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1.
钡铁氧体的颗粒粒径与吸波性能研究   总被引:4,自引:0,他引:4  
采用柠檬酸盐溶胶凝胶法,分别在缓慢升温与快速升温制度下制备钡铁氧体粉体.用X衍射、扫描电镜、原子力显微镜及网络分析仪研究了产物结构组成、复介电常数与磁导率.在加热速率60℃.H-1升温至850℃的条件下,产物的主要物相为六角磁铅石型钡铁氧体BAFE12O19,颗粒尺寸为50 NM;而在加热速率400℃.H-1快速升温至850℃的条件下,产物的主要物相为BAFE11.9O19,颗粒尺寸为153 NM.结合烧结球磨法制得的微米钡铁氧体粉体,在0.1~6.0 GHZ频率范围内测定的介电常数与磁导率表明:随着铁氧体粒径减小,钡铁氧体对电磁波的吸收能力增强.  相似文献   

2.
以硝酸铁[Fe(NO3)39H2O]、乙酸钡[Ba(CH3COO)2]和甘氨酸[C2H5NO2]为原料,采用甘氨酸溶胶凝胶-自蔓延燃烧法成功制备成BaFe12O19纳米粉末;用XRD、SEM和VSM等测试方法研究了不同条件下产物的微观形貌、晶体结构及磁学性能。研究表明,煅烧温度和甘氨酸与金属盐的摩尔比会影响单相六角BaFe12O19的形成;甘氨酸与金属盐摩尔比为3∶1的前驱体在800℃下,煅烧2 h后可得到六角片状、粒度40~50 nm的单相BaFe12O19粉末;当温度升高到900℃时,钡铁氧体颗粒长大到100 nm以上,矫顽力下降。  相似文献   

3.
水热法合成单磁畴M型BaFe12O19超细粉体及其磁性能表征   总被引:1,自引:0,他引:1  
采用水热法分别在不同条件下制备单磁畴M型BaFe12O19磁性颗粒.用X射线衍射仪、透射电镜、振动试样磁强计和网络分析仪对产物的组成、微观形貌和电磁性能进行了表征分析.结果表明,230 ℃水热反应在n(Fe)/n(Ba)和n(OH-)/n(NO-3)分别为8和3时得到平均晶粒为52 nm的单磁畴BaFe12O19磁性颗粒;产物具有6.1×10-3 T饱和磁化强度和8.75×104 A/m矫顽力;试样在3~15 GHz宽频范围内具有至少-5 dB的反射率,因此水热合成的BaFe12O19铁氧体具有宽频微波吸收能力.  相似文献   

4.
六角晶系钡铁氧体纳米晶的制备和表征   总被引:8,自引:0,他引:8  
采用柠檬酸sol gel工艺 ,制备了Zn2 Z型 ,Zn2 W型 ,Co2 Z型 ,M型平面六角晶系的钡铁氧体钠米晶 .采用X射线衍射分析 (XRD) ,透射电镜分析 (TEM)和热分析对其物相组成、显微结构、反应过程等进行研究 ,发现采用本工艺 ,在 75 0℃的较低温度下 ,就可形成均匀单一的铁氧体纳米晶 ,并深入分析了其反应机制 ;对Zn2 Z型铁氧体的吸波特性进行了研究 ,结果表明 :在X波段 (8~ 12GHz)和Ku波段 (12~ 18GHz) ,有多个吸收峰 ,最大吸收量达 6 5dB ,10dB的带宽达到 6 .5GHz ,说明这是一种优质的宽频微波吸收材料 ,并探究了纳米吸波材料的吸波机理 .  相似文献   

5.
采用溶胶-凝胶法制备了掺杂钇的磁铅石型系列Z型钡铁氧体纳米颗粒.通过对相结构的分析表明:Ba3-xYxCO2Fe24O41(x=0,0.1,0.2,0.3,0.4)样品在1300℃下烧结5h后成相主要为Z型钡铁氧体,同时伴有少量W型、Y型杂相.还对添加稀土钇及间隔一段时间后吸波性能的变化进行了研究,结果表明,掺杂适量的稀土钇(x=0.1)在微波X波段平均吸波性能达到最大,抗氧化能力也明显增强,过量或少量掺杂钇都会影响材料的吸波性能及抗氧化能力.  相似文献   

6.
采用溶胶-凝胶法分别在650、750、850、950℃下制备钡铁氧体,发现不同温度下制备的钡铁氧体形貌、大小以及分布明显不同.通过原位聚合法合成了不同形貌钡铁氧体/聚苯胺复合材料,红外光谱显示,聚苯胺的吸收峰由于钡铁氧体的掺入发生轻微的蓝移,证明2物质之间有化学相互作用.煅烧温度在750℃以上时,所制备的钡铁氧体结晶良好,并随着煅烧温度的升高,钡铁氧体的形貌由棒状变成片状或球形.850℃煅烧制备的钡铁氧体分散性良好,部分呈片状,其与聚苯胺组成的复合材料吸波性能最好,当涂层厚度为4mm时,它在6.9GHz频率取得最大反射损耗值-17.1dB,在5.7~8.7GHz频率反射损耗均低于-10dB,说明制备出了分散性良好、形貌独特的钡铁氧体,可以有效提高钡铁氧体聚苯胺复合材料的吸波性能.  相似文献   

7.
纳米晶复合永磁铁氧体的双相交换耦合作用   总被引:1,自引:0,他引:1  
采用sol-gel方法制备纳米晶复合SrFe12O19/γ-Fe2O3铁氧体.利用X射线衍射(XRD),透射电子显微镜(TEM)和振动样品(VSM)对纳米晶样品进行了研究.当焙烧温度介于600~800℃,样品存在SrFe12O19/γ-Fe2O3复相.在同样条件下,压成薄片的样品呈现了硬磁与软磁(SrFe12O19/γ-Fe2O3)的纳米复合相的交换耦合作用.对SrFe12O19/γ-Fe2O3的纳米复合材料的各向同性磁能积的增加和磁性交换耦合作用机制进行了研究.  相似文献   

8.
采用水热合成法对碳纳米管(CNTs)进行酸化处理,并且合成钡铁氧体包覆CNTs的新型纳米复合材料,使用红外光谱仪(FT-IR)对酸化CNTs的表面官能团进行表征,使用X线衍射仪(XRD)与扫描电子显微镜(SEM)对复合材料的物相和形貌进行表征。结果表明:60℃水热法酸化能有效地除去CNTs中的无定形杂质,并在表面引入大量极性基团;在200℃下,Ba2+与Fe3+摩尔比在3∶12和4∶12时,水热合成了结晶程度较高的BaFe12O19/CNTs复合材料,CNTs表面均匀地覆盖了一层BaFe12O19;随着反应体系中Ba2+比例的升高,BaFe12O19的结晶程度有相应提高。  相似文献   

9.
BaLaxFe12-xO19微波吸收性能的研究   总被引:3,自引:0,他引:3  
采用溶胶-凝胶法制备钡铁氧体BaLaxFe12-xO19,对其微波吸收特性进行了研究,在10~12.5GHz频率范围,x取值不同,吸收特性不同.在x=0.15,样品厚度为3.0mm时,最高吸收峰为18.381dB.测试结果表明,添加适量的La3 会提高钡铁氧体的吸波性能.  相似文献   

10.
采用溶胶凝胶自蔓延合成工艺制备了六角晶系M型钡铁氧体微粉BaFe12O19.用X射线衍射仪,振动样品磁强计和矢量网络分析仪对粉末的结构、磁性能以及电磁波吸收性能进行了表征.结果表明,BaFe12O19既能产生磁损耗,又能产生介电损耗,是一种宽频微波吸收材料.  相似文献   

11.
Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.  相似文献   

12.
何延凌 《科技信息》2008,(4):258-258
Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women's language from these perspectives: pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women's language, more attention should be paid to language use in social context. What's more, the linguistic phenomena in a speaking community can be understood more thoroughly.  相似文献   

13.
The discovery of the prolific Ordovician Red River reservoirs in 1995 in southeastern Saskatchewan was the catalyst for extensive exploration activity which resulted in the discovery of more than 15 new Red River pools. The best yields of Red River production to date have been from dolomite reservoirs. Understanding the processes of dolomitization is, therefore, crucial for the prediction of the connectivity, spatial distribution and heterogeneity of dolomite reservoirs.The Red River reservoirs in the Midale area consist of 3~4 thin dolomitized zones, with a total thickness of about 20 m, which occur at the top of the Yeoman Formation. Two types of replacement dolomite were recognized in the Red River reservoir: dolomitized burrow infills and dolomitized host matrix. The spatial distribution of dolomite suggests that burrowing organisms played an important role in facilitating the fluid flow in the backfilled sediments. This resulted in penecontemporaneous dolomitization of burrow infills by normal seawater. The dolomite in the host matrix is interpreted as having occurred at shallow burial by evaporitic seawater during precipitation of Lake Almar anhydrite that immediately overlies the Yeoman Formation. However, the low δ18O values of dolomited burrow infills (-5.9‰~ -7.8‰, PDB) and matrix dolomites (-6.6‰~ -8.1‰, avg. -7.4‰ PDB) compared to the estimated values for the late Ordovician marine dolomite could be attributed to modification and alteration of dolomite at higher temperatures during deeper burial, which could also be responsible for its 87Sr/86Sr ratios (0.7084~0.7088) that are higher than suggested for the late Ordovician seawaters (0.7078~0.7080). The trace amounts of saddle dolomite cement in the Red River carbonates are probably related to "cannibalization" of earlier replacement dolomite during the chemical compaction.  相似文献   

14.
理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。  相似文献   

15.
王慧 《科技信息》2008,(10):240-240
Wuthering Heights, Emily Bronte's only novel, was published in December of 1847 under the pseudonym Ellis Bell. The book did not gain immediate success, but it is now thought one of the finest novels in the English language. Catherine is the key character of this masterpiece, because everybody and everything center on her though she had a short life. We can understand this masterpiece better if we know Catherine well.  相似文献   

16.
The Williston Basin is a significant petroleum province, containing oil production zones that include the Middle Cambrian to Lower Ordovician, Upper Ordovician, Middle Devonian, Upper Devonian and Mississippian and within the Jurassic and Cretaceous. The oils of the Williston Basin exhibit a wide range of geochemical characteristics defined as "oil families", although the geochemical signature of the Cambrian Deadwood Formation and Lower Ordovician Winnipeg reservoired oils does not match any "oil family". Despite their close stratigraphic proximity, it is evident that the oils of the Lower Palaeozoic within the Williston Basin are distinct. This suggests the presence of a new "oil family" within the Williston Basin. Diagnostic geochemical signatures occur in the gasoline range chromatograms, within saturate fraction gas chromatograms and biomarker fingerprints. However, some of the established criteria and cross-plots that are currently used to segregate oils into distinct genetic families within the basin do not always meet with success, particularly when applied to the Lower Palaeozoic oils of the Deadwood and Winnipeg Formation.  相似文献   

17.
There are numerous geometric objects stored in the spatial databases. An importance function in a spatial database is that users can browse the geometric objects as a map efficiently. Thus the spatial database should display the geometric objects users concern about swiftly onto the display window. This process includes two operations:retrieve data from database and then draw them onto screen. Accordingly, to improve the efficiency, we should try to reduce time of both retrieving object and displaying them. The former can be achieved with the aid of spatial index such as R-tree, the latter require to simplify the objects. Simplification means that objects are shown with sufficient but not with unnecessary detail which depend on the scale of browse. So the major problem is how to retrieve data at different detail level efficiently. This paper introduces the implementation of a multi-scale index in the spatial database SISP (Spatial Information Shared Platform) which is generalized from R-tree. The difference between the generalization and the R-tree lies on two facets: One is that every node and geometric object in the generalization is assigned with a importance value which denote the importance of them, and every vertex in the objects are assigned with a importance value,too. The importance value can be use to decide which data should be retrieve from disk in a query. The other difference is that geometric objects in the generalization are divided into one or more sub-blocks, and vertexes are total ordered by their importance value. With the help of the generalized R-tree, one can easily retrieve data at different detail levels.Some experiments are performed on real-life data to evaluate the performance of solutions that separately use normal spatial index and multi-scale spatial index. The results show that the solution using multi-scale index in SISP is satisfying.  相似文献   

18.
As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.  相似文献   

19.
In the 19th century the society was controlled by men, and women were just appendants of them, they had not any rights and freedom. But Jane was an exception, she showed some characteristics of early feminist. Jane showed her characteristics of feminism in three aspects: rebellion, equality, and independence. These characteristics were helpful to her success, and feminism is the only way out for women of that time.  相似文献   

20.
AcomputergeneratorforrandomlylayeredstructuresYUJia shun1,2,HEZhen hua2(1.TheInstituteofGeologicalandNuclearSciences,NewZealand;2.StateKeyLaboratoryofOilandGasReservoirGeologyandExploitation,ChengduUniversityofTechnology,China)Abstract:Analgorithmisintrod…  相似文献   

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