass gain stages indicated by the respective non-isothermal DSC and TG curves. The isothermal oxidation kin-etics of high titania slag powders of different sizes were analyzed using the ln-ln analysis method. The results revealed that the entire isotherm-al oxidation process comprises two stages. The kinetic mechanism of the first stage can be described as f (α)=1.77 (1?α) [?ln (1?α)](1.77?1)/1.77 , f (α)=1.97 (1?α) [?ln (1?α)](1.97?1)/1.97 , and f (α)=1.18 (1?α) [?ln (1?α)](1.18?1)/1.18 . The kinetic mechanism of the second stage for all samples can be described as f (α)=1.5(1?α)2/3[1?(1?α)1/3]?1 . The activation energies of titania slag powders with different sizes (d1 < 0.075 mm, 0.125 mm < d2 < 0.150 mm, and 0.425 mm < d3 < 0.600 mm) for different reaction degrees were calculated. For the given experimental conditions, the rate-controlling step in the first oxidation stage of all the samples is a chemical reaction. The rate-controlling steps of the second oxidation stage are a chemical reaction and internal diffusion (for powders d1 < 0.075 mm) and internal diffusion (for powders 0.125 mm < d2 <0.150 mm and 0.425 mm < d3 < 0.600 mm).     

Morphology control of aluminum nitride (AlN) for a novel high-temperature hydrogen sensor

Hydrogen is a promising renewable energy source for fossil-free transportation and electrical energy generation. However, leaking hydrogen in high-temperature production processes can cause an explosion, which endangers production workers and surrounding areas. To detect leaks early, we used a sensor material based on a wide bandgap aluminum nitride (AlN) that can withstand a high-temperature environment. Three unique AlN morphologies (rod-like, nest-like, and hexagonal plate-like) were synthesized by a direct nitridation method at 1400°C using γ-AlOOH as a precursor. The gas-sensing performance shows that a hexagonal plate-like morphology exhibited p-type sensing behavior and showed good repeatability as well as the highest response (S = 58.7) toward a 750 ppm leak of H₂ gas at high temperature (500°C) compared with the rod-like and nest-like morphologies. Furthermore, the hexagonal plate-like morphology showed fast response and recovery times of 40 and 82 s, respectively. The surface facet of the hexagonal morphology of AlN might be energetically favorable for gas adsorption–desorption for enhanced hydrogen detection.     

铝基复合材料界面Al?Ce?Cu?W非晶层的热驱动固相非晶化研究

Interfacial Al?Ce?Cu?W amorphous layers formed through thermally driven solid-state amorphization within the (W+CeO₂)/2024Al composite were investigated. The elemental distributions and interfacial microstructures were examined with an electron probe microanalyzer and a high-resolution transmission electron microscope, respectively. The consolidation of composites consisted of two thermal processes: vacuum degassing (VD) and hot isostatic pressing (HIP). During consolidation, not only the three major elements (Al, W, and Ce) but also the alloying elements (Mg and Cu) in the Al matrix contributed to amorphization. At VD and HIP temperatures of 723 K and 763 K, interfacial amorphous layers were formed within the composite. Three diffusion processes were necessary for interfacial amorphization: (a) long-range diffusion of Mg from the Al matrix to the interfaces during VD; (b) long-range diffusion of Cu from the Al matrix to the interfaces during HIP; (c) short-range diffusion of W toward the Al matrix during HIP. The newly formed interfacial Al?Ce?Cu?W amorphous layers can be categorized under the Al?Ce?TM (TM: transition metals) amorphous system.     

细粒夹层对尾矿坝毛细带水分迁移的影响

Small-particle interlayers (lenticles) show some characteristic hydraulic properties and can affect the movement of unsaturated water. In this study, we developed a novel online capillary-water-absorption monitoring device and conducted three groups of comparison tests to simulate lenticle positions and thicknesses with respect to the capillary rise. The results show that the characteristic wetting front exhibits a fast rise in the early stage, a slow rise in the middle stage, and stability in the later stage. The motion of the capillary water in the lenticle is mainly transversal, with the upward curve being “flat,” and the longer is “flat,” the longer is the time needed for the water to move. The interlayer can form a capillary stagnation zone with moisture content close to saturation. The high interlayer may form a discontinuous corrugated capillary zone. Thus, when the wetting front reaches the “coarse-grain (lower)?fine-grain (upper)” interface, the “anti-capillary barrier effect” results in more moisture in the upper layer. Thus, when the wetting front of the capillary water reaches the “fine-grain (upper)?coarse-grain (lower)” interface, the “capillary barrier effect” causes the moisture content of the upper tailings to decreases sharply because of the horizontal movement of the water in the fine medium. It is clear that the presence of lenticles can retard the rise of capillary water by storing water.     

Changes of climate extremes of temperature and precipitation in summer in eastern China associated with changes in atmospheric circulation in East Asia during 1960–2008

Climate extremes and changes in eastern China are closely related to variations of the East Asian summer monsoon and corresponding atmospheric circulations.The relationship between frequencies of temperature and precipitation extremes in China during the last half century is investigated using Singular Value Decomposition analysis.During 1980-1996,there was a typical pattern with fewer hot days and more precipitation extremes in the northern part of eastern China,and more hot days and fewer precipitation extremes in the southern part.This geographic pattern tended to reverse after 1997,with fewer hot days and more extreme precipitation days south of the Yangtze River and vice versa to the north.Differences in atmospheric circulation between the former and latter periods are presented.We conclude that a mid-level anomalous high/low,upper-level anomalous easterlies/westerlies over the north/south of eastern China,a weakened East Asian summer monsoon and associated upper-tropospheric center of cooling(30°N,110°E) are all favorable for the changes in frequencies of temperature and precipitation extremes.     

青藏高原积雪异常对亚洲夏季风气候的影响

为了研究青藏高原积雪异常对亚洲夏季风气候的影响,从季风环流和季风降水等方面综合分析了高原积雪异常对气候的影响,并利用IAP 9L AGCM模式,对高原雪量进行了增加和减少的数值试验。从而提出高原多(少)雪年南亚夏季风偏弱(强),东亚夏季风反而偏强(弱)的新观点。高原积雪异常会导致高原上空大气垂直运动的扰动,扰动传播到下游致使我国长江流域和西太副高所在区域大气对流运动发生变化。高原多(少)雪,夏季我国南方的偏南风增强(减弱),有利于水汽从孟加拉湾和南海向我国大陆输送,但到长江流域时,由于偏南风存在较强(弱)的辐合,江淮流域偏涝(旱)。     

Characteristics of decadal-centennial-scale changes in East Asian summer monsoon circulation and precipitation during the Medieval Warm Period and Little Ice Age and in the present day

Using meteorological observations, proxies of precipitation and temperature, and climate simulation outputs, we synthetically analyzed the regularities of decadal-centennial-scale changes in the summer thermal contrast between land and ocean and summer precipitation over the East Asian monsoon region during the past millennium; compared the basic characteristics of the East Asian summer monsoon (EASM) circulation and precipitation in the present day, the Little Ice Age (LIA) and the Medieval Warm Period (MWP); and explored their links with solar irradiance and global climate change. The results indicate that over the last 150 years, the EASM circulation and precipitation, indicated by the temperature contrast between the East Asian mainland and adjacent oceans, had a significant decadal perturbation and have been weaker during the period of rapid global warming over the past 50 years. On the centennial time scale, the EASM in the MWP was strongest over the past 1000 years. Over the past 1000 years, the EASM was weakest in 1450?C1570. When the EASM circulation was weaker, the monsoon rain belt over eastern China was generally located more southward, with there being less precipitation in North China and more precipitation in the Yangtze River valley; therefore, there was an anomalous pattern of southern flood/northern drought. From the 1900s to 1920s, precipitation had a pattern opposite to that of the southern flood/northern drought, with there being less precipitation in the Yangtze River valley and more precipitation in North China. Compared with the case for the MWP, there was a longer-time-scale southern flood/northern drought phenomenon in 1400?C1600. Moreover, the EASM circulation and precipitation did not synchronously vary with the trend of global temperature. During the last 150 years, although the annual mean surface temperature around the world and in China has increased, the EASM circulation and precipitation did not have strengthening or weakening trends. Over the past 1000 years, the weakest EASM occurred ahead of the lowest Northern Hemispheric temperature and corresponded to the weakest solar irradiance.     

大气环流对冬季黑潮延伸体海温异常的响应

利用全球大气环流模式CAM3,研究了冬季北半球大气环流和东亚副热带西风急流对同期黑潮延伸体海温异常增暖响应的敏感性及东亚西风急流的响应机理.结果表明,模式能较好地刻画冬季黑潮延伸体海温异常增暖导致的北半球大气环流异常,特别是中纬地区大气环流异常“+、-”相问的分布特征.中高纬是大气对冬季黑潮延伸体海温异常响应的敏感区,...     

Identifying the northernmost summer monsoon location in East Asia

An integrated index which can be used to indicate the advance of subtropical summer monsoon in East Asia has been proposed in this paper.The index was comhined by three variables including precipitation,wind and pseudo-equivalent potential tempera- ture.The northernmost summer monsoon location(NSML)was identified by using this index annually.It was found that the NSML ex- perienced an interdecadal shift in the period 1977—1979 based on the annual index analysis from 1961 to 2001.A comparison of the NSML with other four summer monsoon indices has also been made.The result showed that the NSML could well represent the interan- nual and interdecadal variability of summer monsoon precipitation in North China(beyond 35°N),while other four indices could well indi- cate the precipitation anomalies of East Asian summer monsoon along the Yangtze River valley(around 30°N).     

Sea surface temperature east of Australia： A predictor of tropical cyclone frequency over the western North Pacific？

The relationship between sea surface temperature (SST) east of Australia and tropical cyclone frequency over the western North Pacific (WNPTCF) is analyzed by use of observation data.The WNPTCF from June to October is correlated negatively to spring SST east of Australia.When the spring SST is in the positive phase,a cyclonic circulation anomaly in the upper troposphere and an anticyclonic circulation anomaly in the lower troposphere prevail over the western North Pacific from June to October,concurrent with an anomalous atmospheric subsidence and an enlarged vertical zonal wind shear.These conditions are unfavorable for tropical cyclone genesis,and thus WNPTCF decreases.The negative phase of the spring SST east of Australia leads to more tropical cyclones over the western North Pacific.The spring SST east of Australia may give rise to simultaneous change in tropical atmospheric circulation via the teleconnection wave train,and then subsequently affect atmospheric circulation variation over the western North Pacific.     

江淮流域夏季降水异常及与全球中低纬海温异常关系的诊断研究

对1951－1999年中国夏季江淮流域降水异常与海温异常关系的分析表明,前期及同期各季节三大洋海表温度异常（SSTA）与长江流域降水异常的关系是非常显著的,而对淮河流域降水异常总体上的影响较小,前期冬季SSTA的影响显著区主要有：热带印度洋、黑潮、热带中东太平洋和大西洋,各关键区海温异常对亚洲夏季风的影响特征为：当前期冬季赤道印度洋、黑潮、赤道大西洋和热带东太平洋海表温度异常升高（降低）,当年夏季印度西南季风和东亚热带辐合带减弱（加强）,副热带高压位置偏南（北）,副热带辐合带加强（减弱）,长江流域易发生洪涝（干旱）,相关显著性分析表明,前冬赤道印度洋和黑潮区的海温异常对中国夏季降水的影响更为显著。     

Interdecadal variations of the East Asian winter surface air temperature and possible causes

Using the NCEP/NCAR and JRA-25 monthly analysis data from 1979 to 2011, this paper analyzes the interdecadal variations of winter (Dec.–Feb.) mean surface air temperature (SAT) over East Asia by means of the empirical orthogonal function (EOF) analysis method. Two dominant modes were extracted, with the leading mode basically depicting a sign consistent SAT variation and the second mode describing a meridional dipole structure between the northern and southern parts of East Asia. These two modes can explain more than 60% of the variance. The leading mode is closely related to the intensity of Siberian high and the East Asian winter monsoon. The second mode exhibits a notable interdecadal shift in the late 1990s, with a turning point around 1996/1997. Winter SAT in the northern (southern) part of East Asia tends to be cooler (warmer) since the late 1990. Winter sea level pressure (SLP) differences between 1997–2011 and 1979–1996 show negative (positive) anomalies over southern (northern) Eurasia. At 500-hPa, an anomalous blocking high occurs over northern Eurasia, while a cyclone anomaly appears over northern East Asia. In addition, the upper-level East Asian jet stream tends to shift northward and become stronger after the late 1990. Indeed, the interdecadal shift of winter SAT over East Asia is dynamical consistent with changes of the large-scale atmospheric circulation in the late 1990s. The result indicates that previous autumn sea surface temperature (SST) in the North Atlantic Ocean, the Northern Indian Ocean and the western North Pacific Ocean, as well as sea ice concentration (SIC) in the northern Eurasia marginal seas and the Beaufort Sea also experienced obvious changes in the late 1990s. In particular, the interdecadal shifts of both SST in the North Atlantic Ocean and SIC in the Arctic Ocean and its marginal seas are well coherent with that of the winter SAT over East Asia. The results indicate that the interdecadal shift of East Asian winter SAT may be related to changes in the North Atlantic SST and the Arctic SIC in the late 1990s.     

Interdecadal change of summer precipitation over Eastern China around the late-1990s and associated circulation anomalies, internal dynamical causes

Observational study indicated that the summer precipitation over Eastern China experienced a notable interdecadal change around the late-1990s. Accompanying this interdecadal change, the dominant mode of anomalous precipitation switched from a meridional triple pattern to a dipole pattern, showing a "south-flood-north-drought" structure (with the exception of the Yangtze River Valley). This interdecadal change of summer precipitation over Eastern China was associated with circulation anomalies in the middle/upper troposphere over East Asia, such as changes in winds and corresponding divergence, vertical motion and moisture transportation (divergence), which all exhibit remarkable meridional dipole structures. Furthermore, on the internal dynamic and thermodynamic aspects, the present study investigated the influence of the midtroposphere zonal and meridional flow changes over East Asia on the interdecadal change around the late-1990s. Results suggested that, during 1999-2010, the East Asia subtropical westerly jet weakened and shifted poleward, forming a meridional dipole feature in anomalous zonal flow. This anomalous zonal flow, on one hand, induced changes in three teleconnection patterns over the Eurasian continent, namely the "Silk Road" pattern along the subtropical upper troposphere westerly jet, the East Asia/Pacific (EAP) pattern along the East Asian coast, and the Eurasia (EU) pattern along the polar jet; on the other hand, it brought about cold advection over Northern China, and warm advection over Southern China in the mid-troposphere. Through these two ways, the changes in the zonal flow induced descent over Northern China and ascent over Southern China, which resulted in the anomalous "south-flood-north-drought" feature of the summer precipitation over Eastern China during 1999-2010.     

青藏高原冬季积雪异常对东、南亚夏季风影响的初步数值模拟研究

利用一个耦合了简化的简单生物圈模式的大气环流谱模式（ＳＳｉＢ－ＧＣＭ），初步探讨了青藏高原冬季积雪异常对东、南亚夏季风环流和降水的影响及其机理。结果表明，高原地区冬季积雪增加将使随后的夏季东、南亚季风明显减弱，主要表现为东、南亚季风区降水减少，索马里急流、印度季风槽和印度西南气流减弱。另外，还提出欧亚大陆雪盖与整个高原雪盖和高原东部雪盖对东、南亚夏季风影响的敏感性问题。与欧亚大陆雪盖相比，高原雪盖是影响东、南亚季风的更敏感区，冬季高原以外雪盖增加，有可能使亚洲季风增强；当高原东部雪盖增加时，高原以东地区及印支半岛降水减少，印度东部、南部和孟加拉湾西北部降水反而增加