大别山超高压榴辉岩的波速各向异性计算

利用大别山超高压榴辉岩中绿辉石的实测组构数据,计算了超高压榴辉岩的波速各向异性值．通过与实测值比较,探讨了相辉岩的波速各向异性与绿辉石晶格优选方位的关系．结果表明：绿辉石的晶格优选方位是引起榴辉岩波速各向异性的主要原因,但不是唯一因素,岩石的其它几何学特征如石榴子石形态组构等对其波速也有影响;绿辉石ＬＰＯ在不同的方向上对Ｖｐ的影响不一样;在Ｙ轴上,即平行于面理,垂直干线理的方向上,剪切波Ｖｓ慢波的波速最小,剪切波快波的最大波速和最小波速与线理面理方向有２０°～３０°左右的偏差．     

汉诺坝地区下地壳与壳-幔过渡带岩石波速实验研究

通过对汉诺坝新生代玄武岩中镁铁质麻粒岩相斜长辉石岩、榴辉岩相石榴辉石岩和辉石岩捕虏体,以及普通的太古代地体麻粒岩,进行高温高压下的波速测定和研究表明:高V p (7.0～8.0km/s)镁铁质捕虏体揭示现今下地壳和壳-幔过渡带组成特征,为幔源岩浆底侵导致地壳垂向增生和壳-幔过渡带形成提供了新证据;低V p (<7.0km/s)太古代地体麻粒岩,乃早期下地壳或上部下地壳的特点.     

RP-HPLC同时测定冷水花属3种植物中2种黄酮苷的含量

 建立反相高效液相色谱法同时测定冷水花属湿生冷水花、冷水花、粗齿冷水花植物中木犀草苷和大波斯菊苷2种黄酮类化合物含量的方法.采用Agilent ZORBAX SB-C₁₈(250mm×4.6mm,5μm)色谱柱,以乙腈-0.2%乙酸水溶液为流动相进行洗脱,检测波长350nm,流速0.mL·min^-1,柱温25℃.结果木犀草苷和大波斯菊苷分别在2.48~79.36μg·mL^-1、1.68~53.76μg·mL^-1范围内线性关系良好,木犀草苷平均回收率为98.06 %,RSD为1.11%;大波斯菊苷平均回收率为99.18%,RSD为0.98 %.所建立的冷水花HPLC含量测定方法结果准确可靠,可用于不同品种冷水花植物中木犀草苷和大波斯菊苷的含量测定.     

催泪喷射器中刺激组分的紫外分光光度法分析

采用紫外分光光度法对催泪喷射器中的刺激组分邻氯苯亚甲基丙二腈(CS)和辣椒素(OC)进行检测.分别选取300 nm和281 nm作为CS和OC的紫外检测波长,通过外加标准物质定量法建立标准曲线,对催泪喷射器中刺激组分进行含量检测,并依据HPLC方法测定结果对比检测可靠性.本方法对邻氯苯亚甲基丙二腈和辣椒素的检出限分别为0.02 μg·mL^-1和0.16 μg·mL^-1,精密度分别为1.04%和0.64%,平均回收率分别为97.37%和102.51%,CS和OC分别在0.1~25.0 μg·mL^-1和1~200 μg·mL^-1范围内具有良好的线性关系,线性相关系数均为0.999 9.结果表明,该方法简单、快速、成本低,可用于催泪剂中刺激组分的含量分析.     

细基江蓠原变型与细基江蓠繁枝变型制取琼胶的比较研究

本文采用三种碱处理方法对细基江蓠原变型、混养细基江蓠繁枝变型和单养细基江蓠繁枝变型进行了对比研究。得出"中温浓碱法"为提高三种江蓠琼胶凝胶强度的较好工艺,而"常温浓碱法"的产率较好."中温浓碱法"三种江蓠琼胶的产率及凝胶强度分别为(次序同上,下同):38.6%、691g/cm²、13.1%、637g/cm²,13.9%、557g/cm²,"常温浓碱法",三种江蓠琼胶的产率及凝胶强度分别是:47.6%、509g/cm²,19.5%、414g/cm²,25.9%,326g/cm²。     

南大别石马榴辉岩多硅白云母和石英脉的年龄及其地质意义

研究发现,与大别-苏鲁超高压变质带中多硅白云母往往含过剩Ar不同,石马地区榴辉岩中多硅白云母基本不含过剩Ar.阐述了其原因,并进而探讨了超高压带中变质流体运移的特点.切穿石马地区榴辉岩及其围岩的白云母石英细脉的年龄表明,南大别超高压变质带角闪岩相退变质作用应结束在180 Ma前,而不会更晚.     

Temperature dependent spectral response characteristic of III-V compound tandem cell

The GaInP/GaAs/Ge triple-junction tandem cells with a conversion efficiency of 27.1% were fabricated using metalorganic chemical vapor deposition (MOCVD) technique. Temperature dependence of the spectral response measurements of the GaInP/GaAs/Ge tandem cell was performed by a quantum effi-ciency system at temperatures ranging from 25℃ to 160℃. The red-shift phenomena of the absorption limit for all subcells were observed with increasing temperature, which is dued to the energy gap nar-rowing with temperature. The short-circuit current densities (J_sc)of GaInP, GaAs and Ge subcells at room temperature calculated based on the spectral response data were 12.9, 13.7 and 17 mA/cm², re-spectively. The temperature coefficient of J_sc for the tandem cell was determined to be 8.9 mA/(cm²·℃), and the corresponding temperature coefficient of the open-circuit voltage deduced from the se-ries-connected model was -6.27 mV/℃.     

西南天山榴辉岩的显微构造及其变形机制探讨

岩石、矿物的显微构造是岩石变形、变质等各种地质作用最直观的记录。新疆西南天山高压变质带中榴辉岩的显微构造研究,对认识其在地壳深俯冲过程中的岩石、矿物变形机制有十分重要的意义。西南天山榴辉岩的显微构造研究发现:绿辉石的动态重结晶亚晶粒化和颗粒边界迁移、云母的扭折和波状消光、方解石的机械双晶等显微变形现象,表明动态恢复作用、位错滑移和位错攀移为主的晶质塑性变形机制是榴辉岩的主要变形机制;石榴子石呈无变形刚性特征,具有变斑晶包迹结构,说明固态物质扩散迁移是榴辉岩的另一个重要变形机制;石榴子石多具有良好的晶型,说明石榴子石是在静变质状态下稳态生长而成,这与大别—苏鲁高压—超高压变质带有明显区别。因此,笔者认为位错蠕变、动态重结晶主导的晶质塑性变形和固态物质扩散迁移组合的显微构造变形现象,是西南天山高压—超高压变质榴辉岩的显微构造组合特征。这样的组合特征可能代表了洋壳深俯冲经历高压—超高压变质作用榴辉岩变形机制。     

泡沫镍上原位生长CoMn2O4多级空心纳米球作为超级电容器电极材料的电化学性能研究

采用水热法结合空气气氛中的热处理过程,在泡沫镍（NF）表面生长了锰酸钴（CoMn₂O₄）多级空心纳米球,通过X射线衍射仪（XRD）、场发射扫描电镜（FE-SEM）和X射线光电子能谱（XPS）等测试手段对纳米球进行了表征.在三电极电化学测量系统中,0.1Co²⁺-250电极材料在5 mA·cm^-2时的面积比电容高达6 184 mF·cm^-2.以0.1Co²⁺-250为正极,商用活性炭（AC）为负极组装而成的混合超级电容器,在1.6 mW·cm^-2时的最大能量密度为0.112 mWh·cm^-2.即使在功率密度为16 mW·cm^-2时,能量密度仍达到0.064 mWh·cm^-2.在2 mA·cm^-2的电流密度下,经过10 000次充放电循环后,电容保持了初始值的93%.因其优越的电化学性能和低成本的便捷合成方法,CoMn₂O₄多级空心纳米球作为电极材料具有重要的应用前景.     

Kinetic studies of the decomposition reaction of adducts of dinuclear Fe(Ⅱ)/O2

Kinetic studies of the decomposition reaction of dinuclear Fe(Ⅱ) adducts [Fe₂(N-Et-HPTB){O₂P(OPh)₂}](Cl- O₄)₂ (1) and [Fe₂(N-Et-HPTB) {O₂P(Ph)₂}] (ClO₄)₂ (2) with O₂ have been carried out at low temperature using UV-vis spectra. The decomposition reaction of Fe(Ⅱ)/O₂ adducts was first-order in the experimental conditions, and the activation parameters were obtained. ?H^¹ = 85.62 kJ·mol^-1, ?S¹ = 19.43 J·mol^-1·K^-1 for compound (1) and ?H^¹ = 97.97 kJ·mol^-1, ?S^¹ = 55.68 J·mol^-1·K^-1 for compound (2). These results are similar to those of dioxygen adducts of other metals complexes and natural enzymes such as methane mono- oxygenase (MMOH).     

IR study on hydrogen bonding in epoxy resin-silica nanocomposites

The chemical and physical interactions between ingredients in composites play an important role in the improvement of service properties. The nucleophilic addition between polymer and isophoron diisocyanate molecules was monitored by FT-IR technique. The intensity loss of isocyanate absorption band in conjunction with the intensity growth of carboxyl absorption band indicates the progress of reaction. FT-IR spectroscopy was also adopted to examine the intermolecular hydrogen bonding of epoxy resin with silica as well as intramolecular one within polymer matrix. The vibration frequency of carboxyl group (-C=O) and hydroxyl group (-OH) shift from 1736cm^-1to 1728 cm^-1and 3420 cm^-1to 3414 cm^-1 respectively, indicating the occurrence of hydrogen bonding between -C=O and -OH. The vibration frequency of Si-OH moves from 3435 cm^-1 to 3414 cm-1, suggesting the involvement of silica. Whereas the vibration frequency of pending –OH in polymer chain moves from 3435 cm^-1to 3420 cm^-1or 3414cm^-1, proposing this kind of interaction can also happen within polymer matrix.     

Partial oxidation of methane to syngas in tubular oxygen-permeable reactor

A dense Ba_0.5Sr_0.5Co_0.8Fe_0.2O_3-δ membrane tube was prepared by the extruding method. Furthermore, a membrane reactor with this tubular membrane was successfully applied to partial oxidation of methane (POM) reaction, in which the separation of oxygen from air and the partial oxidation of methane are integrated in one process. At 875℃, 94% of methane conversion, 98% of CO selectivity, 95% of H₂ selectivity, and as high as 8.8 mL/(min · cm²) of oxygen flux were obtained. In POM reaction condition, the membrane tube shows a very good stability.     

太阳能电池用低掺杂率多晶硅薄膜的制备

通过铝诱导晶化非晶硅(Aluminum-Induced Crystallization, AIC)制备的多晶硅薄膜具有较高的铝掺杂浓度(2×10¹⁸ cm^-3), 不适宜作为薄膜太阳能电池的吸收层. 我们提出了QCGE AIC法, 即: 硅原子的快速扩散; 冷却成核; 晶粒的慢速生长; 铝原子的向外扩散.通过精确控制AIC过程中退火温度及模式制备了掺杂率为2×10¹⁶ cm^-3的高品质多晶硅薄膜. 二次离子质谱(Secondary-Ion-mass Spectroscopy, SIMS)结果表明: 制备多晶硅薄膜中铝残留浓度依赖于退火的温度模式; 霍尔效应测试结果表明: 制备多晶硅薄膜的掺杂率依赖于退火的温度和退火模式; 拉曼光谱表明: 通过QCGE AIC 制备的多晶硅薄膜中包含有少量由小颗粒硅组成的区域.     

Love波在预应力流体饱和双重孔隙介质层中传播的特性

基于扩展的Biot理论,研究了覆盖于各向异性不均匀弹性半空间上的受预应力流体饱和双重孔隙介质中Love波的传播.推导了速度的频散方程以及Love波速的上下界限,讨论了孔隙率、不均匀性、各向异性和预应力等参数对波速的影响.通过数值计算,结果发现孔隙介质层基质孔隙的孔隙率、裂隙孔隙率及基质孔隙的孔隙率占总孔隙率的比重越大,Love波的波速越大;随着不均匀程度的提高及各向异性系数的增大,Love波的波速增大.无论是在双重孔隙介质层中还是弹性半空间中,预拉应力会使Love波的波速提高,而预压应力会降低Love波的波速.     

可穿戴式低强度聚焦超声治疗康复贴

本文为治疗人体软组织损伤,减轻疼痛,加快病情的好转,而设计一款可穿戴式低强度聚焦超声治疗装置.该设备采用QI标准无线充电模块为整个装置提供能源,经高转换率的集成升压电路将3.3 V转为5 V,为驱动电路提供电压,再由采用nrf24l01模块传输的遥控器控制超声发生康复贴,即STM32L151单片机结合PID算法产生1 MHz PWM波,控制驱动电路驱动压电陶瓷片产生频率为1 MHz,强度为100 mW/cm²、132 mW/cm²、150 mW/cm²三档位超声波.该装置具有体积小,充电快,重量轻,成本低,无需耦合剂,可穿戴,电-声转换效率高的特点.     

桐柏山地壳结构的Pb同位素地球化学示踪研究

出露于桐柏山一带的桐柏杂岩,其放射成因Pb同位素组成介于低放射成因Pb同位素组成的大别核部杂岩和相对高放射成因Pb同位素组成的大别超高压变质杂岩之间,侵入于桐柏杂岩的鸡公山花岗岩明显不同于桐柏杂岩的Pb同位素组成,而与大别核部杂岩具有相似的Pb同位素组成.根据Pb同位素组成在地壳垂向剖面上的变化模型及花岗岩的岩浆源区分析,指出在区域地壳结构上,桐柏杂岩是位于大别核部杂岩之上但位于超高压变质杂岩之下的一个岩系.东部大别地区由于地壳剥露程度高,在大别核部杂岩之上的桐柏杂岩基本没有得到保存,而在桐柏地区,地壳剥露相对较浅,在桐柏杂岩之下的深部地壳中仍有类似于东部大别核部杂岩的分布.因此,在造山带的地壳结构上,桐柏地区和大别地区的地壳基底组成是统一的,现今它们在造山带中的分布仅仅反映造山带地壳不同暴露截面的差异.     

重金属污染底泥固化体负载铁去除水中磷的研究

采用免烧结技术将重金属污染的底泥固化稳定化,在满足安全性的基础上,利用FeCl₃对固化体改性,研究改性固化体吸附去除水中磷的性能及机制。研究结果表明：经过免烧结固化之后,当水泥掺量质量分数为40%,养护龄期28 d,Cd,Cu与Pb稳定化率达到92.5%,91.8%,99.5%;Cd,Cu和Pb的浸出浓度分别为1.00×10^-4 ,1.18×10^-2和1.40×10^-4 g·L^-1;改性后底泥固化体的磷去除率由41.2%提升至98.7%,铁改性固化体较佳的铁含量配比为112.0 g·kg^-1（Fe/固化体）;在水体除磷应用中,当磷浓度为5.00×10^-3 g·L^-1,改性固化体投加比为10 g·L^-1、pH为6、在90 min时达到吸附平衡,吸附过程符合Freundlich模型,且与准二级动力学方程的拟合程度高。     

An explanation to the high efficiency ofm-THPC (temporfin) used in photodynamic therapy

Meso-tetrahydroxylphenyl chlorin (m-THPC) is one of the most efficient prospective sensitizers used in photodynamic therapy (PDT). ESR spectroscopy, fluorescence quenching experiments and cyclic voltammogram measurement were used to study its redox properties. The results showed that the ability of m-THPC generating superoxide radical anions was very strong, and the rate constant of m-THPC fluorescence quenching by oxygen k_q (O₂)=1.46×10¹⁰ mol^-1·s^-1. The values of fluorescence quen- ching rate constant of m-THPC by some other electron acceptors, such as methyl viologen (MV²⁺) and anthraquinone (An), were also measured. And they were k_q (MV²⁺)=5.51×10⁹ mol^-1·s^-1, k_q (An)=7.81×10⁹ mol^-1·s^-1. The oxidation potential of m-THPC was examined to be +0.62 V (vs. NHE) in acetonitrile. All these suggested that m-THPC should be a much stronger electron donor than photofrin, the currently used in clinical photodrug, and may react easily through electron transfer with biological matter to yield various radicals. So it seemed reasonable that the type Ⅰ reaction may play an important role in the high activity of m-THPC-PDT.     

高载量钴离子掺杂MnO2用于高性能锌离子混合电容器

通过恒流电沉积的方法在柔性碳布上制备了钴离子掺杂的MnO₂，其负载量达到13.8 mg/cm²。利用X射线衍射仪（X-ray diffractometer, XRD）、扫描电子显微镜（scanning electron microscope, SEM）、X射线光电子能谱（X-ray photoelectron spectrometer, XPS）和电化学工作站等对材料的结构和性能进行表征，探究了钴离子掺杂对MnO₂电化学性能的影响。结果表明，当该电极与活性炭组装成液态锌离子混合电容器（zinc ion hybrid capacitors, Zn-HCs）时，Zn-HCs在2 mA/cm²的电流密度下，面积比电容高达5 883.0 mF/cm²，面积能量密度为3 154.9 μWh/cm²，与锌离子电池的能量水平相当。当该电极与活性炭组装成准固态柔性Zn-HCs时，Zn-HCs具有较好能量密度（在1 mW/cm²的功率密度下达1 351.1 μWh/cm² ）的同时具有优异的机械柔韧性，使Zn-HCs有望应用于新一代的柔性可穿戴设备。     

化学镀银聚酯纤维制备及其导电性能研究

 采用化学镀法在聚酯纤维表面镀覆一层导电银层,采用场发射扫描电镜（FE-SEM）、电子能谱仪（EDS）、X射线衍射仪（XRD）分别对聚酯纤维镀银前后的表面形貌、化学元素组成、银结晶结构进行表征.讨论了乙二胺浓度、AgNO₃浓度、施镀时间和镀液温度对化学镀银聚酯纤维增重率及电阻率的影响,测试化学银镀层与纤维基体的结合牢度和耐腐蚀性.结果表明,最佳工艺条件下,电阻率低至2.31Ω·cm^-1;镀层为高纯度的面心立方结构的单质银;银镀层具有良好的与基体的粘结强度和耐化学腐蚀性能.
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