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1.
The interaction of Ru(phen)2(dppz)2+(phen=1,10-phenanthroline,dppz=dipyrido[3,2−1:2′,3′−c]phenazine) and the calfthymus DNA were studied with fluorescence and
ultraviolet visible absorption spectroscopy. The ultraviolet visible absorption spectrum of Ru(phen)2(dppz)2+ calfthymus DNA, and their interaction demonstrated that Ru(phen)2(dppz)2+ intercalated into the double helix of DNA via the ligand dppz. Fe(CN)6
4− and NaCl can not quench the fluorescence of Ru(phen)2(dppz)2+-DNA, which was in agreement with the intercalation mode.
Foundation item: Supported by National Natural Science Foundation of China
Biography: LING Lian-sheng (1972-), male, PhD, candidate. 相似文献
2.
PANG Tao CAO WangHe 《科学通报(英文版)》2008,53(2):178-182
The synthesis and up-conversion luminescent properties of YTaO4:Er^3+ and YTaO4:Er^3+/Yb^3+ are reported for the first time. According to the measurement results of up-conversion spectra, Yb^3+ co-doping can remarkably enhance the green (^2H11/2/^4S3/2→^4I15/2) and red (^4F9/2→^4I15/2) emissions, but depress the infrared emission (^4I9/2→^4I15/2). With the increase of the Yb^3+ concentration, the intensity of green emission increases, after that, when the Yb^3+ concentration increases continuously, the intensity of green emission decreases, while those of the red and infrared emissions increase and decrease alternately. In addition, the up-conversion mechanisms of Er^3+ doped and Er^3+/Yb^3+ co-doped YTaO4 are also discussed. It is found that the transform of up-conversion mechanism from two-step energy transfer to cooperating sensitization takes place when Yb^3+ concentration is increased up to 12 mol%. With the further increase of Yb^3+ concentration, the energy-back-transfer gradually becomes the dominant up-conversion mechanism, which results in the quenching of the green emission and slight increasing of the red and infrared emissions. 相似文献
3.
Preparation and upconversion luminescence of YVO<Subscript>4</Subscript>:Er<Subscript>3+</Subscript>, Yb<Subscript>3+</Subscript> 下载免费PDF全文
YVO4:Er3+, Yb3+ with varying Yb3+ concentrations were prepared by a precipitation method. The results of X-ray diffraction (XRD) show that all the samples
have a tetragonal zircon structure; the calculated average crystallite sizes are in the range of 14–22 nm. The lattice constants
and cell volume of the samples decrease slightly with the increase in Yb3+ concentration. The upconversion luminescence spectra of all the samples were studied under 980 nm laser excitation. The strong
green emission is observed, which is attributed to the 2H11/2 → 4I15/2 and 4S3/2→4I15/2 transitions of Er3+, and the red emission peaks in 650–675 nm can be ignored. The emission intensity for the sample depends on the Yb3+ concentration. These results reveal that the upconversion processes of YVO4:Er3+, Yb3+ are related to the structure and the doping Yb3+ concentration of the sample. 相似文献
4.
The 0.1 mol% Er^3+ and 0-2 mol% Yb^3+ codoped Al2O3 powders were prepared by the sol-gel method, and the phase structure, including only two crystalline types of doped Al2O3 phase, γ-(Al,Er, Yb)2O3 and θ-(Al,Er, Yb)2O3, was detected at the sintering temperature of 1000℃. The visible and near infrared emissions properties depended strongly on the Yb^3+ codoping, and the corresponding maximal peak intensities centered at about 523, 545, 660 and 1533 nm were obtained respectively for the 0.1 mol% Er^3+ and 0.5 mol% Yb^3+ codoped Al2O3 powders, which were composed of θ-(Al,Er,Yb)2O3 and a small amount of γ-(Al,Er, Yb)2O3 phases. The two-photon absorption process was responsible for the visible up-conversion emissions, and the one-photon absorption process was involved in the near infrared emissions of the Er^3+-yb^3+ codoped Al2O3 powders. 相似文献
5.
Undoped and Eu 3+-doped Sr 2 Mg 1-x Zn x Si 2 O 7 (0≤x≤1) powder crystals were obtained by conventional solid-state reaction.X-ray diffraction,inductively coupled plasma analysis,and Fourier transform infrared spectroscopy results implied that a complete solid-solution formed between Sr 2 MgSi 2 O 7 and Sr 2 ZnSi 2 O 7 as well as local structural adjustment.Excitation spectra exhibited O 2-Eu 3+ charge transfer (CT) bands centered at 250 nm for Sr 2 MgSi 2 O 7:Eu 3+ and 258 nm for Sr 2 ZnSi 2 O 7:Eu 3+.Emission spectra exhibited a major band around 616 nm,which showed the environment around Eu 3+ was non-centrosymmetric in both Sr 2 MgSi 2 O 7:Eu 3+ and Sr 2 ZnSi 2 O 7:Eu 3+.In addition,first principles calculations within the local density approximation (LDA) of density functional theory (DFT) were used to calculate the electronic structure of Sr 2 MgSi 2 O 7 and Sr 2 ZnSi 2 O 7.Calculated results were correlated with experimental UV-vis reflection spectra and the observed shift of the O 2-Eu 3+ CT band. 相似文献
6.
The fluorozirconate glasses ZBLANP( ZrF4-BaF2-LaF3-AlF3-NaF-PbF2) doped with different Yb3+ concentration were prepared. The Raman spectra and absorption spectra are measured to substantiate the existence of phonon-assisted emission. After analyzing the normalized absorption spectra of samples with different Yb3+-doped concentration, we calculated the maximum cooling effect in the 3 wt% Yb3+-doped sample pumped at 1 012.5 nm. The corresponding cooling capability is about -4.09 ℃/W and the cooling efficiency reaches 1.76%. 相似文献
7.
SHI Bo’an~ ZENG Danyun~ JI Xinghu~ XI Juan~ AI Xinping~ HE Zhike~ . College of Chemistry Molecular Sciences Wuhan University Wuhan Hubei China . Department of Chemistry Chemical Engineering Hubei Institute for Nationalities Enshi Hubei China 《武汉大学学报:自然科学英文版》2006,11(3):672-676
0 IntroductionThbiep ycroidmipnlee)xru ctahteinoinu mof(Ⅱ r)u t(he Rniuu(mbip,y m)3ai2n +ly) atrnids- t(r2is -,(21’ -,10-phenanthroline)ruthenium(Ⅱ) (Ru(phen)32 +) ,is a kindof sensitive analytical reagent for electrogenerated chemilumi-nescence(ECL) and chemiluminescence(CL) ,on which a par-ticular review has been presented[1]. The earliest publicationon the synthesis of Ru(bipy)32 +appeared in 1936[2], andduringthefollowing30 years ,theinvestigations relatedtothissubstance were only in… 相似文献
8.
Yong Yi Dong Cai Zhonghong Gao Xiangliang Yang Anlian Qu Huibi Xu Xiaomin Wang Songping Han 《科学通报(英文版)》1998,43(20):1727-1727
The mechanism of peroxynitrite (ONOO−)-induced [ca2+]i increase in single MN9D cell (Dopaminergic neuroblastoma cell line) was studied by using Fura-2 microfluorometric technique.
The results show that ONOO− caused a rapid increase of [Ca2+]i when ONOO− was puffed to the cell. Removing Ca2+ from the bath or using calcium channel antagonist (CdCl2, Nifedipine) greatly inhibited the [Ca2+]i increase induced by ONOO−1, suggesting that the opening of L-Ca2+ channel makes a great contribution to the [Ca2+]i increase. The effect of sulfhydryl reductive agent (DTT) on ONOO−-induced [Ca2+]i increase suggests that ONOO−-activating L-Ca2+ channel is partly related to its oxidative speciality. 相似文献
9.
An electrochemical method for the simultaneous determination of lead(II) and Cadmium(II) with a calix[6]arene modified carbon
paste electrode (CPE) has been developed. Pb2+ and Cd2+ were accumulated at the surface of the modified electrode via formation of chemical complexes with calix[6]arene, and reduced
at 1.40 V. During the following anodic potential sweep, reduced lead and cadmium were oxidized, and two well-defined striping
peaks appeared at about −0.60 V and −0.84 V. Compared with a bare carbon paste electrode, the calix[6]arene modified CPE greatly
improves the sensitivity of determining lead and cadmium. The stripping peak currents change linearly with the concentration
of Pb2+ 3.0×10−8–8.0×10−6 mol·L−1 and with that of Cd2+ 6.0×10−8–1.0×10−5 mol ·L−1. The detection limits of Pb2+ and Cd2+ are found to be 8.0×10−9 mol·L−1 and 2.0×10−8 mol·L−1, respectively. The modified carbon paste electrode was applied to determine trace levels of lead and cadmium in water samples.
Comparing with that of atomic absorption spectrometry, the results suggests that the calix[6]arene modified CPE has great
potential for the practical sample analysis.
Foundation item: Supported by the National Natural Science Foundation of China (60171023)
Biography: JI Xiao-bo (1980-), male, Master, research direction: electroanalytical chemistry. 相似文献
10.
A new chemiluminescence (CL) method for the determination of tetracycline and oxytetracycline is developed, based on the CL
reaction of tetracycline and oxytetracycline with Ru (bipy)3
2+ and Ce (IV). In sulfuric acid medium, the CL emission is generated upon continuous oxidtion of Ru(bipy)3
2+ by cerium (IV). The emission intensity is greatly enhanced when tetracycline and oxytetracycline are introduced into the
reaction system after acid degradation. Under the optimum conditions, the calibration curves are linear over the range of
8.0×10−8∼4.0×10−6 mol/L for tetracycline and of 2.0×10−7∼4.0×10−5 mol/L for oxytetracycline, with the detection limits are 4.2×10−8 mol/L for tetracycline and 1.5×10−7 mol/L for oxytetracycline, respectively. The proposed method was used for the determination of tetracycline and oxytetracycline
in pharmaceutical formulations with good results.
Foundation item: Supported by the National Natural Science Foundation of China and the Natural Science Foundation of Hubei
Province.
Biography: HAH He-you (1962), male, Associate profeddor, Ph.D graduate candidate. Present address, Department of Chemistry,
Huainan Teacher's College, Huainan. 相似文献
11.
The electroanalytical method of ferriheme was studied by linear sweep voltammetry in medium of 0.05 mol/L Tris+0.05 mol/L
NH3−NH4Cl buffer at hang mercury drop electrodes (HMDE). Heme exhibits two pair reversible redox peaks and one irreversible peak.
The cathodic peak potentials are−;0.236 V, −0.422 V and −1.408 V respectively. The first and the third peaks can be used for
directly quantitative determination of heme concentrations. The peak currents are good linear relationship with heme concentration
in ranges of 3×10−6–6×10−5 mol/L and 3×10−7–1.5×10−5 mol/L respectively.
Supported by the National Natural Science Foundation of China
Lju Huihong: born in 1965, Lecturer. Visiting scholar from Xiangyang Teacher’s College, Hubei, 441053 相似文献
12.
Co2+/γ-Al2O3 samples were prepared by incipient wetness impregnation of γ-Al2O3 with different concentration solution of CoCl2 and dried at 40 °C. We measured the positron lifetime spectra of the samples of different Co2+ mass fractions (0%–8.24%) heated at different temperatures (100–500°C). All lifetime spectra were resolved into four components,
in which the third and the fourth components were related to the surface state of the micropores and the secondary pores of
the γ-Al2O3. The experimental results showed that the Co2+ was mainly located in the micropores and the secondary pores near to the exterior of the support. For low Co2+ mass fraction samples, when the heating temperature was above 400 °C, dispersal was almost finished. When the Co2+ mass fraction was above 5.59%, Co2+ and Cl− were dispersed into the secondary pores in the form of multiple layers. 相似文献
13.
Sensitive Determination of DNA by RLS Enhancement of Metal Ions 总被引:1,自引:0,他引:1
Huang Jian-ping Chen Fang Ai Xin-ping He Zhi-ke . College of Chemistry Molecular Sciences Wuhan University Wuhan Hubei China . Department of Environmental Engineering Hubei Agricultural College Jingzhou Hubei China 《武汉大学学报:自然科学英文版》2004,9(2):234-238
0 IntroductionThequantitativeanalysisofnucleicacids,especiallythemi cro determinationofnucleicacids,isbecomingmoreandmoreimportantinmanybiologicalstudies.Recently ,apromisingspectraltechnique ,whichwasbasedonthemeasurementofen hancedresonancelightscattering (RLS) [1 ,2 ] ,hasgivenrisetostronginterestbyanalystsandbiochemistsfornucleicacidsandproteinassay[3 9] .Uptonow ,manykindscompoundshavebeenfoundRLSenhancementwhilebindingtoDNA ,andallthesecompoundsarecharacterizedofpositivechargewhicha… 相似文献
14.
ZHENG Qi~ CAO Qihua~ LIU Zhihong~ CAI Ruxiu~ . College of Chemistry Environmental Engineering Jianghan University Wuhan Hubei China . College of Chemistry Molecular Sciences Wuhan University Wuhan Hubei China 《武汉大学学报:自然科学英文版》2006,11(3):677-681
0 IntroductionSltougdiiceasl csoynstceermnsin gharveeac btieveen o txhyeg ei nm psopretcaienst ( oRbjOecSt) iinn bbiioo--medicine and analytical chemistry in recent years[1-4]. Manyi mportant life phenomena and diseases are relatedtotheinter-mediates of ROS[5-7].ROS have beeni mplicated as ani mpor-tant causative factor in cell damage,including apoptosis andnecrosis . Their proposed actions comprise lipid peroxidation,DNAdamage,the mitochondrial respiratory chain destructionand protein mo… 相似文献
15.
A new method of determination of trace CN− in water was proposed. A thin film of Ag2S was electrochemically deposited on both sides of a silver coated piezoelectric crystal. The Ag2S−Ag films can react with CN− selectively, which causes the frequency shifts of the plezoelectric crystal. The frequency shifts are proportional to the
concentration of CN− in the range of 10−6≈10−3 g/L. XPS experiments indicated the sensing film was Ag2S−Ag. A coordination complex Ag−CN− was formed when Ag2S−Ag film contacted with solution containing CN− ion. A response mechanism was proposed based on the XPS data.
Supported by National Natural Science Foundation of China
Hu Jiming: born in Sept, 1952, Professor 相似文献
16.
Han Dong-dong Cheng Gong-zhen Ji Zhen-ping Zhang Bing-guang . College of Chemistry Molecular Sciences Wuhan University Wuhan Hubei China . The State Key Laboratory of Coordination Chemistry Nanjing University Nanjing Jiangsu China 《武汉大学学报:自然科学英文版》2004,9(1):93-98
0 IntroductionThemetalionsinmetallamacrocylesformedbysupramolecularself assemblycantaketrigonal,square planar,andtetrahe dralconfiguration[1 ,2 ] .Metallacrownisaspecialclassofmetalla macrocyle,theyareanalogoustocrownethersinbothstructureandfunctionexceptthatthemetalionsarenowtakingthepositionsofcoordinationatomsincrownether[3,4] .Themetallacrownswithdifferentnumberof [M—N—O]repeatunithavedifferentcavitysizes,suchas 9 MC 3[5 7] ,12 MC 4 [4,8 1 4 ] and 15 MC 5 [1 5] .Thereportedazameta… 相似文献
17.
GenTian Yue JiHuai Wu YaoMing Xiao HaiFeng Ye JianMing Lin MiaoLiang Huang 《科学通报(英文版)》2011,56(3):325-330
Using blend heterojunction consisting of C60 derivatives [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) and poly(3-hexylthiophene) (P3HT) as charge carrier transferring medium to replace I3–/I– redox electrolyte,a novel flexible dye-sensitized solar cell (DSSC) is fabricated.The characterization of infrared spectra and ultraviolet-visible spectra shows that the PCBM/P3HT heterojunction has not only the absorption in ultraviolet light for PCBM,but also the absorption in visible and near infrared light for P3HT,which widens the photoelectric response range for DSSC.The influence of PCBM/P3HT mass ratio on the performance of the solar cell is discussed.Under 100 mW cm–2 (AM 1.5) simulated solar irradiation,the flexible solar cell achieves a lightto-electric energy conversion efficiency of 1.43%,open circuit voltage of 0.87 V,short circuit current density of 3.0 mA cm–2 and fill factor of 0.54. 相似文献
18.
QIAN Shahua~ LUO Yan~ MO Shaobo~ WENG Yue~ . College of Resources Environmental Sciences Wuhan University Wuhan Hubei China . College of Chemistry Molecular Sciences Wuhan University Wuhan Hubei China 《武汉大学学报:自然科学英文版》2006,11(2):437-440
0Introduction Vanadiumplaysanimportantroleinmodernindustry,es peciallyinsteelandchemicalindustry.Forinstance,itscompoundsarewidelyappliedintheproceduresofvitrioland petroleumchemicalmanufactureascatalyzers[14].Vanadium hasseveralvalences,butgenerallyitslowvalencesturnintohighoneseasilyinenvironment[5].BecauseV(Ⅴ)isthemost stableandpoisonousone,weoftenlayemphasisonitinenvi ronmentalpollutioncontrol.Vanadiumexistsinenvironmentalwaterwithextremelylowconcentration.Inseawateritscontentislessthan… 相似文献
19.
A new TFEL material ZnSxO1−x: Ce3+ is prepared. The EL brightness of ZnSxO1−x: Ce3+ is at least one order higher than that of ZnS: Ce3+ at the same doping concentration of Ce3+. The EL emission wavelength of ZnSxO1−x: Ce3+ (X = 0.5) ranges from 400 to 600 nm. The emission of ZnSxO1−x: Ce3+ may be used as the blue part of white TFEL. 相似文献
20.
CHEN Lihua~ ZHANG Yongkang~ YIN Hong~ LIU Liuzhan~ YANG Zhaoxia~ SHEN Hanxi~ . College of Chemistry Chemical Engineering Jishou University Jishou Hunan China . College of Chemistry Nankai University Tianjin China 《武汉大学学报:自然科学英文版》2006,11(3):704-708
0 IntroductionMaalnadria siusb atr ompajicosr .he aAltrthe pmrisoibnlienmi (n qtihneghtraoopsiucs,QHS,Fig.1) is a sesquiterpene endoperoxide isola-ted fromArtemisia annuaL., an ancient Chineseherbal medicine usedfor treatment of fever and ma-laria.Studies of the structure and activity relation-ship have shownthat endoperoxide groupis essentialfor anti malarial activity of QHS and absence of thismoiety lead to completely loss in activity of thedrug. Many techniques have been developed to de… 相似文献