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1.
利用离子注入然后退火的方法制备镶嵌有锗纳米晶的二氧化硅复合膜,再利用中子嬗变方法,对镶嵌有锗纳米晶的二氧化硅复合膜进行精确均匀掺杂,用激光拉曼散射测量表征锗纳米晶的存在,测量嬗变掺杂前后样品的I-U曲线和lnR-1/T曲线.结果表明:掺杂样品未退火时电阻极大,退火后电阻明显减小,但比未掺杂时大;其它条件相同时,锗的注入量越大,纳米晶层的电阻越小;在掺杂样品的低温I-U曲线中发现台阶.  相似文献   

2.
采用离子注入法及退火工艺,在硅基二氧化硅薄膜中制备了镶嵌结构的天然Ge纳米晶样品. 通过退火实验研究,发现随着退火温度的升高,纳米晶的晶态峰峰位红移,这意味着Ge纳米晶受到的应力减小. 当退火温度达到 700 ℃时,纳米晶的晶态峰强度显著增强,而且薄膜中与Ge有关的缺陷发光减弱. 采用中子嬗变掺杂法对天然Ge纳米晶进行了掺杂,X射线荧光光谱数据表明,样品中成功的引入了Ga杂质和As杂质. 薄膜中形成的与Ge有关的缺陷具有稳定的结构,中子辐照之后其发光仍然存在,而且,掺杂后的样品中没有发现与Ga或As有关的  相似文献   

3.
采用射频磁控技术,用Ge、SiO_2的复合靶制备锗纳米晶镶嵌在二氧化硅中的复合薄膜.作为量子点的Ge纳米晶粒的尺寸是决定这类材料物性的关键,因而研究对镶嵌在SiO_2中的Ge晶粒尺寸调制的工艺十分重要.本文研究了制备过程中各种工艺参数与薄膜中Ge晶粒尺寸的关系.结果表明通过溅射时控制基片温度能有效地对锗晶粒尺寸进行调制.  相似文献   

4.
利用磁控溅射方法在单晶硅基片上制备出不同Al含量AlCN非晶薄膜,随后分别在700℃和1000℃进行真空退火热处理.使用X射线衍射仪和高分辨透射电镜研究了沉积态和退火态薄膜的组织和微观结构,用纳米压痕仪测试硬度和弹性模量.结果表明,退火态薄膜组织和微观结构强烈依赖于薄膜的Al含量.经1000℃退火后,低Al含量AlCN薄膜没有出现结晶现象,但形成了分层;高Al含量AlCN薄膜中,退火促使AlN纳米晶的生成,使薄膜形成了非晶包裹纳米晶的复合结构,随着距表面深度的增加,形成的纳米晶密度和尺寸均有减小的趋势.随着退火温度的升高,AlCN薄膜的硬度和弹性模量均降低;而对于高Al含量AlCN薄膜,由于形成了纳米复合结构,硬度和弹性模量下降幅度减少.  相似文献   

5.
采用射频磁控溅射技术和热退火处理方法制备纳米锗镶嵌二氧化硅( Ge-SiO2)薄膜.利用光吸收谱和X射线衍射谱对薄膜材料进行表征,得到薄膜的光学带隙为1.12 eV,纳米Ge晶粒的平均尺寸约为16.4 nm.将纳米Ge-SiO2薄膜作为可饱和吸收体插入激光二极管泵浦的平-凹腔Nd∶YVO4激光器内,实现1 342 nm...  相似文献   

6.
采用MEVVA离子源强束流离子注入机,将稀土Er离子注入单晶硅、Si和Er离子双注入单晶硅及热氧化硅,Er在硅基薄膜中的掺杂原子分数可达10%,即数密度约10^21cm^-3,注入态样品快速退火后有纳米晶Si形成;77K和室温时用441.6nm光激发有Er^3 较强的1.54μm特征发光发射,探讨了在硅基材料中高浓度Er掺杂薄膜中纳米结构的形成与Er^3 的光致发光性能。  相似文献   

7.
以Zn(NO3)2.6H2O和(NH2)2CO为源物质,通过水热法以及退火工艺,在F:SnO2(FTO)导电玻璃表面制备了ZnO介孔纳米片薄膜.XRD表征结果表明,经由水热法直接生长在导电玻璃表面的薄膜为Zn(CO3)x(OH)y.nH2O,属于底心单斜晶体结构;经过退火以后,Zn(CO3)x(OH)y.nH2O转变成六角纤锌矿结构ZnO.能谱测量结果也佐证了这一点.扫描电子显微镜(SEM)图像表明,退火后得到的ZnO薄膜为垂直于导电玻璃表面的纳米片结构,纳米片表面密布着纳米尺度的孔洞.在FTO导电玻璃表面直接制备的ZnO介孔纳米片结构可望提高染敏电池光伏性能,是一种有潜力的工作电极结构材料.  相似文献   

8.
铝诱导晶化(AIC)法是一种低成本、低温制备高质量多晶硅薄膜的方法.采用磁控溅射和自然氧化法在石英衬底上生长铝/三氧化二铝/非晶硅结构的材料,然后进行低温(低于硅铝共熔温度577℃)退火处理.通过共焦显微镜、扫描电子显微镜(SEM)、拉曼光谱(Raman)和X射线衍射(XRD)手段进行表征.结果表明,退火后薄膜分为两层,上层是铝、非晶硅和多晶硅的连续混合膜,随退火时间增加,上层晶化率快速增加;下层形成了完全晶化的大尺寸多晶硅晶粒,晶粒结晶质量接近单晶硅;增加退火时间,下层晶粒增长很缓慢;降低退火温度,下层晶粒尺寸明显增大;形成的多晶硅薄膜均具有高度(111)择优取向.并且,进一步地对上述退火过程中样品的变化行为作出分析.  相似文献   

9.
纳米薄膜是指纳米晶粒构成的薄膜,或将纳米晶粒镶嵌于某种薄膜中构成的复合膜,以及每层厚度在纳米量级的单层或多层膜。其性能强烈依赖于晶粒(颗粒)尺寸、膜的厚度、表面粗糙度及多层膜的结构。与普通薄膜相比,纳米薄膜具有许多独特的性能,例如巨电导效应、巨磁电阻效应、巨霍尔效应、可见光发射等。目前制备纳米薄膜的方法很多,其中水热法是很重要的一种。本论文利用水热法以金属锌片作为基片和反应物,加入尿素和NaH2PO4·2H2O或Zn(H2PO4)2·2H2O,以CTAB或OP作为表面活性剂,制备出由菱柱状、块状和片状微米晶组成的磷酸锌薄膜,讨论了反应物的种类、表面活性剂的类型、表面活性剂(CTAB)的加入量、反应时间、反应温度和尿素对磷酸锌物相和微晶形貌的影响,对不同形貌纳米(微米)晶薄膜的形成机理进行了讨论。  相似文献   

10.
超细NiB非晶态合金的结构及催化性能   总被引:1,自引:0,他引:1  
采用XAFS、XRD和DTA技术研究了化学还原法制备的超细NiB非晶态合金的结构及退火晶化行为.结果表明,NiB非晶态合金的退火晶化分两步进行在598K形成晶态的Ni3B和纳米晶的Ni;652K退火导致Ni3B分解以及纳米晶Ni聚集.在623K退火处理后的NiB样品的苯加氢活性最高.活性组分的苯加氢催化性能高低顺序为纳米晶Ni>超细Ni-B非晶态合金>晶态Ni.超细Ni-B非晶态合金的活性中心主要为纳米晶的Ni和Ni富集的NiB非晶态.超细NiB非晶态合金催化剂在反应过程中失活的原因主要是纳米晶Ni的聚集和积碳而所导致活性表面降低.  相似文献   

11.
There are numerous geometric objects stored in the spatial databases. An importance function in a spatial database is that users can browse the geometric objects as a map efficiently. Thus the spatial database should display the geometric objects users concern about swiftly onto the display window. This process includes two operations:retrieve data from database and then draw them onto screen. Accordingly, to improve the efficiency, we should try to reduce time of both retrieving object and displaying them. The former can be achieved with the aid of spatial index such as R-tree, the latter require to simplify the objects. Simplification means that objects are shown with sufficient but not with unnecessary detail which depend on the scale of browse. So the major problem is how to retrieve data at different detail level efficiently. This paper introduces the implementation of a multi-scale index in the spatial database SISP (Spatial Information Shared Platform) which is generalized from R-tree. The difference between the generalization and the R-tree lies on two facets: One is that every node and geometric object in the generalization is assigned with a importance value which denote the importance of them, and every vertex in the objects are assigned with a importance value,too. The importance value can be use to decide which data should be retrieve from disk in a query. The other difference is that geometric objects in the generalization are divided into one or more sub-blocks, and vertexes are total ordered by their importance value. With the help of the generalized R-tree, one can easily retrieve data at different detail levels.Some experiments are performed on real-life data to evaluate the performance of solutions that separately use normal spatial index and multi-scale spatial index. The results show that the solution using multi-scale index in SISP is satisfying.  相似文献   

12.
Instead of following Fock’s expansion,we solve the Schrodinger equation for some quantum mechanical manybody systems such as electrons in atoms and charged excitons in quantum wells in a similar way in hyperspherical coordinates by expanding the wave functions into orthonormal complete basis sets of the hyperspherical hannonics(HHs)of hyperangles and generalized Laguerre polynomials(GLPs)of the hyperradius.This leads the equation to  相似文献   

13.
Future mobile communication systems aim at providing very high data transmission rates, even in high-mobility scenarios such as high-speed wheel-track trains, maglev trains, highway vehicles, airplanes, guided missiles or spacecraft. A particularly important commercial application is the strong and increasing worldwide demand for high- speed broadband wireless communications (up to 574.8 km/ h test speeds or 380 km/h commercial speeds) in railways, providing data, voice and video services for applications such as onboard entertainment services to passengers, train control, train dispatch, train sensor status handling and sur- veillance. In such high-mobility scenarios, there are a number of communication challenges, including fast hand- over, location updating, high-speed channel modeling, estimation and equalization, anti-Doppler spreading tech- niques, fast power control, and dedicated network architec- ture. Because signal transmission in very high-speed scenarios will inevitably experience serious deterioration, it is imperative to develop key broadband mobile communi- cation techniques for such high-speed vehicles.  相似文献   

14.
15.
Being the primary media of geographical information and the elementary objects manipulated, almost all of maps adopt the layer-based model to represent geographic information in the existent GIS. However, it is difficult to extend the map represented in layer-based model. Furthermore, in Web-Based GIS, It is slow to transmit the spatial data for map viewing. In this paper, for solving the questions above, we have proposed a new method for representing the spatial data. That is scale-based model. In this model we represent maps in three levels: scale-view, block, and spatial object, and organize the maps in a set of map layers, named Scale-View, which associates some given scales.Lastly, a prototype Web-Based GIS using the proposed spatial data representation is described briefly.  相似文献   

16.
何延凌 《科技信息》2008,(4):258-258
Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women's language from these perspectives: pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women's language, more attention should be paid to language use in social context. What's more, the linguistic phenomena in a speaking community can be understood more thoroughly.  相似文献   

17.
为了有助于提高英文爱好者的个人情操、文化素养和学习兴趣,以及专业人员对英语学习和研究进行多途径的探索,本文通过一些精选诗歌的引证和分析,着重论述了喻类修辞法在英文诗歌中的运用其及效果。  相似文献   

18.
Tennessee Williams is considered as one of the most important American playwrights since World War II.The Glass Menagerie is his first successful drama,which describes a tragic situation of family and means to say that Man is unable to change the miserable life,no matter whatever means he try,This essay focuses on the analysis of the arrangement of the four main characters:Laura.Amanda,Jim and Tom to reveal the theme.Laura is fragile.Amanda is brave.Jim is vital.Tom is sensible.And all of them develop and try the different means to struggle against life,but fail tragically.With the evidence,the paper comes to conclusion naturally that Man is unable to change the miserable life,and he dooms to fail.  相似文献   

19.
The aim of this study is to investigate the diversity of Retama raetam root-nodule bacteria isolated from arid regions of Tunisia. Twelve isolates, chosen as representative for different 16S rRNA gene patterns, were characterized by 16S rRNA gene sequencing and phenotypic analysis. Isolates were assigned to Sinorhizobium, Rhizobium and Agrobacterium. Symbiotic properties of Sinorhizobium and Rhizobium isolates showed a large diversity in their capacity to infect their host plant and fix atmospheric nitrogen. Strain RK 22 identified as Rhizobium was the most effective isolate.  相似文献   

20.
正Recently,docking has been widely used to predict the binding-modes of protein-inhibitors,when the crystal complexes structure was absent.Most docking algorithms are able to generate a large number of probable conformations,it,however,is difficult to effectively evaluate these docking poses and identify the most reasonable bindingmode.In the present study,on the basis of the crystallographic data of human 3-hydroxy-3-methylglutaryl coenzyme  相似文献   

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