Calcite is a common gangue mineral in dachang mining area. Previous studies on calcite of tin polymetallic ore in the upper part of the region are detailed, but the research on zinc copper ore in the lower part has not been carried out. This study added test the pull yao skarn type zinc copper and copper pit deep zinc skarn type copper deposit calcite content of rare earth, total content of the rare-earth element in zinc copper mine are generally lower, ΣREE = 11.15 x 10-6-16.17 x 10-6, europium has positive anomaly, the delta Eu = 1.46 ~ 2.80, and light and heavy rare earth obvious fractionation, LREE/HREE = 2.63 ~ 6.84, distribution patterns with europium is abnormal enrichment of light rare earth right model, the distribution patterns and tin polymetallic calcite distribution patterns of rare earth elements are similar, which implies that they may be products of different stages of the same origin. The results show that the mineralization fluid is derived from magmatic hydrothermal fluid of longbulid magmatic crystallization period, and the mineralization environment is the transition from reduction environment to oxidation environment.