Direct observation of monomer film structure of bacteriochlorophyll <Emphasis Type="Italic">c</Emphasis>

The adsorption and assembling of bacteriochlorophyll c (BChl c) on a highly oriented pyrolytic graphite (HOPG) surface have been investigated by the scanning tunneling microscopy (STM). BChl c molecules are found to self-organize a well-defined adlayer on HOPG surface with a monomeric structure different from the dimer association seen on adlayers of Chls a, c and BChlide c, d. A structural model is proposed for the adlayer.     

Limit of Julia sets forz d +c

The limit behavior of Julia set J(fd,c) for polynomials fd,c(z) = zd + c is considered. That { J( fd,c) } d≥2 converges to the unit circle S1 in Hausdorff metric for some fixed parameter c is proved and some examples showing { J( fd,C) } d≥2 has no limit are given.     

铁磁纳米颗粒系统磁性质对尺寸和各向异性效应的依赖

研究了随机分布颗粒系统的尺寸、各向异性、矫顽力和温度之间的关系.从FexCu1-x,Fe/SiO2,Fe/Al2O3颗粒膜实验结果入手,以Néel-Bron理论和Storner-Wohlfartly模型为依据,建立了描述细磁性颗粒矫顽力Hc与颗粒大小d、热力学温度T的函数关系,并得出在粒径小于dm(=18~20 nm)范围内,矫顽力随着颗粒的尺寸的增加而迅速地增大,而在颗粒尺寸大于这个范围,则按照Hc∝1/d规律变化.       

Itinerant-electron metamagnetic transition and giant magnetic entropy change in La0.8Ce0.2Fe11.4Si1.6 compound

Iron-based rare-earth intermetallic compounds LaFe13?xSix (1.2≤x≤2.6) and CeFe13?xSix (2.4≤x≤2.6) both have the cubic NaZn13-type structure with Fm3c(Oh6) space-group symmetry[1―3]. Fujita et al. [4] demonstrated that the cubic NaZn13-type LaFe13?xSi     

Restricted allowable generalized quantum gates

An allowable generalized quantum gate (introduced by Long, Liu and Wang) has the form of U = Σ _k=0 ^d−1 c _k U _k , where U _k’s are unitary operators on a Hilbert space H and |Σ _k=0 ^d−1 c _k |⩽1 and |c _k |⩽1 (0⩽k⩽d−1). In this work we consider a kind of AGQGs, called restricted allowable generalized quantum gates (RAGQGs), satisfying 0 < Σ _k=0 ^d−1|c _k |⩽1. Some properties of the set RAGQG(H) of all RAGQGs on H are established. Especially, we prove that the extreme points of RAGQG(H) are exactly unitary operators on H and that B(H)=R ⁺ RAGQG(H).     

RN中一类非局部问题基态解的存在性

利用变分方法研究了一类R^N上带有非局部项的分数阶椭圆型偏微分方程基态解的存在性。首先证明了对应泛函在Nehari流形上强制且下有界，因而得到有界极小化序列的存在性，其次应用Ekeland变分原理证明该序列是(PS)_c序列，并且结合假设条件证明泛函满足(PS)_c条件，最终得到该类方程基态解的存在性。     

Enhanced parametric amplification in slow-light photonic crystal waveguides

We demonstrate both theoretically and numerically that slow light can enhance the parametric process of silicon in photonic crystal line-defect waveguides. Specifically, to get the desired gain, the pump power for a given gain medium length or the gain medium length for given pump power can be reduced by （c/vgn）^2 when slow light waveguides are used, where n is the material index of conventional waveguide, vg is the group velocity of the slow light waveguide and c is the light velocity in vacuum.     

QSPR between Physical-Chemical Properties and Molecule Parameters of Alkanes

A set of molecule parameters, namely, N, N′, p, q, n, were used to express the structures of alkanes. A correlative model was established between certain physical-chemical properties and molecular parameters of alkanes by regression method. Eight physical-chemical properties, such as evaporation heat （△vHm^20）, density（D^20 ）, capacity （C^20）, surface tension （δ^20）, boiling point （Tb）, critical temperature（Tc）, critical pressure（Pc） and critical volume（Vc）, of fifty-six C3-C16 alkanes were calculated directly from the model in this paper. The calculated values are in good accordance with the literature ones reported for alkanes, and the correlation coefficients （R） equal or exceed 0.99 . The research results indicate that the principle of the method is simple and clear, the method is practical, the correlativity is excellent, and the predicted data are credible.     

Correlation between the standard formation enthalpy and the path index of pyridine-derivatives

A formulated as △fH _m ^◯ (PPDs,g)=a+Σb_iP_i + c_if_i is put forward for estimating standard formation enthalpies of pyridine-derivatives (PDDs), in which,P _i is path index andc _i f _i is an amended term of interaction between substituent and N atom on pyridine ring. The Calculations based on the model were carried out for some pyridine-derivatives. The values of standard formation enthalpy calculated are consistent with those in literature. Foundation item: Supported by the National Natural Science Foundation of China (29971024) Biography: LI Liang-chao (1958-), male, Associate professor, Research direction: calculating chemistry.     

Microcalorimetric study on the antibiotic activity of clarithromycin and erythromycin

By using LKB-2277 Bioactivity Monitoring System, the heat effect changes in the process of inhibitory action of clarithromycin and erythromycin onEscherichia coli at 37°C were determined. Quantitative analysis showed that relationship between antibiotic concentrationc and rate contantk ofEscherichia coli growth, and half inhibitory ratio concentration IC₅₀: clarithromycin:k=0. 030 03–1. 1736×10⁻³ c, 8. 45 mg ·L⁻¹; erythromycin:k=0.031 08–8.4657×10⁻⁴ c, 14. 45 mg·L⁻¹. As a result of the microcalorimetry experiments, it not only indicated that antibacterial activity of clarithromycin was stronger than that of erythromycin, but also reported the changeable features of thermodynamics of the bacterial cell in biological, biochemical and metabolic process under different drug action. Foundation item: Supported by Natinal Natural Science Fundation of China (29973030), Natural Science Fundation of Hubei Province (98J052) and Post-doctoral Science Fundation of China Biography, SHEN Xue-song (1956-), Associate professor Research direction: biothermochemistry.     

Fabrication and superconducting properties of nano-SiC doped MgB2 tapes

Nano-SiC doped MgB2 tapes were prepared by the in situ powder-in-tube method. Heat treatment was performed at 650℃ for 1 h. XRD data indicate that SiC particles had reacted with the MgB2 during sintering process. MgB2 core seemed to be denser after SiC doping, and the critical temperature was slightly depressed. The critical current density Jc of the SiC doped tapes was significantly enhanced in magnetic fields up to 14 T compared to the undoped ones. For the 5% SiC doped samples, Jc was in- creased by a factor of 32 at 4.2 K, 10 T. The enhancement of Jc-B properties in SiC doped MgB2 tapes is considered to be due to the enhancement of grain linkages and the introduction of effective flux pining centers. The substitution of B by C in MgB2 grains is thought to be the main reason for the improve- ment of the flux pinning ability in SiC doped MgB2 tapes.     

Hydrothermal synthesis and crystal structure of copper （Ⅱ） coordination polymer composed of helix-like chains： [Cu（NIeH）（bpy）]

Hydrothermal reactions of Cu （Ⅱ） acetate, 2,2＇-bipyridyl （bpy） with 5-nitroisophthalic acid （H2NIPH） resulted in a new coordination polymer [Cu（NIPH）（bpy）] 1. Single crystal X-ray diffraction experiment indicates that 1 possesses a single helixlike chains, of which Cu atoms are coordinated by NIPH ligands and bpy ligands. Compound 1 crystallizes in the space group P2（ 1）/c, a = 0.955（19） nm, b = 1.259（3） nm, c = 1.3737（3） nm, ,6= 95.13（3）°, V= 1.6455（6） nm^3 and Z = 4. The TGA analysis shows that 1 has no remarkable weight loss up to 284℃, as a result of its high thermal stability. Magnetic measurements indicate an antiferromagnetic behavior of compound 1.     

Measurement of Magnetization Curve and Magnetic Relaxation for 2H-NbSe2 Crystals

The characteristics of electronic transport properties: behaviors of magnetization curve and magnetic relaxation of a typical normal superconductor 2H-NbSe2 are investigated. The results show that Tc and △Tc of the samples are 7. 2,0. 18 K, indicating that superconducting energy gap at zero temperature is 1. 1 meV. No fish tail shape is found in the magnetization curves at several temperatures. The relationship between remnant magnetic moment and time reveals that the magnetic flux creep of the sample agrees with the Kim-Anderson thermal activation model with the relaxation rate S=0.000 36 at T=6 K.     

Study on the charge transference and local magnetic moment of yttrium-cobalt compound

The electronic charge transference and local magnetic moment of the YCo₅ intermetallic compound were calculated using SCF-MO-DVXα method and multiple cluster model. The result shows that about one 4d-electron is transferred from anY atom to Co₁(2c), and the calculated local spin magnetic moments of Co_I(2c) and Co_II(3g) atoms in YCo₅ compound are 1.33 and 1.48μ _B , respectively, which are in very good agreement with experiments. Supported by the National Natural Science Foundation of China Qiao Haoxue: born in Apr. 1970, Master     

超声波下酸化碘酸钾和亚硫酸钠反应的反应速率研究

分别测定在有超声波作用和在无超声波作用条件下 ,酸化碘酸钾 (KIO3 )和亚硫酸钠 (Na2 SO3 )反应的反应速率方程式及活化能 ,从而研究该反应的机理以及超声波在该反应中的作用 ,并确定反应的最佳条件。实验得出 ,超声波对该反应有一定的促进作用 ,但是这种促进作用只提高反应的速率常数和降低反应的活化能 ,并没有改变反应机理。在超声波功率为 30 0W时 ,反应的速率方程表示式为 :v =k·c1 0 9(KIO3 ) ·c1 0 0 (Na2 SO3 )·c1 0 8(H+ ) ,其中 :k =95 0 (mol-1·L) 2 ·s-1,活化能为 17 35kJ·mol-1。实验还得出 ,在温度为2 98K时 ,当KIO3 与Na2 SO3 的初始浓度比为 2∶5 ,H+ 的初始浓度为 0 0 4 2 8mol·L-1,超声功率为 30 0W时 ,反应速率为最快 ,即v =4 31× 10 -4mol·L-1·s-1)。     

关于Terai猜想的一点注记

运用Gel’fond-Baker方法证明了在一定条件下方程a~x+b~y=c~z仅有正整数解(x,y,z)=(2,2,r),并推广了文献[3]的结论。     

Optimization of nanocavity field enhancement using two-dimensional plasmonic photonic crystals

We have investigated the influence of Ag nanorod radius(r)on the resonant modes of a two-dimensional plasmonic photonic crystal(PPC)with dipole sources embedded into the central vacancy area,using finite-difference time-domain methods.Both the localized surface plasmon(LSP)mode of individual Ag nanorods and the resonant cavity mode of PPC are found to vary as a function of r.The resonant cavity mode is strongly enhanced as r is increased,while the LSP signal will eventually become no longer discernable in the Fourier spectrum of the time-evolved field.An optimized condition for the nanocavity field enhancement is found for a given PPC periodicity(e.g.d=375 nm)with the critical nanorod radius rc=d/3.At this point the resonant cavity mode has the strongest field enhancement,best field confinement and largest Q-factor.We attribute this to competition between the blocking of cavity confined light to radiate out when the cavity resonant frequency falls inside the opened photonic stopband as r reaches rc,and the transfer of cavity mode energy to inter-particle plasmons when r is further increased.     

弱c*-正规子群与有限群的p-幂零性

引入弱c*-正规子群的定义,并利用此定义得到有限群p-幂零的两组充分条件.     

Preparation,crystal structure and quantum chemical investigation of [Li(NTO) (H2O)]

[Li(NTO)(H₂O)₂] was prepared by mixing the aqueous solution of 3-nitro-1,2,4-triazol-5-one (NTO) and lithium hydroxide. The crystal structure of [Li(NTO)(H₂O)₂] was determined by single crystal diffraction analysis. The crystal is monoclinic, space group P2₁/n with crystal parameters of a = 0.742 0(2) nm, b = 0.344 9(1) nm,c = 2.490 6(3) nm, β= 94.89(1)°, Z = 4,D _c , = 1.799 g cm⁻³,V = 0.635 nm³, μ = 1.591 cm⁻¹, F(000) = 392. The finalR is 0.051. The MNDO MO calculation shows that the coordinate bonds of title compound possess certain extent of covalent character. O₂ atom of NTO anion is bonded to Li atom; the nitro group will be lost first when NTO is decomposed.     

Effect of Mach number on transonic flow past a circular cylinder

The effect of Mach number on transonic flow past a circular cylinder is investigated numerically for the free-stream Mach number M∞ from 0.85 to 0.98 and the Reynolds number 2×10^5 based on the diameter of the cylinder. The work provides an insight into several salient features, including unsteady and quasi-steady flow state, formation of local supersonic zone, and evolution of turbulent shear layer. Results show that there exist two flow states dependent of a critical Mach number Mcr around 0.9. One is an unsteady flow state characterized by moving shock waves interacting with the turbulent flow in the near region of the cylinder for M∞〈Mcr, and the other is a quasi-steady flow state with nearly stationary shock waves formed in the near wake for M∞〉Mcrs, suppressing vortex shedding from the cylin- der. Some flow behaviors in the unsteady and quasi-steady flow states are revealed. From time evolu- tion of flow structures, local supersonic zones are identified in the wake and generated by two typical processes, i.e. reverse flow behind the cylinder and shed vortices in the near wake. The convective Mach number Mc of turbulent shear layers shed from the cylinder is identified nearly as Mc〈I in the unsteady flow regime and Mc〉I in the quasi-steady flow regime, resulting in different evolutions of the shear layers.