| 含氟砌块的分子设计合成及其在合成含氟杂环化合物中的应用 |
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| 引用本文： | 蒋海珍,宋力平,罗会华,易海,朱仕正,郝健.含氟砌块的分子设计合成及其在合成含氟杂环化合物中的应用[J].上海大学学报(自然科学版),2011,17(4):458-470. |
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| 作者姓名： | 蒋海珍 宋力平 罗会华 易海 朱仕正 郝健 |
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| 作者单位： | 1.上海大学 理学院，上海 200444; 2.中国科学院 有机氟化学重点实验室，上海 200032 |
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| 基金项目： | 国家自然科学基金资助项目(20772079,21072127,21032006,21072128); 上海市科委基金资助项目(08JC1409900,10JC1405600) |
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| 摘 要： | 由于氟原子赋予的特殊性能,含氟杂环化合物在医药、农药及特种功能材料等研究领域受到广泛关注.综述近年来本研究团队常用的一些新颖含氟砌块如含氟酮酸酯、含氟亚胺酰卤等的设计合成及其在含氟杂环化合物合成中的应用进展.
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| 关 键 词： | 含氟砌块 含氟杂环化合物 酮酸酯 亚胺酰卤 |
| 收稿时间： | 2011-06-30 |
Design and Synthesis of Fluorine-Containing Building Blocks and Application to Synthesis of Fluorinated Heterocycles |
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| JIANG Hai-zhen,SONG Li-ping,LUO Hui-hua,YI Hai,ZHU Shi-zheng,HAO Jian.Design and Synthesis of Fluorine-Containing Building Blocks and Application to Synthesis of Fluorinated Heterocycles[J].Journal of Shanghai University(Natural Science),2011,17(4):458-470. |
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| Authors: | JIANG Hai-zhen SONG Li-ping LUO Hui-hua YI Hai ZHU Shi-zheng HAO Jian |
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| Affiliation: | 1. College of Sciences, Shanghai University, Shanghai 200444, China; 2. Key Laboratory of Organofluorine Chemistry, Chinese Academy of Sciences, Shanghai 200032, China |
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| Abstract: | Fluorinated heterocycles have attracted substantial research attention in the fields of medicine, pesticide and special-function materials,which have special properties caused by fluorine atoms.This review highlights the recent development on the synthesis of novel fluorine-containing building blocks, such as fluorine-containing keto esters and fluorine-containing imidoyl halides,and on their applications to the preparation of fluorinated heterocycles. |
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| Keywords: | fluorine-containing building block fluorinated heterocycle keto ester imidoyl halide |
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