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Reductive leaching of manganese from low-grade pyrolusite ore in sulfuric acid using pyrolysis-pretreated sawdust as a reductant
作者姓名:Ya-li Feng  Shi-yuan Zhang  Hao-ran Li
作者单位:School of Civil and Environmental Engineering, University of Science and Technology Beijing, Beijing, 100083, China
基金项目:This research was financially supported by the China Ocean Mineral Resource Research and Development Association(DY125-15-T-08),the National Key Technology Research and Development Program of China(2012BAB07B05),the National High Technology Research and Development Program of China(2012AA062401),the National Natural Science Foundation of China(.21176242 and 21176026)
摘    要:Manganese (Mn) leaching and recovery from low-grade pyrolusite ore were studied using sulfuric acid (H2SO4) as a leachant and pyrolysis-pretreated sawdust as a reductant. The effects of the dosage of pyrolysis-pretreated sawdust to pyrolusite ore, the concentration of sulfuric acid, the liquid/solid ratio, the leaching temperature, and the leaching time on manganese and iron leaching efficiencies were investigated. Analysis of manganese and iron leaching efficiencies revealed that a high manganese leaching efficiency was achieved with low iron extraction. The optimal leaching efficiency was determined to be 20wt% pyrolysis-pretreated sawdust and 3.0 mol/L H2SO4 using a liquid/ solid ratio of 6.0 mL/g for 90 min at 90℃. Other low-grade pyrolusite ores were tested, and the results showed that they responded well with manganese leaching efficiencies greater than 98%.

关 键 词:manganese  ore  treatment    pyrolusite    sawdust    pyrolysis    leaching    manganese

Reductive leaching of manganese from low-grade pyrolusite ore in sulfuric acid using pyrolysis-pretreated sawdust as a reductant
Ya-li Feng,Shi-yuan Zhang,Hao-ran Li.Reductive leaching of manganese from low-grade pyrolusite ore in sulfuric acid using pyrolysis-pretreated sawdust as a reductant[J].International Journal of Minerals,Metallurgy and Materials,2016,23(3):241-246.
Authors:Ya-li Feng  Shi-yuan Zhang  Hao-ran Li
Affiliation:1. School of Civil and Environmental Engineering, University of Science and Technology Beijing, Beijing 100083, China;2. School of Civil and Environmental Engineering, University of Science and Technology Beijing, Beijing 100083, China;National Key Laboratory of Biochemical Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;3. National Key Laboratory of Biochemical Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China
Abstract:Manganese (Mn) leaching and recovery from low-grade pyrolusite ore were studied using sulfuric acid (H2SO4) as a leachant and pyrolysis-pretreated sawdust as a reductant. The effects of the dosage of pyrolysis-pretreated sawdust to pyrolusite ore, the concentration of sulfuric acid, the liquid/solid ratio, the leaching temperature, and the leaching time on manganese and iron leaching efficiencies were investigated. Analysis of manganese and iron leaching efficiencies revealed that a high manganese leaching efficiency was achieved with low iron extraction. The optimal leaching efficiency was determined to be 20wt% pyrolysis-pretreated sawdust and 3.0 mol/L H2SO4 using a liquid/ solid ratio of 6.0 mL/g for 90 min at 90°C. Other low-grade pyrolusite ores were tested, and the results showed that they responded well with manganese leaching efficiencies greater than 98%.
Keywords:manganese ore treatment  pyrolusite  sawdust  pyrolysis  leaching  manganese
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