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Kinetic modeling of copper bioleaching from low-grade ore from the Shahrbabak Copper Complex
作者姓名:Saman Beikzadeh Noei  Saeed Sheibani  Fereshteh Rashchi  Seyed Mohammad Javad Mirazimi
作者单位:School of Metallurgy and Materials Engineering, College of Engineering, University of Tehran, Tehran 13145-1318, Iran
摘    要:The copper recovery from low-grade copper sulfide ore was investigated using microbial leaching. Several parameters substantially affect the bioleaching of copper; among them, pulp density and nutrient media were selected for investigation. The optimum conditions for copper recovery were a pulp density of 5 g/mL, a mixed-mineral salt medium of Acidithiobacillus thiooxidans (70vol%) and Acidithiobacillus ferrooxidans (30vol%), and 10vol% of inoculum. Under these conditions, the maximum bioleaching capacity of the medium for copper recovery was determined to be approximately 99%. The effect of pulp density on the kinetics of the bioleaching process was surveyed using both da Silva's method and constrained multilinear regression analysis. The kinetics of copper dissolution followed the shrinking core model, and the process was diffusion controlled at a pulp density of 5 g/mL. Nevertheless, at higher pulp densities, the process was controlled by chemical reaction.

关 键 词:bioleaching    kinetics    modeling    copper    mesophilic  bacteria

Kinetic modeling of copper bioleaching from low-grade ore from the Shahrbabak Copper Complex
Saman Beikzadeh Noei,Saeed Sheibani,Fereshteh Rashchi,Seyed Mohammad Javad Mirazimi.Kinetic modeling of copper bioleaching from low-grade ore from the Shahrbabak Copper Complex[J].International Journal of Minerals,Metallurgy and Materials,2017,24(6):611-620.
Authors:Saman Beikzadeh Noei  Saeed Sheibani  Fereshteh Rashchi  Seyed Mohammad Javad Mirazimi
Affiliation:School of Metallurgy and Materials Engineering,College of Engineering,University of Tehran,Tehran 13145-1318,Iran
Abstract:The copper recovery from low-grade copper sulfide ore was investigated using microbial leaching. Several parameters substan-tially affect the bioleaching of copper; among them, pulp density and nutrient media were selected for investigation. The optimum conditions for copper recovery were a pulp density of 5 g/mL, a mixed-mineral salt medium ofAcidithiobacillus thiooxidans (70vol%) andAcidithioba-cillus ferrooxidans (30vol%), and 10vol% of inoculum. Under these conditions, the maximum bioleaching capacity of the medium for copper recovery was determined to be approximately 99%. The effect of pulp density on the kinetics of the bioleaching process was surveyed using both da Silva's method and constrained multilinear regression analysis. The kinetics of copper dissolution followed the shrinking core model, and the process was diffusion controlled at a pulp density of 5 g/mL. Nevertheless, at higher pulp densities, the process was controlled by chemi-cal reaction.
Keywords:bioleaching  kinetics  modeling  copper  mesophilic bacteria
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