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1.
采用水热反应法合成了超细微羟基磷灰石(HA),研究了晶化时间对HA微晶尺寸的影响。结果表明,反应时间增长,沿c-轴的微晶尺寸略有增大,沿-α-轴的微晶尺寸不变。FTIR分析表明,HA晶胞中不存在OH^-之间的强烈氢键作用,但支持OH^-与PO4^3-存在弱的氢键的结论。用聚乳聚、棕榈酸、三甲基一氯硅烷分别对HA进行表面处理,显著改善了HA粒子在有机介质中的分散性,其中以聚乳酸改性的效果最好。  相似文献   

2.
本文采用FT-IR、DSC、SEM、WAXD等手段对POM/COPA共混物的微观结构进行分析,并且对其力学性能进行测试.研究结果表明,在POM/COPA共混物中存在着氢键的相互作用,且氢键的相对强度随COPA含量的增加而增大,氢键作用使得微晶尺寸L_(110)及晶胞尺寸均增大.在氢键的相对强度低于1.5的范围内,COPA对POM具有增韧改性作用.  相似文献   

3.
氯化血红素催化显色反应的研究   总被引:1,自引:0,他引:1  
研究了氯化血红素作为过氧化物模拟酶对H2O24AAPC6H5OH显色反应的催化活性.拟定的光度法可准确地测定0~6mg·L-1H2O2的含量,对样品进行分析,平均回收率为1017%.  相似文献   

4.
牛血清白蛋白-羟基磷灰石难溶性复合物的FT-IR光谱研究   总被引:6,自引:0,他引:6  
利用富立叶变换红外光谱(FTIR)法对牛血清白蛋白(BSA)羟基磷灰石[Ca10(OH)2(PO4)6]难溶性复合物的组成及BSA与羟基磷灰石的作用方式进行了研究。结果表明,复合物中BSA与羟基磷灰石之间存在着强烈的相互作用,这种相互作用使水溶性的BSA进入固体羟基磷灰石的结构形成难溶性BSA羟基磷灰石复合物。复合物具有非化学计量的性质,体现了生物矿化的特征。正是这种蛋白质与羟基磷灰石间的复杂相互作用,形成高级自组装结构,使矿化产物具有高强度和韧性。  相似文献   

5.
采用熔融挤出法制备了PA6/POE和PA6/POEgMAH共混合金,借助于力学试验机、TEM、SEM、Molau实验和毛细管流变仪测定了共混合金的力学性能、亚微相态、冲击断口形貌和流变性能,系统地研究了POEgMAH对PA6的增容增韧作用。结果表明,POE与PA6是不相容体系,经MAH接枝改性后的POE与PA6发生化学反应,生成的POEgPA6共聚物起到了原位增容作用,细化了分散相尺寸,有效地改善了合金的力学性能,PA6/POEgMAH共混合金的缺口冲击强度是PA6的12倍。  相似文献   

6.
聚酰胺/硅胶吸附剂吸附分离茶多酚的红外光谱   总被引:3,自引:0,他引:3  
用傅里叶变换红外光谱研究了室温下聚酰胺/硅胶吸附剂( P A/ Si O2)对茶叶中茶多酚的分离提取原理.红外光谱表明, P A/ Si O2 中 P A 分子的酰胺基- O‖ C- N H- 是通过氢键吸附茶多酚分子的活性基团,而酰胺基对咖啡因分子没有吸附作用. P A/ Si O2 中 Si O2 表面羟基 O H 是吸附咖啡因及茶多酚分子的活性基团.由于氢键的作用,茶多酚和咖啡因分子之间也能相互吸附. P A/ Si O2 对氨基酸类物质不起吸附作用,因而容易将其分离.  相似文献   

7.
对位溴代苯甲酸p-BrC6 H5COOH晶体属单斜晶系,空间群是 C52h-P21 /c;晶胞参数为:a=3.95A,b=6.14a,c=29.4A, β=94.45’;晶胞中含四个分子。这四个分子两两地通过羧基间所形成的氢键(O-H…O=2.65A)结合成为具有对称心的双聚分子。羧基和苯环基本上共面。双聚分子的长轴差不多就在(102 )面上,与b轴的交角为54°12’;它的平面绕着分子长轴偏离(102 )面的角度为28°12’。  相似文献   

8.
采用量子化学SCF LCAO-MO CNDO/2的方法,对水分子在不同位置与二聚半乳糖醛酸形成的氢键体系进行了探讨,在端位-OH上形成氢键比在-COOH位形成氢键更为有利,进一步分析了水分子的氢键作用对二聚半乳糖醛酸的稳定构象,水解易于发生的可能构象的影响。  相似文献   

9.
用FT-IR光谱等方法对羟基磷灰石陶瓷中一种氧缺陷进行研究的结果表明,这种缺陷与羟基磷灰石OH离子有氢键作用生成,使陶瓷呈暗红色。该试样可以在N2甚至CO2中退火漂白,又能在O2中重新赋色。经光谱与结构分析推断,这种缺陷是位于羟基磷灰石OH格位上的双氧基团构成。  相似文献   

10.
′(ω羧基壬酰基)苯并15冠5(L)的丙酮溶液与碘化钠的丙酮溶液作用,得到了配合物Na+L·I-晶体.配合物的1HNMR与自由配体冠L的1HNMR谱相比较,ArH和OCH2的δ向低场移动了0.01~0.05ppm.比较二者的IR,配合物冠环上的C-O-C和Ar-O-C的振动频率向低波数方向移动了7~46cm-1.并对配合物的成键性能进行了初步讨论.  相似文献   

11.
Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.  相似文献   

12.
何延凌 《科技信息》2008,(4):258-258
Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women's language from these perspectives: pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women's language, more attention should be paid to language use in social context. What's more, the linguistic phenomena in a speaking community can be understood more thoroughly.  相似文献   

13.
The discovery of the prolific Ordovician Red River reservoirs in 1995 in southeastern Saskatchewan was the catalyst for extensive exploration activity which resulted in the discovery of more than 15 new Red River pools. The best yields of Red River production to date have been from dolomite reservoirs. Understanding the processes of dolomitization is, therefore, crucial for the prediction of the connectivity, spatial distribution and heterogeneity of dolomite reservoirs.The Red River reservoirs in the Midale area consist of 3~4 thin dolomitized zones, with a total thickness of about 20 m, which occur at the top of the Yeoman Formation. Two types of replacement dolomite were recognized in the Red River reservoir: dolomitized burrow infills and dolomitized host matrix. The spatial distribution of dolomite suggests that burrowing organisms played an important role in facilitating the fluid flow in the backfilled sediments. This resulted in penecontemporaneous dolomitization of burrow infills by normal seawater. The dolomite in the host matrix is interpreted as having occurred at shallow burial by evaporitic seawater during precipitation of Lake Almar anhydrite that immediately overlies the Yeoman Formation. However, the low δ18O values of dolomited burrow infills (-5.9‰~ -7.8‰, PDB) and matrix dolomites (-6.6‰~ -8.1‰, avg. -7.4‰ PDB) compared to the estimated values for the late Ordovician marine dolomite could be attributed to modification and alteration of dolomite at higher temperatures during deeper burial, which could also be responsible for its 87Sr/86Sr ratios (0.7084~0.7088) that are higher than suggested for the late Ordovician seawaters (0.7078~0.7080). The trace amounts of saddle dolomite cement in the Red River carbonates are probably related to "cannibalization" of earlier replacement dolomite during the chemical compaction.  相似文献   

14.
There are numerous geometric objects stored in the spatial databases. An importance function in a spatial database is that users can browse the geometric objects as a map efficiently. Thus the spatial database should display the geometric objects users concern about swiftly onto the display window. This process includes two operations:retrieve data from database and then draw them onto screen. Accordingly, to improve the efficiency, we should try to reduce time of both retrieving object and displaying them. The former can be achieved with the aid of spatial index such as R-tree, the latter require to simplify the objects. Simplification means that objects are shown with sufficient but not with unnecessary detail which depend on the scale of browse. So the major problem is how to retrieve data at different detail level efficiently. This paper introduces the implementation of a multi-scale index in the spatial database SISP (Spatial Information Shared Platform) which is generalized from R-tree. The difference between the generalization and the R-tree lies on two facets: One is that every node and geometric object in the generalization is assigned with a importance value which denote the importance of them, and every vertex in the objects are assigned with a importance value,too. The importance value can be use to decide which data should be retrieve from disk in a query. The other difference is that geometric objects in the generalization are divided into one or more sub-blocks, and vertexes are total ordered by their importance value. With the help of the generalized R-tree, one can easily retrieve data at different detail levels.Some experiments are performed on real-life data to evaluate the performance of solutions that separately use normal spatial index and multi-scale spatial index. The results show that the solution using multi-scale index in SISP is satisfying.  相似文献   

15.
理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。  相似文献   

16.
王慧 《科技信息》2008,(10):240-240
Wuthering Heights, Emily Bronte's only novel, was published in December of 1847 under the pseudonym Ellis Bell. The book did not gain immediate success, but it is now thought one of the finest novels in the English language. Catherine is the key character of this masterpiece, because everybody and everything center on her though she had a short life. We can understand this masterpiece better if we know Catherine well.  相似文献   

17.
The Williston Basin is a significant petroleum province, containing oil production zones that include the Middle Cambrian to Lower Ordovician, Upper Ordovician, Middle Devonian, Upper Devonian and Mississippian and within the Jurassic and Cretaceous. The oils of the Williston Basin exhibit a wide range of geochemical characteristics defined as "oil families", although the geochemical signature of the Cambrian Deadwood Formation and Lower Ordovician Winnipeg reservoired oils does not match any "oil family". Despite their close stratigraphic proximity, it is evident that the oils of the Lower Palaeozoic within the Williston Basin are distinct. This suggests the presence of a new "oil family" within the Williston Basin. Diagnostic geochemical signatures occur in the gasoline range chromatograms, within saturate fraction gas chromatograms and biomarker fingerprints. However, some of the established criteria and cross-plots that are currently used to segregate oils into distinct genetic families within the basin do not always meet with success, particularly when applied to the Lower Palaeozoic oils of the Deadwood and Winnipeg Formation.  相似文献   

18.
As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.  相似文献   

19.
AcomputergeneratorforrandomlylayeredstructuresYUJia shun1,2,HEZhen hua2(1.TheInstituteofGeologicalandNuclearSciences,NewZealand;2.StateKeyLaboratoryofOilandGasReservoirGeologyandExploitation,ChengduUniversityofTechnology,China)Abstract:Analgorithmisintrod…  相似文献   

20.
In the 19th century the society was controlled by men, and women were just appendants of them, they had not any rights and freedom. But Jane was an exception, she showed some characteristics of early feminist. Jane showed her characteristics of feminism in three aspects: rebellion, equality, and independence. These characteristics were helpful to her success, and feminism is the only way out for women of that time.  相似文献   

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